Showing papers in "International Journal of Life Cycle Assessment in 2005"

The ecoinvent Database: Overview and Methodological Framework (7 pp)

Abstract: This paper provides an overview on the content of the ecoinvent database and of selected metholodogical issues applied on the life cycle inventories implemented in the ecoinvent database. In the year 2000, several Swiss Federal Offices and research institutes of the ETH domain agreed to a joint effort to harmonise and update life cycle inventory (LCI) data for its use in life cycle assessment (LCA). With the ecoinvent data-base and its actual data v1.1, a consistent set of more than 2’500 product and service LCIs is now available. Nearly all process datasets are transparently documented on the level of unit process inputs and outputs. Methodological approaches have been applied consistently throughout the entire database content and thus guarantee for a coherent set of LCI data. This is particularly true for market and trade modelling (see, for example, electricity modelling), for the treatment of multi-out-put and of recycling processes, but also for the recording and reporting of elementary flows. The differentiation of diameter size for particulate matter emissions, for instance, allows for a more comprehensive impact assessment of human health effects. Data quality is quantitatively reported in terms of standard deviations of the amounts of input and output flows. In many cases qualitative indicators are reported additionally on the level of each individual input and output. The information sources used vary from extensive statistical works to individual (point) measurements or assumptions derived from process descriptions. However, all datasets passed the same quality control procedure and all information relevant and necessary to judge the suitability of a dataset in a certain context are provided in the database. Data documentation and exchange is based on the EcoSpold data format, which complies with the technical specification ISO/TS 14048. Free access to process information via the Internet helps the user to judge the appropriateness of a dataset. The existence of the ecoinvent database proves that it is possible and feasible to build up a large interlinked system of LCI unit processes. The project work proved to be demanding in terms of co-ordination efforts required and consent identification. One main characteristic of the database is its transparency in reporting to enable individual assessment of data appropriateness and to support the plurality in methodological approaches. Further work on the ecoinvent database may comprise work on the database content (new or more detailed data-sets covering existing or new economic sectors), LCI (modelling) methodology, the structure and features of the data-base system (e.g. extension of Monte Carlo simulation to the impact assessment phase) or improvements in eco-invent data supply and data query. Furthermore, the deepening and building up of international co-operations in LCI data collection and supply is in the focus of future activities.

Environmental Evaluation of Different Treatment Processes for Sludge from Urban Wastewater Treatments: Anaerobic Digestion versus Thermal Processes (10 pp)

Abstract: Huge amounts of sewage sludge, that need to be handled, are generated all around the world from wastewater treatment plants and its management in an economically and environmentally acceptable way has become a matter of increasing importance during the last few years. In this paper, we make use of Life Cycle Assessment (LCA) to compare biological and thermal processes, that is to say, anaerobic digestion versus pyrolysis and incineration. This paper will complete the analysis performed in a wastewater treatment plant, where sludge post-treatment was identified as one of the main contributors to the environmental impact on the global system. LCA is a tool for evaluating the environmental performance of goods as well as processes or services (collectively termed products). ISO 14040 defines LCA as a compilation and evaluation of the inputs, outputs and the potential environmental impacts of a system throughout its life cycle: from the production of raw materials to the disposal of the waste generated. In this study, data relating to the actual scenario from an existent wastewater treatment plant were considered. Both bibliographical and real data from existing facilities were used for the thermal processes proposed. The Centre of Environmental Science (CML) of Leiden University's methodology was chosen to quantify the potential environmental impacts associated with the different scenarios under study. The software SimaPro 5.1 was used and CML factors (updated in 2002) were chosen for characterisation and normalisation stages. In a previous study, sewage sludge was found to be a critical point in the environmental performance of a wastewater treatment plant, so different alternatives have been tackled here. Anaerobic digestion followed by land application of pasty sludge comprises both energy recovery and nutrient recovery. Other thermal processes, such as incineration or pyrolysis, allow energy recovery (both electrical and thermal) and, although nutrients are lost, new co-products are produced (tar and char at pyrolysis). Here, the most adverse case (that is to say, the total amount of heavy metals is supposed to be released from the sludge and reach the environment) was applied to consider the most negative impact due to sludge spreading in agricultural soils; so more research is required in order to establish the precise amount of heavy metals that is effectively uptaken by the plants and crops as well as the amount that is transferred to another phase as a leachate. Thermal processes are presented here as a good option to recover energy from the sludge; although the value of nutrients is lost. Tar and char, co-products from pyrolysis, are good examples that were evaluated here, recycling of bottom ashes from sludge incineration or manufacture of ceramic materials from sludge are other options to be studied in the near future. During the last few years, several opinions have been declared in favour of land application, incineration or pyrolysis, but many voices have also spoken out against each one. To obtain general conclusions for an overall comparison of different post-treatment of urban wastewater sludge is not easy as there are many contradictory aspects. The most effective utilisation of sewage sludge implies both energy and material re-use, but this is not always possible. Nevertheless, we think that land application of digested sludge is an acceptable option, probably not the best but at least a good one, for sludge treatment as long as efforts are focused on the minimisation of heavy metal content in the final cake.

Life Cycle Inventories of Transport Services: Background Data for Freight Transport (10 pp)

Abstract: Background, Goal and Scope The ecoinvent database is a reference work for life cycle inventory data covering the areas of energy, building materials, metals, chemicals, paper and cardboard, forestry, agriculture, detergents, transport services and waste treatment. Generic inventories are available for freight and passenger transport including air, rail, road, and water transport. The goal of freight transport modelling is to provide background data for transport services, which occur between nearly any two process steps of a product system. This paper presents and discusses the model structure, basic assumptions and results for selected freight transport services.

Life Cycle Assessment for Emerging Technologies: Case Studies for Photovoltaic and Wind Power (11 pp)

Abstract: Goal, Scope and Background This paper describes the modelling of two emerging electricity systems based on renewable energy: photovoltaic (PV) and wind power. The paper shows the approach used in the ecoinvent database for multi-output processes.

Environmental Systems Analysis of Pig Production - The Impact of Feed Choice (12 pp)

Abstract: The purpose of this environmental system analysis was to investigate the impact of feed choice in three pig production scenarios using substance flow models complemented by life cycle assessment methodology. The function of the system studied was to grow piglets of 29 kg to finished pigs of 115 kg. Three alternative scenarios of protein supply were designed, one based on imported soybean meal (scenario SOY); one based on locally grown peas and rapeseed cake (scenario PEA) and one based on Swedish peas and rapeseed meal complemented by synthetic amino acids (scenario SAA). The environmental impact of both feed production as such and the subsequent environmental impact of the feed in the pig production sub-system were analysed. The analysed feed ingredients were barley, wheat, peas, rapeseed meal, rapeseed cake, soybean meal and synthetic amino acids. The crude protein level of the feed affected the nitrogen content in the manure, which in turn affected nitrogen emissions throughout the system and the fertilising value of the manure, ultimately affecting the need for mineral fertiliser application for feed production. The results showed that feed production contributed more than animal husbandry to the environmental burden of the system for the impact categories energy use, global warming potential and eutrophication, whereas the opposite situation was the case for acidification. The environmental impacts of scenarios SOY, PEA and SAA were 6.8, 5.3 and 6.3 MJ/kg pig growth; 1.5, 1.3 and 1.4 kg CO2-eq/kg pig growth; 0.55, 0.55 and 0.45 kg O2-eq/kg pig growth; and 24, 25 and 20 g SO2-eq/kg pig growth, respectively. The results suggested that scenario SAA was environmentally preferable, and that the reason for this was a low crude protein level of the feed and exclusion of soybean meal from the feed. Feed choice had an impact on the environmental performance of pig meat production, not only via the features of the feed as fed to the pigs, such as the crude protein content, but also via the raw materials used, since the environmental impact from the production of these differs and since feed production had a large impact on the system as a whole.

A Consistent Framework for Assessing the Impacts from Resource Use - A focus on resource functionality (8 pp)

Abstract: The quantification of resource depletion in Life Cycle Assessment has been the topic of much debate; to date no definitive approach for quantifying effects in this impact category has been developed. In this paper we argue that the main reason for this extensive debate is because all methods for quantifying resource depletion impacts have focussed on resource extraction. Aim and Scope. To further the state of the debate we present a general framework for assessing the impacts of resource use across the entire suite of biotic and abiotic resources. The main aim of this framework is to define the necessary and sufficient set of information required to quantify the effects of resources use. logy. Our method is based on a generic concept of the quality state of resource inputs and outputs to and from a production system. Using this approach we show that it is not the extraction of materials which is of concern, but rather the dissipative use and disposal of materials. Using this as a point of departure we develop and define two key variables for use in the modelling of impacts of resource use, namely the ultimate quality limit, which is related to the functionality of the material, and backup technology. Existing methodologies for determining the effects of resource depletion are discussed in the context of this framework. We demonstrate the ability of the general framework to describe impacts related to all resource categories: metallic and non-metallic minerals, energy minerals, water, soil, and biotic resources (wild or domesticated plants and animals). focus on suggestions for a functionality measure for each of these categories; and how best the two modelling variables derived can be determined.

Uncertainty Analysis in Life Cycle Assessment (LCA): Case Study on Plant - Protection Products and Implications for Decision Making (3 pp)

Abstract: Goal, Scope, and Background Uncertainty analysis in LCA is important for sound decision support. Nevertheless, the actual influence of uncertainty on decision making in specific LCA case-studies has only been little studied so far. Therefore, we assessed the uncertainty in an LCA comparing two plant-protection products.

Life cycle assessment study of biopolymers (polyhydroxyalkanoates) derived from no-tilled corn.

Abstract: This study attempts to estimate the environmental performance of Polyhydroxyalkanoates (PHA), from agricultural production through the PHA fermentation and recovery process – “cradle to gate”. Two types of PHA production systems are investigated: corn grain based PHA and corn grain and corn stover based PHA. Corn cultivation data are taken from 14 counties in the Corn Belt states of the United States – Illinois, Indiana, Iowa, Michigan, Minnesota, Ohio, and Wisconsin. The environmental burdens associated with the corn wet milling process, in which dextrose, corn oil, corn gluten meal and corn gluten feed are produced, are allocated to dextrose and its coproducts by the system expansion approach. Greenhouse gases include carbon taken up by soil, nitrous oxide (N2O) released from soil during corn cultivation, carbon contents in biobased products as well as carbon dioxide, methane and nitrous oxide released from industrial processing. The soil carbon and nitrogen dynamics in corn cultivation are predicted by an agro–ecosystem model, the DAYCENT model. The environmental performance of the PHA production system is compared to that of a conventional polymer fulfilling an equivalent function. The environmental performance is addressed as nonrenewable energy and selected potential environmental impacts including global warming, photochemical smog, acidification, and eutrophication. The characterization factors are adapted from the TRACI model (Tools for the Reduction and Assessment of Chemical and Other Environmental Impacts) developed by the United States Environmental Protection Agency. Global warming associated with corn grain based PHA is 1.6–4.1 kg-CO2 eq. kg–1. The primary contributing process to most environmental impacts except for photochemical smog and eutrophication is the PHA fermentation and recovery process. For photochemical smog and eutrophication, the primary contributing process is corn cultivation due to nitrogen related burdens from soil. The trend of PHA fermentation development shows that the PHA fermentation technology is still immature and continues to improve, thereby also decreasing the environmental impacts. PHA produced in an integrated system, in which corn stover is harvested and used as raw material for PHA along with corn grain, offers global warming credits (negative greenhouse gas emissions), ranging from –0.28 to –1.9 kg-CO2 eq. kg–1, depending on the PHA fermentation technologies employed and significantly reduces the environmental impacts compared to corn based PHA. The significant reductions from the integrated system are due to 1) less environmental impacts in corn cultivation and wet milling, and 2) exporting surplus energy from lignin–rich residues in corn stover process. Under the current PHA fermentation technology, corn grain based PHA does not provide an environmental advantage over polystyrene. Corn grain based PHA produced by the near future PHA fermentation technology would be more favorable than polystyrene in terms of nonrenewable energy and global warming due to improvement in the PHA fermentation and recovery process. However, corn grain based PHA produced in even the near future technology does not provide better profiles for other environmental impacts (i.e., photochemical smog, acidification and eutrophication) than polystyrene. One of the primary reasons for high impacts of PHA in photochemical smog, acidification and eutrophication is the environmental burdens associated with corn cultivation. Thus other approaches to reduce these burdens in the agricultural process (e.g., use of buffer strips, etc.) are necessary to achieve better profiles for photochemical smog, acidification and eutrophication associated with corn cultivation. PHA produced in the integrated system is more favorable than polystyrene in terms of most environmental impacts considered here except for eutrophication.

Life Cycle Assessment of Water Production Technologies - Part 1: Life Cycle Assessment of Different Commercial Desalination Technologies (MSF, MED, RO) (9 pp)

Abstract: - Preamble. This series of two papers analyses and compares the environmental loads of different water production technologies in order to establish, in a global, rigorous and objective way, the less aggressive technology for the environment with the present state of the art of the technology. Further, it is also presented an estimation of the potential environmental loads that the considered technologies could provoke in future, taking into account the most suitable evolution of the technology.

Life Cycle Inventories of Metals and Methodological Aspects of Inventorying Material Resources in ecoinvent (7 pp)

Abstract: Goal, Scope and Background The ecoinvent database provides harmonised generic life cycle inventories for metal production and processing. They can be used as background data for different LCA applications. The goal of this paper is to provide an overview of the metals inventoried in ecoinvent. Beside, some methodological background information is given. The focus lies on a new methodology developed to inventorying joint resources. The implementation is shown in a case study of the production of primary copper on a global average. The respective process is assessed with Eco-indicator 99 (H,A) to identify dominant impacts within the production chain.

Establishing Life Cycle Inventories of Chemicals Based on Differing Data Availability (9 pp)

Abstract: In contrast to inventory data of energy and transport processes, public inventory data of chemicals are rather scarce. Chemicals are important to consider in LCA, because they are used in the production of many, if not all, products. Moreover, they may cause considerable environmental impacts. For these reasons, it was one goal of the new ecoinvent database to provide LCI data on chemicals. In this paper, the methods and procedures used for establishing LCIs of chemicals in ecoinvent are presented. Three different approaches are suggested for situations of differing data availability. First, in the case of good data availability, the general quality guidelines of ecoinvent can be followed. Second, a procedure is proposed for the translation of aggregated inventory data (cumulative LCI results) from industry into the ecoinvent format. This approach was used, if adequate unit process data was not available. Third, a procedure is put forward for estimating inventory data using stoichiometric equations from technical literature as a main information source. This latter method was used if no other information was available. The application of each of the three procedures is illustrated with the help of a case study. When sufficient information is available to follow the general guidelines of ecoinvent, the resulting dataset is characterized by a high degree of detail, and it is thus of high quality. For chemicals, however, the application of the standard procedure is possible in only a few cases. When using industrial data, the main drawback is the fact that those data are often available only as aggregated data, thus being out of tune with the quality guidelines of ecoinvent and its main aim, the harmonization of LCI data. As a third approach, the use of the stoichiometric reaction equation is used for the compilation of LCI datasets of chemicals. This approach represents an alternative to neglecting chemicals completely, but it contains a high risk to not consider important aspects of the life cycle of the respective substance. Further work in the area of chemicals should focus on an improvement of datasets, so far established by either of the two estimation procedures (APME method; estimation based on technical literature) described. Besides the improvement of already established inventories, the compilation of further harmonized inventories of specific types of chemicals (e.g. solvents) or of chemicals for new industrial sectors (e.g. electronics industry) are in discussion.

The Ecology of Scale: Assessment of Regional Energy Turnover and Comparison with Global Food (5 pp)

Abstract: Obviously, people assume that the regional production and distribution of food requires less energy turnover, compared with global transports of food. Politicians claim the term “regionality”, maintaining that regionality is a medicine against wasting so much energy for the global food distribution. Additionally the energy turnover is causing pollution. But remarkably, there is a lack of empirical data to support this idea. At the same time, nobody really requires regional origin for non-food items, e.g. for bicycles, dishwashers, furniture or cars etc. The public mainstream asks for regional origin merely for food. Hence, the first scientific issue worked out in this paper is how the energy turnover of comparable food items can be measured, regarding the lifecycle of food in total. That means to investigate the partial systems of crop or breed, of food production, of packaging including transport and distribution up to the point of sale. Secondly, it has to be checked, if the assumed coincidence of low energy turnover and regional origin can be verified. The specific energy turnover, calculated in the unit [kWh per kg] or [kWh per l] of food, is investigated by comparing regional with global process chains for different food items. Two examples of food – fruit juices and lamb meat – are researched, by personal investigation worldwide. Firstly, fruit juices of high grade quality from Brazil, from European origin and from local German farmers are compared, in terms of energy. Secondly, a comparison of lamb meat from New Zealand and lamb meat from local German farmers is conducted. Lamb meat has been investigated, because it is shipped around the world as frozen natural food, not concentrated like juices. In addition, the business size of the food producers is researched for both examples. As a part of LCA the energy turnover of each process step from the very beginning up to the point of sale is investigated. These primary results are the basic empirical data, in order to allocate the energy turnover at the food items as functional units. The results of regional, European-continental and of global process chains are compared. In addition, the issue is investigated, whether the specific energy turnover depends upon the business size. Surprisingly, the data in both cases demonstrate a strong degressive relation of the specific energy turnover and the business size. Here it is not important, if the business is regional or not. Merely the efficiency and logistics of the production and the operations determine the specific energy turnover. These findings seem closely connected with the business size, because small companies are not able to invest in energy recovering and saving technology. The regional juices business is worsened by the huge number of smallsized transports of the crop and the nearly bottle-wise distribution. Regarding lamb meat we once more find the disadvantages of comparably small farms again. In addition, the German farmers need daily shepherds, fences by night, stables and usually additional feed during the wintertime. All these efforts are not necessary in New Zealand, where the climatic conditions and the open countryside with low population allow rather easy and low energy breeding of lamb. The coincidence of economic and ecological facts is obvious. As a matter of fact, in economics there is a strong degressive relation between the production costs and the number of produced items. This relation is very well known as “Economy of Scale.” Our findings lead to similar conclusions, in terms of ecology. That means, the production ecology depends on the number of produced items. Additionally, our results demonstrate a minimum business size, so that we can claim an “Ecology of Scale” as well. However, on the other hand, the reported data and the conclusions are valid for the investigated food items – fruit juices and lamb meat – only. Nevertheless, one conclusion is already evident: The most popular claims for regional food production and distribution instead of global process chains are not generally valid. Small farmers basically need much more energy to produce and distribute their products, compared with bigger units. Both food items demonstrate clearly, that the ecological quality is mainly influenced by the operational efficiency and not by the marketing distance itself. Much more detailed data of all the investigated operational units, processing fruit juices and lamb meat, have been published (Fleissner 2001). As a further example, we investigate wine from different countries as a further example. Different from fruit juices, which can be shipped as a concentrate, and different from lamb meat, which is shipped as frozen food, wine of high grade quality is always bottled close to the place of origin. That means, that not only the food, but also the heavy weight packaging is transported around the world. So, we are very curious about the results, which we expect for 2004.

Life Cycle Assessment of Water Production Technologies - Part 2: Reverse Osmosis Desalination versus the Ebro River Water Transfer (9 pp)

Abstract: Preamble. This series of two papers analyses and compares the environmental loads of different water production technologies in order to establish, in a global, rigorous and objective way, the less aggressive technology for the environment with the present state of the art of technology. Further, an estimation of the potential environmental loads that the considered technologies could provoke in future is also presented, taking into account the most suitable evolution of the technology. Part 1 presents the assessment of most commercial desalination technologies which are spread worldwide: Reverse Osmosis, Multi Effect Desalination and Multi Stage Flash. Part 2 presents the comparative LCA analysis of a big hydraulic infrastructure, as is to be found in the Ebro River Water Transfer project, with respect to desalination. Intention, Goal and Background. In this paper some relevant results of a research work are presented, the main aim of which consists of performing the environmental assessment of different water production technologies in order to establish, in a global, rigorous and objective way, the less aggressive technology for the environment for supplying potable water to the end users. The scope of this paper is mostly oriented to the comparative Life Cycle Assessment of different water production technologies instead of presenting new advancements in the LCA methodology. Based on the results obtained in Part 1 (LCA of most widespread commercial desalination technologies), the particular case of a big hydraulic project, which is the Ebro River Water Transfer (ERWT) considered in the Spanish National Hydrologic Plan, versus the production by desalination of the same amount of water to be diverted, is compared in Part 2. The assessment technique is the Life Cycle Analysis (LCA), which includes the entire life cycle of each technology, encompassing: extraction and processing raw materials, manufacturing, transportation and distribution, operation and final waste disposal. and Main Features. The software SimaPro 5.0, developed by Dutch PRe Consultants, has been used as the analysis tool, because it is a well known, internationally accepted and validated tool. Different evaluation methods have been applied in the LCA evaluation: CML 2 baseline 2000, Eco-Points 97 and Eco-Indicator 99. Data used in the inventory analysis of this Part 2 come from: a) desalination: data obtained for existing plants in operation; b) ERWT: Project approved in the Spanish National Hydrologic Plan and its Environmental Impact Evaluation and; c) data bases implemented in the SimaPro software – BUWAL 250, ETH-ESU 96, IDEMAT 2001. Different scenarios have been analyzed in both parts in order to estimate not only the potential of reduction of the provoked environmental loads with the present state of the art of technology, but also the most likely future trend of technological evolution. In Part 1, different energy production models and the integration of desalination with other productive processes are studied, while the effect of the most likely technological evolution in the midterm, and the estimation of the environmental loads to the water transfer during drought periods are considered in Part 2. As proven in Part 1, RO is a less aggressive desalination technology for the environment. Its aggression is one order of magnitude lower than that of the thermal processes, MSF and MED. The main contribution to the global environmental impact of RO comes from the operation, while the other phases, construction and disposal, are almost negligible when compared to it. In the case of the ERWT, the contribution of the operation phase is also the most important one, but the construction phase has an important contribution too. Its corresponding environmental load, with the present state of the art of technology, is slightly lower than that provoked by the RO desalination technology. However, the results obtained in the different scenarios analyzed show that the potential reduction of the environmental load in the case of the ERWT is significantly lower than that in the case of the RO. The effect of drought periods in the assessed environmental loads of the water transfer is not negligible, obtaining as a result an increasing environmental load per m3 of diverted water. The environmental load associated with RO, with the present state of the art of technology, is slightly higher than that provoked by the ERWT. However, considering the actual trend of technological improvement of the RO and the present trend of energy production technology in the address of reducing the fossil fuels\ contribution in the electricity production, the environmental load associated with RO in the short mid-term would be likely to be lower than that corresponding to the ERWT. Although desalination technologies are energy intensive and provoke an important environmental load, as already explained in Part 1, they present a high potential of reducing it. In respect to ERWT, the results indicate, when the infrastructure of ERWT is completed (by 2010–2012), that the LCA of RO will be likely to be against the water transfer. With the present technological evolution of water production technologies and from the results obtained in this paper, it seems, from an environmental viewpoint, that big hydraulic projects should be considered the last option because they are rigid and long-term infrastructures (several decades and even centuries of operation) that provoke important environmental loads with only a small margin for reducing them.

Scenario Modelling in Prospective LCA of Transport Systems. Application of Formative Scenario Analysis (11 pp)

Abstract: Tools and methods able to cope with uncertainties are essential for improving the credibility of Life Cycle Assessment (LCA) as a decision support tool. Previous approaches have focussed predominately upon data quality. and Scope. An epistemological approach is presented conceptualising uncertainties in a comparative, prospective, attributional LCA. This is achieved by considering a set of cornerstone scenarios representing future developments of an entire Life Cycle Inventory (LCI) product system. We illustrate the method using a comparison of future transport systems. Scenario modelling is organized by means of Formative Scenario Analysis (FSA), which provides a set of possible and consistent scenarios of those unit processes of an LCI product system which are time dependent and of environmental importance. Scenarios are combinations of levels of socio-economic or technological impact variables. Two core elements of FSA are applied in LCI scenario modelling. So-called impact matrix analysis is applied to determine the relationship between unit process specific socio-economic variables and technology variables. Consistency Analysis is employed to integrate unit process scenarios, based on pair-wise ratings of the consistency of the levels of socio-economic impact variables of all unit processes. Two software applications are employed which are available from the authors. The study reveals that each possible level or development of a technology variable is best conceived of as the impact of a specific socio-economic (sub-) scenario. This allows for linking possible future technology options within the socio-economic context of the future development of various background processes. In an illustrative case study, the climate change scores and nitrogen dioxide scores per seat kilometre for six technology options of regional rail transport are compared. Similar scores are calculated for a future bus alternative and an average Swiss car. The scenarios are deliberately chosen to maximise diversity. That is, they represent the entire range of future possible developments. Reference data and the unit process structure are taken from the Swiss LCA database 'ecoinvent 2000'. The results reveal that rail transport remains the best option for future regional transport in Switzerland. In all four assessed scenarios, four technology options of future rail transport perform considerably better than regional bus transport and car transport. and Recommendations. The case study demonstrates the general feasibility of the developed approach for attributional prospective LCA. It allows for a focussed and in-depth analysis of the future development of each single unit process, while still accounting for the requirements of the final scenario integration. Due to its high transparency, the procedure supports the validation of LCI results. Furthermore, it is well-suited for incorporation into participatory methods so as to increase their credibility. and Future Work. Thus far, the proposed approach is only applied on a vehicle level not taking into account alterations in demand and use of different transport modes. Future projects will enhance the approach by tackling uncertainties in technology assessment of future transport systems. For instance, environmental interventions involving future maglev technology will be assessed so as to account for induced traffic generated by the introduction of a new transport system.

Comparative LCAs for Curbside Recycling Versus Either Landfilling or Incineration with Energy Recovery (12 pp)

Abstract: This article describes two projects conducted recently by Sound Resource Management (SRMG) – one for the San Luis Obispo County Integrated Waste Management Authority (SLO IWMA) and the other for the Washington State Department of Ecology (WA Ecology). For both projects we used life cycle assessment (LCA) techniques to evaluate the environmental burdens associated with collection and management of municipal solid waste. Both projects compared environmental burdens from curbside collection for recycling, processing, and market shipment of recyclable materials picked up from households and/or businesses against environmental burdens from curbside collection and disposal of mixed solid waste. logy. The SLO IWMA project compared curbside recycling for households and businesses against curbside collection of mixed refuse for deposition in a landfill where landfill gas is collected and used for energy generation. The WA Ecology project compared residential curbside recycling in three regions of Washington State against the collection and deposition of those same materials in landfills where landfill gas is collected and flared. In the fourth Washington region (the urban east encompassing Spokane) the WA Ecology project compared curbside recycling against collection and deposition in a wasteto- energy (WTE) combustion facility used to generate electricity for sale on the regional energy grid. During the time period covered by the SLO study, households and businesses used either one or two containers, depending on the collection company, to separate and set out materials for recycling in San Luis Obispo County. During the time of the WA study households used either two or three containers for the residential curbside recycling programs surveyed for that study. Typically participants in collection programs requiring separation of materials into more than one container used one of the containers to separate at least glass bottles and jars from other recyclable materials. For the WA Ecology project SRMG used life cycle inventory (LCI) techniques to estimate atmospheric emissions of ten pollutants, waterborne emissions of seventeen pollutants, and emissions of industrial solid waste, as well as total energy consumption, associated with curbside recycling and disposal methods for managing municipal solid waste. Emissions estimates came from the Decision Support Tool (DST) developed for assessing the cost and environmental burdens of integrated solid waste management strategies by North Carolina State University (NCSU) in conjunction with Research Triangle Institute (RTI) and the US Environmental Protection Agency (US EPA)1. RTI used the DST to estimate environmental emissions during the life cycle of products. RTI provided those estimates to SRMG for analysis in the WA Ecology project2. For the SLO IWMA project SRMG also used LCI techniques and data from the Municipal Solid Waste Life- Cycle Database (Database), prepared by RTI with the support of US EPA during DST model development, to estimate environmental emissions from solid waste management practices3. Once we developed the LCI data for each project, SRMG then prepared a life cycle environmental impacts assessment of the environmental burdens associated with these emissions using the Environmental Problems approach discussed in the methodology section of this article. Finally, for the WA study we also developed estimates of the economic costs of certain environmental impacts in order to assess whether recycling was cost effective from a societal point of view. Recycling of newspaper, cardboard, mixed paper, glass bottles and jars, aluminum cans, tin-plated steel cans, plastic bottles, and other conventionally recoverable materials found in household and business municipal solid wastes consumes less energy and imposes lower environmental burdens than disposal of solid waste materials via landfilling or incineration, even after accounting for energy that may be recovered from waste materials at either type disposal facility. This result holds for a variety of environmental impacts, including global warming, acidification, eutrophication, disability adjusted life year (DALY) losses from emission of criteria air pollutants, human toxicity and ecological toxicity. The basic reason for this conclusion is that energy conservation and pollution prevention engendered by using recycled rather than virgin materials as feedstocks for manufacturing new products tends to be an order of magnitude greater than the additional energy and environmental burdens imposed by curbside collection trucks, recycled material processing facilities, and transportation of processed recyclables to end-use markets. Furthermore, the energy grid offsets and associated reductions in environmental burdens yielded by generation of energy from landfill gas or from waste combustion are substantially smaller then the upstream energy and pollution offsets attained by manufacturing products with processed recyclables, even after accounting for energy usage and pollutant emissions during collection, processing and transportation to end-use markets for recycled materials. The analysis that leads to this conclusion included a direct comparison of the collection for recycling versus collection for disposal of the same quantity and composition of materials handled through existing curbside recycling programs in Washington State. This comparison provides a better approximation to marginal energy usage and environmental burdens of recycling versus disposal for recyclable materials in solid waste than does a comparison of the energy and environmental impacts of recycling versus management methods for handling typical mixed refuse, where that refuse includes organics and non-recyclables in addition to whatever recyclable materials may remain in the garbage. Finally, the analysis also suggests that, under reasonable assumptions regarding the economic cost of impacts from pollutant emissions, the societal benefits of recycling outweigh its costs.

Modelling Representative Life Cycle Inventories for Swiss Arable Crops (9 pp)

Abstract: Life cycle inventories (LCIs) of agricultural products, infrastructure, inputs and processes are required to optimise food supply chains. In the past, the use of LCA was hindered by the limited availability of databases with LCIs for such agricultural inputs, processes and products in combination with LCIs of other major economic sectors. The ecoinvent database covers this need for the Swiss, and to an extent, the European context. A suitable approach had to be outlined for defining representative datasets for products from arable crops, since there was no comprehensive survey of agricultural production. No single data source was available for defining representative datasets for arable crops. It was therefore decided to define model crops on the basis of a variety of sources in collaboration with experts on the crops in question. The datasets were validated by experts and by comparison with literature. Field emissions were calculated using a set of models taking into account situation-specific parameters. Data defined by this procedure are more generally usable, but their definition is also more laborious. Selected results (inventories and impact assessment) are presented for infrastructure (buildings, machinery), work processes, fertilisers, pesticides, seed and arable crop products. Infrastructure has a higher share of environmental impacts than in typical industrial processes, often due to low utilisation rates. Energy use is dominated by mechanisation, the use of mineral fertilisers (particularly nitrogen) and grain drying. Eutrophication is caused mainly by nitrogen compounds. In general, field emissions are of decisive importance for many environmental impacts. The ecoinvent database provides representative agricultural data for the Swiss, and to an extent, the European context. It also provides the meta-information necessary for deciding whether a dataset is suitable for the purpose of a particular LCA study. To further improve the representativeness of the datasets, an environmental farm monitoring network is required.

Life Cycle Inventories for the Nuclear and Natural Gas Energy Systems, and Examples of Uncertainty Analysis (14 pp)

Abstract: tory data should reconsider production and transport from Rus- sia, as it is a major producer and exporter to Europe. The calculated ranges of uncertainty factors in ecoinvent pro- vide useful information but they are more indications of uncer- tainties rather than strict 95% intervals, and should therefore be applied carefully. Abstract Goal, Scope and Background. The energy systems included in the ecoinvent database v1.1 describe the situation around year 2000 of Swiss and Western European power plants and boilers with the associated energy chains. The addressed nuclear sys- tems concern Light Water Reactors (LWR) with mix of open and closed fuel cycles. The system model 'Natural Gas' describes production, distribution, and combustion of natural gas. Methods. Comprehensive life cycle inventories of the energy sys- tems were established and cumulative results calculated within the ecoinvent framework. Swiss conditions for the nuclear cycle were extrapolated to major nuclear countries. Long-term radon emissions from uranium mill tailings have been estimated with a simplified model. Average natural gas power plants were ana- lysed for different countries considering specific import/export of the gas, with seven production regions separately assessed. Uncertainties have been estimated quantitatively. Results and Discussion. Different radioactive emission species and wastes are produced from different steps of the nuclear cy- cle. Emissions of greenhouse gases from the nuclear cycle are mostly from the upstream chain, and the total is small and de- creasing with increasing share of centrifuge enrichment. The results for natural gas show the importance of transport and low pressure distribution network for the methane emissions, whereas energy is mostly invested for production and long-dis- tance pipeline transportation. Because of significant differences in power plant efficiencies and gas supply, country specific av- erages differ greatly. Conclusion. The inventory describes average worldwide supply of nuclear fuel and average nuclear reactors in Western Europe. Although the model for nuclear waste management was extrapo- lated from Swiss conditions, the ranges obtained for cumulative results can represent the average in Europe. Emissions per kWh electricity are distributed very differently over the natural gas chain for different species. Modern combined cycle plants show better performance for several burdens like cumulative green- house gas emissions compared to average plants. Recommendation and Perspective. Comparison of country-spe- cific LWRs or LWR types on the basis of these results is not recommended. Specific issues on different strategies for the nu- clear fuel cycle or location-specific characteristics would require extension of analysis. Results of the gas chain should not be directly applied to areas other than those modelled because emission factors and energy requirements may differ significantly. A future update of inven-

Assessing the Environmental-Hazard Potential for Life Cycle Assessment, Eco-Efficiency and SEEbalance (8 pp)

Abstract: BASF has developed the eco-efficiency analysis tool to address not only strategic issues but also issues posed by the marketplace, politics and research. The goal was to develop a tool for supporting decision-making processes, which is useful for many of applications in the Chemical and other industries. A part of the eco-efficiency analysis involves the evaluation of the toxicity and the eco-toxicity potential. Many life cycle analyses do not include an assessment of the toxicity potential nor the eco-toxicity potential. However, in order to arrive at a comprehensive assessment of products and processes, it is often the eco-toxicity potential, which constitutes an important factor with regard to the evaluation of sustainability. The cradle-to-grave approach is also important for this calculation and will be done based on a database that will be discussed also in this paper. The method used for the determination of the eco-toxicity potential follows the basic rules of the European Union Risk Ranking System (EURAM). The other criteria of the ecological fingerprint are combined with the economical results in the eco-efficiency portfolio. The results of the studies are shown in a simple diagram, the eco-efficiency portfolio. Therefore ecological data are summarized in a special manner as described previously. It has been shown that the weighting factors, which are used in our method, have a negligible impact on the results. In most cases, the input data have the dominant impact on the results of the study. The eco-toxicity assessment will be a part of the ecological calculation. Because of the cradle-to-grave approach, substances of the whole life cycle can be identified that might have a toxic impact to the environment. The results can be used for optimization of the process. The new calculation model allows the assessment of eco-toxicological substances in an appropriate and easy way. In most of the cases the data from a European safety data sheet are sufficient for the calculation. The normalized data can be incorporated very easily in the ecological fingerprint and in the drawing of the eco-efficiency portfolio. LCA in combination with the evaluation of the eco-toxicity potential will for reasons of optimizing for least impact become more important in certain cases. Especially in those systems where water emissions are likely, the use of the evaluation system in the eco-efficiency analysis is recommended. This new methodology allows the calculation of eco-toxicity potentials in a short time with a small set of input information. The analytical eco-efficiency tool helps in implementing more sustainable processes and products in the future.

Life Cycle Inventory Information of the United States Electricity System (11/17 pp)

Abstract: This study estimates the life cycle inventory (LCI) of the electricity system in the United States, including the 10 NERC (North American Electric Reliability Council) regions, Alaska, Hawaii, off-grid non-utility plants and the US average figures. The greenhouse gas emissions associated with the United States electricity system are also estimated. The fuel mix of the electricity system based on year 2000 data is used. The environmental burdens associated with raw material extraction, petroleum oil production and transportation for petroleum oil and natural gas to power plants are adopted from the DEAMTM LCA database. Coal transportation from a mining site to a power plant is specified with the data from the Energy Information Administration (EIA), which includes the mode of transportation as well as the distance traveled. The gate-to-gate environmental burdens associated with generating electricity from a fossil-fired power plant are obtained from the DEAMTM LCA database and the eGRID model developed by the United States Environmental Protection Agency. For nuclear power plants and hydroelectric power plants, the data from the DEAMTM LCA database are used. Selected environmental profiles of the US electricity system are presented in the paper version, while the on-line version presents the whole LCI data. The overall US electricity system in the year 2000 released about 2,654 Tg CO2 eq. of greenhouse gas emissions based on 100-year global warming potentials with 193 g CO2 eq. MJe–1 as an weighted average emission rate per one MJ electricity generated. Most greenhouse gases are released during combusting fossil fuels, accounting for 78–95% of the total. The greenhouse gas emissions released from coal-fired power plants account for 81% of the total greenhouse gas emissions associated with electricity generation, and natural gas-fired power plants contribute about 16% of the total. The most significant regions for the total greenhouse gas emissions are the SERC (Southeastern Electric Reliability Council) and ECAR (East Central Area Reliability Coordination Agreement) regions, which account for 22% and 21% of the total, respectively. A sensitivity analysis on the generation and consumption based calculations indicates that the environmental profiles of electricity based on consumption are more uncertain than those based on generation unless exchange data from the same year are available because the exchange rates (region to region import and export of electricity) vary significantly from year to year. Those who are interested in the LCI data of the US electricity system can refer to the on-line version. When the inventory data presented in the on-line version are used in a life cycle assessment study, the distribution and transmission losses should be taken into account, which is about 9.5% of the net generation [1]. The comprehensive technical information presented in this study can be used in estimating the environmental burdens when new information on the regional fuel mix or the upstream processes is available. The exchange rates presented in this study also offer useful information in consequential LCI studies.

Site-dependent Life-Cycle Impact Assessment in Sweden (5 pp)

Abstract: Goal, Scope and Background Although LCA is traditionally a site-independent tool, there is currently a trend towards making LCA more site-dependent if not site-specific. For Europe, site-dependent impact factors have been calculated on a country basis for acidification, terrestrial eutrophication and toxicological impacts. It is, however, an open question whether this is the optimum level for site-dependent factors. The aim of this paper is to develop site-dependent characterisation factors for different parts of Sweden for air emissions of NOx, SOx and particulates regarding ecosystem and human health impacts. Based on experiences from a case-study, the usability of the site-dependent factors for LCA are discussed, as well as the appropriate level of site-dependency for ecosystem and human health impacts.

Waste Treatment and Assessment of Long-Term Emissions (8pp)

Abstract: Conclusion. The disposal phase should by default be included in LCA studies. The use of a material not only necessitates its production, but also requires its disposal. The created inven- tories and user tools facilitate heeding the disposal phase with a similar level of detail as production processes. The risk of LCA-based decisions shifting burdens from the production or use phase to the disposal phase because of data gaps can there- fore be diminished. Recommendation and Perspective. Future improvements should include the modelling of metal ore refining waste (tailings) which is currently neglected in ecoinvent, but is likely to be relevant for metals production. The disposal technologies con- sidered here are those of developed Western countries. Dis- posal in other parts of the World can differ distinctly, for logis- tic, climatic and economic reasons. The cross-examination of landfill models to LCIA soil fate models could be advantageous. Currently only chemical elements, like copper, zinc, nitrogen etc. are heeded by the disposal models. A possible extension could be the modelling of the behaviour of chemical compounds, like dioxins or other hydrocarbons. Abstract Goal, Scope and Background. The disposal phase of a product's life cycle in LCA is often neglected or based on coarse indica- tors like 'kilogram waste'. The goal of report No. 13 of the ecoinvent project (Doka 2003) is to create detailed Life Cycle Inventories of waste disposal processes. The purpose of this paper is to give an overview of the models behind the waste disposal inventories in ecoinvent, to present exemplary results and to discuss the assessment of long-term emissions. This paper does not present a particular LCA study. Inventories are compiled for many different materials and various disposal technologies. Considered disposal technologies are municipal incineration and different landfill types, including sanitary landfills, hazardous waste incineration, waste deposits in deep salt mines, surface spreading of sludges, municipal wastewater treatment, and build- ing dismantling. The inventoried technologies are largely based on Swiss plants. Inventories can be used for assessment of the disposal of common, generic waste materials like paper, plas- tics, packaging etc. Inventories are also used within the ecoinvent database itself to inventory the disposal of specific wastes gen- erated during the production phase. Inventories relate as far as possible to the specific chemical composition of the waste mate- rial (waste-specific burdens). Certain expenditures are not re- lated to the waste composition and are inventoried with aver- age values (process-specific burdens). Methods. The disposal models are based on previous work, partly used in earlier versions of ecoinvent/ETH LCI data. Important improvements were the extension of the number of considered chemical elements to 41 throughout all disposal models and new landfill models based on field data. New inventories are compiled for waste deposits in deep salt mines and building ma- terial disposal. Along with the ecoinvent data and the reports, also Excel-based software tools were created, which allow ecoinvent members to calculate waste disposal inventories from arbitrary waste compositions. The modelling of long-term emis- sions from landfills is a crucial part in any waste disposal proc- ess. In ecoinvent long-term emissions are defined as emissions occurring 100 years after present. They are reported in separate emission categories. The landfill inventories include long-term emissions with a time horizon of 60'000 years after present. Results and Discussion. As in earlier studies, the landfills prove to be generally relevant disposal processes, as also incineration and wastewater treatment processes produce landfilled wastes. Heavy metals tend to concentrate in landfills and are washed out to a varying degree over time. Long-term emissions usually represent an important burden from landfills. Comparisons be- tween burdens from production of materials and the burdens from their disposal show that disposal has a certain relevance. 1 Motivation Waste disposal is a somewhat neglected part in life cycle inventories. For production and use phases elaborate data

Using Standard Statistics to Consider Uncertainty in Industry-Based Life Cycle Inventory Databases (7 pp)

Abstract: Goal, Scope and Background Decision-makers demand information about the range of possible outcomes of their actions. Therefore, for developing Life Cycle Assessment (LCA) as a decision-making tool, Life Cycle Inventory (LCI) databases should provide uncertainty information. Approaches for incorporating uncertainty should be selected properly contingent upon the characteristics of the LCI database. For example, in industry-based LCI databases where large amounts of up-to-date process data are collected, statistical methods might be useful for quantifying the uncertainties. However, in practice, there is still a lack of knowledge as to what statistical methods are most effective for obtaining the required parameters. Another concern from the industry's perspective is the confidentiality of the process data. The aim of this paper is to propose a procedure for incorporating uncertainty information with statistical methods in industry-based LCI databases, which at the same time preserves the confidentiality of individual data.

Numerical approaches to life cycle interpretation: the case of the Ecoinvent'96 database

Abstract: Goal, Scope and Background To strengthen the evaluative power of LCA, life cycle interpretation should be further developed. A previous contribution (Heijungs & Kleijn 2001) elaborated five examples of concrete methods within the subset of numerical approaches towards interpretation. These methods were: contribution analysis, perturbation analysis, uncertainty analysis, comparative analysis, and discernibility analysis. Developments in software have enabled the possibility to apply the five example methods to explore the much-used Ecoinvent”96 database.

Enhancing the application efficiency of life cycle assessment for industrial uses

Abstract: Sustainable development is an issue that is gaining more and more relevance in all areas of society, though specifically in industry. In order to move towards the goal of sustainability, life cycle thinking is an essential element. For the implementation of life cycle thinking in industry life cycle management (LCM) has been proposed as the general concept. However, the assessment of environmental impacts with the method of life cycle assessment, which is essentially the only tool available for this purpose, has been limited in industrial practice due to involved complexity and the resulting necessary effort and know-how. Therefore, this thesis proposed improved methods that enhance the application efficiency of LCA for industrial uses. After a short introduction in Chapter 1, new developments for the more efficient application of LCA for environmental assessments are presented in Chapter 2 – both for situations where pre-existing data are available and for studies, where no or very limited information of the involved unit processes and elementary flows exist. This concerns the modeling based on reusable elements as well as limiting system boundaries by recommended cut-offs. Specific and easy to apply recommendations for using cut-off rules are proposed. Chapter 3 explores another path, namely the usage of LCA models for life cycle costing. A consistent framework of the economic life cycle based assessment in sustainable development is proposed and tested. Essentially, one can conclude that the deployment of the systems approach and underlying model of LCA is extremely useful also for conducting economic analyses, while causing very little additional efforts. Chapter 4 elaborates case studies, one for an automotive component, and one for the service of waste water treatment. Detailed LCA results are presented and discussed, and the aforementioned methods in regards to a more efficient LCA "from scratch" and relating to life cycle costing are tested and demonstrated. The thesis concludes with some concise recommendations for future research and development activities in relation to a better usage of LCA and related life cycle approaches.

Representing statistical distributions for uncertain parameters in LCA. Relationships between mathematical forms, their representation in EcoSpold, and their representation in CMLCA

Abstract: Statistical information for LCA is increasingly becoming available in databases. At the same time, processing of statistical information is increasingly becoming easier by software for LCA. A practical problem is that there is no unique unambiguous representation for statistical distributions. Representations. This paper discusses the most frequently encountered statistical distributions, their representation in mathematical statistics, EcoSpold and CMLCA, and the relationships between these representations. The distributions. Four statistical distributions are discussed: uniform, triangular, normal and lognormal. Software and examples. An easy to use software tool is available for supporting the conversion steps. Its use is illustrated with a simple example. This paper shows which ambiguities exist for specifying statistical distributions, and which complications can arise when uncertainty information is transferred from a database to an LCA program. This calls for a more extensive standardization of the vocabulary and symbols to express such information. We invite suppliers of software and databases to provide their parameter representations in a clear and unambiguous way and hope that a future revision of the ISO/TS 14048 document will standardize representation and terminology for statistical information.

LCA of Ex-Situ Bioremediation of Diesel-Contaminated Soil (11 pp)

Abstract: DOI: http://dx.doi.org/10.1065/lca2004.09.180.12 Primary and secondary environmental impacts associated with bioremediation of diesel-contaminated sites were assessed using a retrospective life cycle assessment (LCA) as a function of the duration of treatment and the achievement of regulatory criteria. The case study was the remediation with biopiles of 8000 m3 of subsurface soil impacted with an average of 6145 mg of diesel fuel/kg soil during a two-year period. Two scenarios were compared; the construction of a single-use treatment facility on site or the use of a permanent treatment center that can accept 25000 m3 soil/year. Moreover, since bioremediation is never 100% efficient, different efficiency scenarios, including the transportation of partially treated soil to landfill were analyzed. The primary impact of residual soil contamination was determined by developing a specific characterization factor (ecotoxicity and human toxicity categories in the EDIP method) based on the toxic components of diesel. Secondary impacts were assessed with an LCA software. One major observation was the fact that the soil itself is responsible for an important fraction of the system's total impact, suggesting that it is beneficial to reach the highest level of remediation. The reutilization of the treatment facility is also an important issue in the overall environmental performance of the system. In the case of a single-use treatment center, the analysis showed that site preparation and site closure were the major contributing stages to the overall impact, mainly due to the asphalt paving and landfilling processes. Results indicated that off-site transport and the biotreatment process did not contribute notably to the level of environmental impact. The use of a permanent treatment center is preferred since it allows a significant decrease of the secondary impact. However, when soil had to be transported for a distance greater than 200 km from the site, global impacts increased significantly. Conclusion – Results from this study allowed identifying several process optimizations in order to improve the environmental performance of the biopile technology including: the achievement of low level of residual contaminants, the minimization of asphalt or the use of a permanent treatment center. LCA was found to be an efficient tool to manage contaminated soil in a sustainable way. However, because of the major contribution of residual soil contamination, additional spatial and temporal data should be collected and integrated in the substance characterization models.

ecoinvent Data v1.1 (2004): From heterogenous databases to unified and transparent LCI data

Abstract: © 2005 ecomed publishers (Verlagsgruppe Huthig Jehle Rehm GmbH), D-86899 Landsberg and Tokyo • Mumbai • Seoul • Melbourne • Paris Int J LCA 10 (1) 1–2 ( 2005) – Accepted October 18th, 2004 logical and reporting differences. Not surprising that first ideas for a harmonised Swiss national LCI database root back in in that period, namely in 1997. At that time, Konrad Hungerbuhler, who was then responsible for the ecoinvent database at the ETHZ, approached Swiss Federal Offices with the idea of bringing together Swiss LCI competences so as to create a national LCI database. From the first moment, he got support from Swiss Federal Offices. After intensive discussions, the pilot project started one year later, in June 1998, with the goal stated in the project description: