Journal ArticleDOI
415. The alkaloids of Picralima Klaineana, pierre. Part II
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This article is published in Journal of The Chemical Society (resumed).The article was published on 1932-01-01. It has received 34 citations till now. The article focuses on the topics: Picralima.read more
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Cascade reactions: a driving force in akuammiline alkaloid total synthesis.
TL;DR: An overview of the rich history of the akuammiline alkaloids, including their isolation, structural features, biological activity, and proposed biosyntheses is provided, and several recently completed total syntheses are discussed in detail.
Journal ArticleDOI
Total Synthesis of the Monoterpenoid Indole Alkaloid (+/-)-Aspidophylline A
TL;DR: A 15-step synthesis of Aspidophylline from readily available starting materials is described in this article, where the key elements of the synthesis include an intramolecular oxidative coupling to create the tetracyclic furoindoline motif of the natural product and a [Ni(cod)(2)]-mediated cyclization to install its piperidine ring.
Journal ArticleDOI
Access to the akuammiline family of alkaloids: total synthesis of (+)-scholarisine A.
TL;DR: The planning and implementation of an enantioselective total synthesis of (+)-scholarisine A is presented and the development of a possible "retro-biosynthetic" approach to other members of the akuammiline alkaloid family is described.
Journal ArticleDOI
Total Synthesis of the Monoterpenoid Indole Alkaloid (±)‐Aspidophylline A
Mingxing Teng,Weiwei Zi,Dawei Ma +2 more
TL;DR: A 15-step synthesis of Aspidophylline A from conveniently available starting materials includes an intramolecular oxidative coupling to create the tetracyclic furoindoline motif of the natural product and a [Ni(cod)2 ]-mediated cyclization to install its piperidine ring.
Journal ArticleDOI
Total Synthesis of (+)-Scholarisine A
TL;DR: An effective total synthesis and assignment of the absolute configuration of the architecturally challenging compound (+)-scholarisine A has been achieved via a 20-step sequence.
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Total synthesis of Akuammiline alkaloid (-)-vincorine via intramolecular oxidative coupling.
Weiwei Zi,Weiqing Xie,Dawei Ma +2 more