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Showing papers by "Karlsruhe Institute of Technology published in 1983"


Journal ArticleDOI
TL;DR: In this paper, the velocity distribution and reattachment length of a single backward-facing step mounted in a two-dimensional channel were measured using laser-Doppler measurements.
Abstract: Laser-Doppler measurements of velocity distribution and reattachment length are reported downstream of a single backward-facing step mounted in a two-dimensional channel. Results are presented for laminar, transitional and turbulent flow of air in a Reynolds-number range of 70 < Re < 8000. The experimental results show that the various flow regimes are characterized by typical variations of the separation length with Reynolds number. The reported laser-Doppler measurements do not only yield the expected primary zone of recirculating flow attached to the backward-facing step but also show additional regions of flow separation downstream of the step and on both sides of the channel test section. These additional separation regions have not been previously reported in the literature.Although the high aspect ratio of the test section (1:36) ensured that the oncoming flow was fully developed and two-dimensional, the experiments showed that the flow downstream of the step only remained two-dimensional at low and high Reynolds numbers.The present study also included numerical predictions of backward-facing step flow. The two-dimensional steady differential equations for conservation of mass and momentum were solved. Results are reported and are compared with experiments for those Reynolds numbers for which the flow maintained its two-dimensionality in the experiments. Under these circumstances, good agreement between experimental and numerical results is obtained.

1,637 citations


Proceedings Article
08 Aug 1983
TL;DR: Results are reported of an investigation about how an ``oriented smoothness'' constraint may be formulated and evaluated about how variations of the displacement vector field only in directions with small or no variation of gray values are restricted.
Abstract: Smoothness constraints have been used to facilitate the estimation of displacement vector fields. Differing from HORN and SCHUNCK 81 who employ a general smoothness requirement, this contribution reports an analysis of an "oriented smoothness" requirement: a change in the displacement vector field is only constrained in the direction perpendicular to the characteristic gray value variation based on which the displacement vector is estimated. An iterative solution for the resulting system of nonlinear partial differential equations is developed. It is shown how this system of equations relates to the one derived by HORN and SCHUNCK 81.

916 citations


Journal ArticleDOI
TL;DR: In this article, the motion of a quantum mechanical particle is studied in the presence of a periodic potential and frictional forces, and the behavior changes from diffusion to localization depending on the parameters.
Abstract: The motion of a quantum mechanical particle is studied in the presence of a periodic potential and frictional forces. Depending on the parameters, the behavior changes from diffusion to localization.

356 citations


Journal ArticleDOI
TL;DR: In this paper, the pure n-alkanes with 9 to 16 carbon atoms were converted on a Pt/HZSM-5 zeolite in the presence of hydrogen.

317 citations


Journal ArticleDOI
TL;DR: An overview of the developments that have taken place in this area since 1956 is provided, dealing with new unsaturated amino acids, cyclopropane- and cyclobutane-amino acids, heterocyclic amino acid, halogen-containing amino acids sulfur-, selenium- and phosphorus- containing amino acids as well as aliphatic amino acids.
Abstract: The majority of the 500 or so naturally occurring amino acids known today were discovered during the last 30 years, for example during the search for new antibiotics in the culture media of microorganisms, or as components of the antibiotics in fungi, seeds, in numerous plants and fruits, and in the body fluids of animals. Some 240 of these amino acids occur free in nature, some only as intermediates in metabolism. This article provides an overview of the developments that have taken place in this area since 1956 when the last review appeared. Summary accounts are presented, dealing with new unsaturated amino acids, cyclopropane- and cyclobutane-amino acids, heterocyclic amino acids, halogen-containing amino acids sulfur-, selenium- and phosphorus-containing amino acids as well as aliphatic amino acids. In a few cases, e. g. betalamic acid and muscaflavin, the biosynthesis is described in detail.

264 citations


Book ChapterDOI
01 Dec 1983
TL;DR: This chapter presents the new methods of solving algebraic problems with high accuracy, that is, error control is performed automatically by the computer without any requirement on the part of the user, such as estimating spectral radii.
Abstract: Publisher Summary This chapter presents the new methods of solving algebraic problems with high accuracy. Examples of such problems are the solving of linear systems, eigenvalue/eigenvector determination, computing zeros of polynomials, sparse matrix problems, computation of the value of an arbitrary arithmetic expression, in particular, the value of a polynomial at a point, nonlinear systems, linear, quadratic, and convex programming over the field of real or complex numbers as well as over the corresponding interval spaces. All the algorithms based on new methods have some key properties in common: (1) every result is automatically verified to be correct by the algorithm; (2) the results are of high accuracy, that is, the error of every component of the result is of the magnitude of the relative rounding error unit; (3) the solution of the given problem is automatically shown to exist and to be unique within the given error bounds; and (4) the computing time is of the same order as comparable floating-point algorithm. The key property of the algorithms is that error control is performed automatically by the computer without any requirement on the part of the user, such as estimating spectral radii. The error bounds for all components of the inverse of the Hilbert 15 × 15 matrix are as small as possible, that is, left and right bounds differ only by one in the 12 place of the mantissa of each component. It is called least significant bit accuracy.

220 citations


Journal ArticleDOI
TL;DR: In this paper, a manageable superfield formulation is developed which allows one to evaluate the physical effects of the non-linear field when it is coupled to other multiplets, useful in model building.

212 citations


Journal ArticleDOI
TL;DR: In this article, the capacity of a polycrystalline pure aluminium/0.16 M NH 4 -tartrate at pH 5-7, in the potential range −900 mV ≤ E H ≤ 400 mV, is characterized by a high-frequency capacitive and a low-frequency inductive behaviour.

210 citations


Book ChapterDOI
01 Jan 1983
TL;DR: A zonoid is a convex body in euclidean space which can be approximated, in sense of the Hausdorff metric, by finite vector sums of line segments as mentioned in this paper.
Abstract: A zonoid is a convex body in euclidean space which can be approximated, in sense of the Hausdorff metric, by finite vector sums of line segments Several equivalent definitions are known, and zonoids appear in some surprisingly different contexts The purpose of the present survey article is twofold After giving some basic definitions and properties of zonotopes and zonoids, we describe the various ways in which zonoids enter the discussion of a number of seemingly unrelated topics The stress is here on interrelations between the geometry of convex bodies and other fields The second part treats those results and problems concerning zonoids and their generalizations which are of interest within the theory of convex bodies

187 citations


Journal ArticleDOI
TL;DR: In this paper, a six site potential model for liquid acetonitrile was developed based on atomic interaction parameters taken from studies of other liquids and partial charges derived by ab initio calculations, which yields results in good agreement with experimental data on the thermodynamics, structure, self diffusion coefficients and reorientational correlation times of the liquid.
Abstract: A six site potential model has been developed for liquid acetonitrile, based on atomic interaction parameters taken from studies of other liquids and partial charges derived by ab initio calculations. When used in molecular dynamics simulations, the model yields results in good agreement with experimental data on the thermodynamics, structure, self diffusion coefficients and reorientational correlation times of the liquid.

170 citations


Journal ArticleDOI
TL;DR: In this article, a range of petrological models compatible with the observed azimuthal variation of seismic P-wave velocity is explored, and it is shown that the preferred orientation of olivine is formed in the recent West European crustal stress field leaking into the upper mantle.

Journal ArticleDOI
TL;DR: In this paper, the authors give an introduction to the science of measuring and mapping the earth's surface according to the classical definition of geodesy, and the last phrase of Seneca's "There is nothing which does not fall prey to your yardstick".

Book ChapterDOI
01 Jan 1983
TL;DR: This work describes an algorithm due to Kronecker based on the minimum root Separation, Sturm's algorithm, an algorithm based on Rolle’s theorem due to Collins and Loos and the modified Uspensky algorithm dueto Collins and Aritas.
Abstract: Let A be a polynomial over Z, Q or Q(α) where α is a real algebraic number. The problem is to compute a sequence of disjoint intervals with rational endpoints, each containing exactly one real zero of A and together containing all real zeros of A. We describe an algorithm due to Kronecker based on the minimum root Separation, Sturm’s algorithm, an algorithm based on Rolle’s theorem due to Collins and Loos and the modified Uspensky algorithm due to Collins and Aritas. For the last algorithm a recursive version with correctness proof is given which appears in print for the first time.

Book ChapterDOI
01 Jan 1983
TL;DR: In this article, a simple resultant calculus for algebraic number theory is presented, which reduces all operations on algebraic numbers to polynomial arithmetic on long integers together with some auxiliary arithmetic on rational intervals.
Abstract: The aim of this chapter is an introduction to elementary algorithms in algebraic extensions, mainly over Q and, to some extent, over GF(p). We will talk about arithmetic in Q(α) and GF(p n ) in Section 1 and some polynomial algorithms with coefficients from these domains in Section 2. Then, we will consider the field K of all algebraic numbers over Q and show constructively that K indeed is a field, that multiple extensions can be replaced by single ones and that K is algebraically closed, i.e. that zeros of algebraic number polynomials will be elements of K (Section 4 — 6). For this purpose we develop a simple resultant calculus which reduces all Operations on algebraic numbers to polynomial arithmetic on long integers together with some auxiliary arithmetic on rational intervals (Section 3). Finally, we present some auxiliary algebraic number algorithms used in other chapters of this volume (Section 7). This chapter does not include any special algorithms of algebraic number theory. For an introduction and survey with an extensive bibliography the reader is referred to Zimmer [15].

Journal ArticleDOI
TL;DR: From the results, it is concluded that plastids possess an independent HMG-CoA reductase, which emphazises the specifity of the mevinolin effect and indicates that the biosynthesis of mevalonic acid is a mandatory requirement for root growth.
Abstract: To obtain information on the importance of a functional mevalonate synthesis for plant growth and development, we investigated the effect of mevinolin, a highly specific inhibitor of 3-hydroxy-3-methylglutaryl (HMG) coenzyme A reductase (the mevalonate-producing enzyme) on growth, sterol accumulation and pigment formation of radish seedlings (Raphanus sativus L. cv. Saxa Treib) and in part also wheat seedlings (Triticum aestivum L. cv. Kolibri). Mevinolin applied during germination inhibits root elongation and development of lateral roots in etiolated and light-grown radish seedlings. This effect cannot be overcome by exogenous GA3, but by addition of mevalonic acid, the product of the internally inhibited reaction. This emphazises the specifity of the mevinolin effect and indicates that the biosynthesis of mevalonic acid is a mandatory requirement for root growth. In light-grown radish seedlings mevinolin also affects hypocotyl length-growth and inhibits sterol accumulation, but has little effect on the chlorophyll and carotenoid accumulation in the chloroplasts of the cotyledons. This indicates the possible presence of an independent mevalonate synthesizing pathway within the plastids and suggests a low transport rate of mevinolin from the radish roots to the cotyledons. When mevinolin is directly applied to the leaves at higher concentrations, it also reduces the light-induced chlorophyll and carotenoid accumulation as has been shown with etiolated primary leaves of wheat. This inhibition is age-dependent and proceeds to a higher extent in older than in younger etiolated leaf tissue. From our results we conclude that plastids possess an independent HMG-CoA reductase. In the cotyledons of radish, mevinolin seems to induce a senescence retardation and sun-type growth response, as has been evaluated by measuring the fast and slow chlorophyll fluorescence induction kinetics (Kautsky effect). These responses may be due to inhibitor-induced changes in the intracellular phytohormone balance.

Journal ArticleDOI
TL;DR: In this article, the weight function method was used to calculate stress intensity factors for a semi-elliptical surface crack in a plate exposed to stress gradients, and the stress intensity factor was calculated for a plate with respect to a fixed number of cracks.
Abstract: The weight function method is used to calculate stress intensity factors for a semi-elliptical surface crack in a plate exposed to stress gradients.

Journal ArticleDOI
TL;DR: In this article, a detailed investigation of 140 slope movements in slightly cohesive soils show that the process of movement is represented by sliding and flow events, and that shallow scars with planar slides predominate so that the supposition of an infinite slope model for slope stability appears to be justified.

Journal ArticleDOI
TL;DR: In this article, a regionS of the complex plane is determined such that a two-step iterative method converges if the eigenvalues of an iteration operatorT are contained inS. For a givenS, optimal methods are described, and upper and lower bounds are derived for the associated asymptotic rate of convergence.
Abstract: Using the theory of Euler methods from summability theory, we investigate general iterative methods for solving linear systems of equations. In particular, for a given Euler method, a regionS of the complex plane is determined such that ak-step iterative method converges if the eigenvalues of an iteration operatorT are contained inS. For a givenS, optimal methods are described, and upper and lower bounds are derived for the associated asymptotic rate of convergence. Special attention is given to two-step methods with complex parameters.

Journal ArticleDOI
TL;DR: This study indicates that cucumber is one of the most UV-B sensitive crop species so far identified with respect to reduced growth and flavonoid content.

Journal ArticleDOI
TL;DR: In this article, a new method for the analysis of multiaxial residual stress states is presented, which is based on high resolution neutron diffraction, analogous to X-ray stress analysis, but the use of neutrons instead of X-rays allows to analyse the stress distributions also in the interior of technical components in a non-destructive way.

01 Oct 1983
TL;DR: In this paper, an equation for predicting heat transfer coefficients for nucleate boiling of mixtures is derived, which contains only one adjustable parameter and the liquid-phase mass transfer coefficient.
Abstract: An equation for predicting heat transfer coefficients for nucleate boiling of mixtures is derived. This expression contains only one adjustable parameter and the liquid-phase mass transfer coefficient. If the adjustable parameter is put equal to unity, comparison with the most recent data for the SF/sub 6/-CF/sub 2/-Cl/sub 2/ system gives a mass transfer coefficient of 2 X 10/sup -4/ m/s, which is of the same order of magnitude as the value obtained in physical and chemical absorption and in fallingfilm vaporization. The new equation corresponds particularly well with the experimental observation that the heat transfer coefficient is less dependent on the heat flux density and the pressure for nucleate boiling of mixtures than in the case of the pure components.

Journal ArticleDOI
TL;DR: In this article, the electrocatalytic effect of underpotential deposition (UPD) of bismuth on the cathodic reduction of oxygen and hydrogen peroxide has been investigated on poly- and mono-crystalline (111) and (100) gold electrodes in 0.5 M HClO4 solution.

Journal ArticleDOI
TL;DR: In this paper, the electrocatalytic effect of underpotential lead adsorbates on the cathodic reduction of O2 and H2O2 has been investigated in 0.5 M HClO4 solutions on rotating disc gold (111), (100) and (110) single-crystal surfaces.

Journal ArticleDOI
TL;DR: In this paper, an extended scattered light measuring system is described, with which the scattered light signals of all "border" particles can be recognized and eliminated, and the apparatus permits improvements with respect to the possible measurement range, the maximum permissible particle concentration and the unambiguity of the scattering light signals for irregularly shaped particles.

Book ChapterDOI
01 Jan 1983
TL;DR: In this article, a long-range seismic refraction experiment to investigate the crust and uppermost mantle structure beneath the Rhenish Massif was completed during 1978 and 1979, which included a 600-km-long main profile extending from the Paris Basin in the southwest, across the Massif itself, to the Hessian Depression in the northeast, and three cross-profiles, up to 170 km long, almost wholly located in the massif itself.
Abstract: The long-range seismic refraction experiment to investigate the crust and uppermost mantle structure beneath the Rhenish Massif was completed during 1978 and 1979. It included a 600-km-long main profile extending from the Paris Basin in the southwest, across the Massif itself, to the Hessian Depression in the northeast, and three cross-profiles, up to 170 km long, almost wholly located in the Massif itself. Interpretation of the data, including ray-tracing through laterally inhomogeneous media and calculation of synthetic seismograms, has yielded the following velocity-depth information.

Journal ArticleDOI
TL;DR: In this article, the P7(SiMe3)-3-n(SnMe3)n with (n = 1, 2 or 3) depending on the molar ratio.

Journal ArticleDOI
TL;DR: In this paper, photoemission spectra are reported for the valence band of quench-condensed Au x Sn 100−x (0⩽x ⩽100) films in the amorphous state.
Abstract: Photoemission spectra are reported for the valence band of quench-condensed Au x Sn 100−x (0⩽x⩽100) films in the amorphous state. It is found that the valence-band spectra for the 20⩽x⩽80 region, measured just after condensation exhibit a decrease in intensity towards the Fermi energy E F which can be understood in terms of a minimum in the density of states near E F . The minimum seems to be induced by a maximum in the structure factor and is correlated with the stability of the amorphous state.

Journal ArticleDOI
TL;DR: In this article, the underpotential deposition (UPD) of Cd on polycrystalline silver substrate has been investigated in 0.5 M Na2SO4 supporting electrolyte solutions.

Journal ArticleDOI
TL;DR: In this paper, the level scheme of the biexcitons in ZnO was solved by two-photon reabsorption spectroscopy, and three levels were detected, corresponding to the possible combinations of A and B valence band holes.
Abstract: The controversy about the level scheme of the biexcitons in ZnO is solved by two-photon reabsorption spectroscopy. Three levels are detected, corresponding to the possible combinations of A and B valence band holes. The diamagnetic shift of these states is below 2 × 10−6 eV T−2 in agreement with the small exciton and biexciton radii. In forward two-photon Raman scattering, two excitation induced renormalizations of the polariton dispersion are observed, partly involving transitions to the biexciton level. The M-band luminescence and the resonance structure observed in backward two-photon Raman scattering are reconsidered in terms of the new level scheme. Das Problem des Termschemas der Biexzitonen in ZnO wird durch Zweiphotonen-Reabsorptionsspektroskopie gelost. Drei Biexzitonenniveaus werden beobachtet entsprechend den moglichen Kombinationen von Lochern aus den A- und B-Valenzbandern. Die diamagnetische Verschiebung dieser Zustande liegt unter 2 × 10−6 eV T−2 in Ubereinstimmung mit den kleinen Exzitonen- und Biexzitonenradien. Die Zweiphotonen-Ramanstreuung in Vorwartsrichtung zeigt zwei anregungsinduzierte Renormierungen der Polaritonendispersion, die sich teilweise auf Ubergange zum Biexziton zuruckfuhren lassen. Die Lumineszenz der M-Bande und die Resonanz in der Zweiphotonen-Ramanstreuung in Ruckwartsrichtung werden im Rahmen des neuen Biexzitonen-Termschemas diskutiert.

Journal ArticleDOI
TL;DR: In this paper, the steady flow of a row of turbulent jets issuing normally into a nearly uniform cross flow, using three-dimensional finite-difference numerical procedures, is calculated using a quadratic upstream weighted (QUICK) difference scheme in representing the convection terms.