Tomsk Polytechnic University

About: Tomsk Polytechnic University is a education organization based out in Tomsk, Russia. It is known for research contribution in the topics: Combustion & Ignition system. The organization has 9190 authors who have published 13224 publications receiving 103735 citations.

Preparation and X-ray Structural Study of Dibenziodolium Derivatives

Abstract: New experimental procedures for the preparation of dibenziodolium salts by oxidative cyclization of 2-iodobiphenyl in the presence of appropriate strong acids are described. Particularly useful is a convenient one-pot synthesis of dibenziodolium hydrogen sulfate from 2-iodobiphenyl using Oxone as an inexpensive and environmentally safe oxidant. Dibenziodolium hydrogen sulfate, bis(triflyl)imidate, or triflate can be readily converted to various other dibenziodolium derivatives (chloride, bromide, thiocyanate, azide, cyanide, phenylsulfinate) by anion exchange. Structures of key products have been established by single-crystal X-ray diffraction analysis. Particularly interesting is the X-ray structure of dibenziodolium thiocyanate, which represents the first example of a structurally characterized hypervalent iodine compound with a relatively short iodine–sulfur secondary bond distance.

Measurement of the cross section for electroweak production of a Z boson, a photon and two jets in proton-proton collisions at √s = 13 TeV and constraints on anomalous quartic couplings

Abstract: A measurement is presented of the cross section for electroweak production of a Z boson and a photon in association with two jets (Zγjj) in proton-proton collisions. The Z boson candidates are selected through their decay into a pair of electrons or muons. The process of interest, electroweak Zγjj production, is isolated by selecting events with a large dijet mass and a large pseudorapidity gap between the two jets. The measurement is based on data collected at the CMS experiment at $ \sqrt{s} $ = 13 TeV, corresponding to an integrated luminosity of 35.9 fb$^{−1}$. The observed significance of the signal is 3.9 standard deviations, where a significance of 5.2 standard deviations is expected in the standard model. These results are combined with published results by CMS at $ \sqrt{s} $ = 8 TeV, which leads to observed and expected respective significances of 4.7 and 5.5 standard deviations. From the 13 TeV data, a value is obtained for the signal strength of electroweak Zγjj production and bounds are given on quartic vector boson interactions in the framework of dimension-eight effective field theory operators.[graphic not available: see fulltext]

Thermal Degradation of Polymer Blends, Composites and Nanocomposites

Abstract: This chapter deals with a brief account of thermal degradation of polymer-based blends, composites and nanocomposites. Different synthesising, preparation and characterisation methods of thermal degradation of polymer-based blends, composites and nanocomposites are discussed. Finally the applications, new challenges and opportunities for these thermal degradation of polymer-based blends, composites and nanocomposites are discussed.