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W. Bernd Schweizer
Researcher at École Polytechnique Fédérale de Lausanne
Publications - 58
Citations - 2903
W. Bernd Schweizer is an academic researcher from École Polytechnique Fédérale de Lausanne. The author has contributed to research in topics: Iminium & Organocatalysis. The author has an hindex of 27, co-authored 58 publications receiving 2785 citations. Previous affiliations of W. Bernd Schweizer include ETH Zurich.
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On the validity of Wallach's rule: on the density and stability of racemic crystals compared with their chiral counterparts
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Structure elucidation of hexabromocyclododecanes—a class of compounds with a complex stereochemistry
TL;DR: Spectroscopic and chromatographic data is reported for eight out of 16 possible HBCD stereoisomers, which were isolated from a technical product and the occurrence, fate, and toxicology of these individual stereoisomer can now be studied.
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Tetrameric Cubic Structures of Two Solvated Lithium Enolates
TL;DR: The structures of the crystalline lithium enolates derived from 3, 3-dimethyl-2-butanone and from cyclopentanone have been determined by X-ray analysis as mentioned in this paper.
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Structures of Three Lithium Ester Enolates by X-ray Diffraction: Derivation of Reaction Path for Cleavage into Ketene and Alcoholate'
TL;DR: In this article, a detailed analysis of the geometry of the ester enolate grouping was derived, and the reaction path trajectory for the breakdown of this type of molecule can be derived.
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The Fluorine‐Iminium Ion Gauche Effect: Proof of Principle and Application to Asymmetric Organocatalysis
TL;DR: The gauche effect that is induced upon reversible formation of an iminium ion provides a powerful method for the preorganization of transient intermediates that are central to secondary amine catalyzed processes.