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Journal ArticleDOI

A comparison of the electrode/electrolyte reaction at elevated temperatures for various Li-ion battery cathodes

TLDR
Differential scanning calorimetry (DSC) was used to compare the thermal stability of charged cathodes in 1-M LiPF 6 EC/DEC electrolyte as discussed by the authors.
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This article is published in Journal of Power Sources.The article was published on 2002-06-01. It has received 371 citations till now. The article focuses on the topics: Electrolyte & Differential scanning calorimetry.

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Citations
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Positive Electrode Materials for Li-Ion and Li-Batteries†

TL;DR: In this article, positive electrodes for Li-ion and lithium batteries have been under intense scrutiny since the advent of the Li ion cell in 1991, and a growing interest in developing Li−sulfur and Li−air batteries that have the potential for vastly increased capacity and energy density, which is needed to power large scale systems.
Journal ArticleDOI

High-energy cathode material for long-life and safe lithium batteries

TL;DR: The results suggest that the cathode material reported on could enable production of batteries that meet the demanding performance and safety requirements of plug-in hybrid electric vehicles.
Journal ArticleDOI

Safety mechanisms in lithium-ion batteries

TL;DR: In this paper, a review analyzes possible scenarios that trigger such hazards before proceeding to discuss safety mechanisms such as pressure release valves, one-shot fuses, reversible and irreversible positive temperature coefficient elements, shutdown separators, chemical shuttles, non-flammable electrolytes and coatings.
References
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Journal ArticleDOI

Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries

TL;DR: In this article, the authors showed that a reversible loss in capacity with increasing current density appears to be associated with a diffusion-limited transfer of lithium across the two-phase interface.
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Optimized LiFePO4 for Lithium Battery Cathodes

TL;DR: LiFePO 4 powders were synthesized under various conditions and the performance of the cathodes was evaluated using coin cells, the samples were characterized by X-ray diffraction, scanning electron microscope observations, Brunauer, Emmett, and Teller surface area measurements, particle-size distribution measurements, and Mossbauer spectroscopy.
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Layered Cathode Materials Li [ Ni x Li ( 1 / 3 − 2x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O 2 for Lithium-Ion Batteries

TL;DR: The structure, synthesis, and electrochemical behavior of layered for 5/12, and 1/2 are reported for the first time in this article, where the authors derive from or by substitution of and by while maintaining all the remaining Mn atoms in the 4+ oxidation state.
Journal ArticleDOI

Electroactivity of natural and synthetic triphylite

TL;DR: In this paper, the electrochemical behavior of three triphylite (LiFePO4) ores from different mining localities has been investigated, and the best results were obtained with carbon coatings coming from the decomposition of a modified polycyclic aromatic.
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Thermal stability of LixCoO2, LixNiO2 and λ-MnO2 and consequences for the safety of Li-ion cells

TL;DR: In this paper, the authors studied the thermal decomposition of Li-ion cells in inert gas and found that the nickel materials are least stable, the manganese compounds are most stable, and that the cobalt compounds show intermediate behaviour.
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