Journal ArticleDOI
193 nm Excimer laser photochemistry in cryogenic matrices: synthesis of N-methylmethyleneimine
TLDR
In this article, an excimer laser operating at 193 nm was coupled with the matrix isolation technique for the synthesis of chemical intermediates, which yielded CH 4 and H 2 CNCH 3 upon irradiation, likely by the photodetachment of a methyl group followed by hydrogen atom abstract within the matrix cage.About:
This article is published in Chemical Physics Letters.The article was published on 1987-10-09. It has received 7 citations till now. The article focuses on the topics: Excimer laser & Matrix isolation.read more
Citations
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Journal ArticleDOI
Electron diffraction study of thermal decomposition products of trimethylamine: molecular structure of CH3NCH2
TL;DR: In this paper, the zero-point average structure of trimethylamine (CH 3 ) was determined by a joint analysis of electron diffraction data and rotational constants, and then compared with ab initio calculations.
Journal ArticleDOI
Excimer-laser-induced oxidation of diborane: Formation and isolation of HBO, HB18O AND H3B3O3 in argon matrices
TL;DR: In this article, an excimer laser operating at 193 nm was used in conjunction with the matrix isolation technique to study the reaction of B2H6 with oxygen atoms, and the most intense fundamental of BH3 was tentatively identified at 1138 cm−1.
Journal ArticleDOI
Multiphoton ionization by excimer laser irradiation of cryogenic matrices: Formation of CCl+4 and related cations
Book ChapterDOI
Generation and Study of Inorganic Cations in Rare Gas Matrices by Electron Spin Resonance
TL;DR: A comprehensive treatment of electron spin resonance (ESR) results for inorganic cation radicals isolated in rare gas matrices is presented in this article, where the most recent method used to generate cations for rare gas trapping experiments is described, namely, direct ion trapping of plasma generated by pulsed laser bombardment.
Journal ArticleDOI
Spectroscopic Study on the Pyrolytic Products of Amines
Yoshiaki Hamada,Harutoshi Takeo +1 more
TL;DR: The use of light, particularly the advent of the laser in this century, added another tool for chemical reaction and the ease of regulation and superior selectivity of laser frequencies are advantages over the thermal reaction as discussed by the authors.
References
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Journal ArticleDOI
Photofragmentation infrared emission studies of vibrationally excited free radicals CH3 and CH2I
TL;DR: In this article, the photofragmentation dynamics of CH2I2 and CH3I at the excimer laser wavelengths of 248 and 308 nm were studied using time and wavelength-resolved infrared fluorescence techniques.
Journal ArticleDOI
Chemistry and thermodynamics of ruthenium and some of its inorganic compounds and aqueous species
Journal ArticleDOI
ArF laser photodissociation of NH3 at 193 nm: internal energy distributions in NH2 X̃2B1 and Ã2A1, and two-photon generatin of NH A 3Π and b 1Σ+
TL;DR: In this article, the A 2 A 1 state has a propensity for being formed in high K a rotational levels v 2 vibrational levels, with an average vibrational energy content of 1000 cm −1.
Related Papers (5)
Photoreversible hydrogen migration system in a solid argon matrix formed by the reaction of methyl fluoride with laser-ablated titanium atoms
Han-Gook Cho,Lester Andrews +1 more