Journal ArticleDOI
A kinetic study of oxygen reduction reaction on La2NiO4 cathodes by means of impedance spectroscopy
TLDR
In this paper, the authors investigated the oxygen reduction reaction at the La 2 NiO 4+ δ /YSZ interface by impedance spectroscopy and found at least the presence of three processes involved in the reduction reaction.About:
This article is published in Journal of Electroanalytical Chemistry.The article was published on 2007-12-15. It has received 318 citations till now. The article focuses on the topics: Oxygen & Partial pressure.read more
Citations
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Journal ArticleDOI
Progress in understanding and development of Ba0.5Sr0.5Co0.8Fe0.2O3−δ-based cathodes for intermediate-temperature solid-oxide fuel cells: A review
Wei Zhou,Ran Ran,Zongping Shao +2 more
TL;DR: In this article, a review of the current research activities on BSCF-based cathodes for intermediate-temperature (IT)-SOFCs is presented and analyzed to provide some guidelines in the search for the new generation of cathode materials for IT-SOFC.
Journal ArticleDOI
Intermediate-temperature electrochemical performance of a polycrystalline PrBaCo2O5+δ cathode on samarium-doped ceria electrolyte
TL;DR: A site cation-ordered PrBaCo2O5+δ (PrBC) double perovskite oxide was synthesized and evaluated as the cathode of an intermediate-temperature solid-oxide fuel cell (IT-SOFC) on a samarium-doped ceria (SDC) electrolyte as mentioned in this paper.
Journal ArticleDOI
Advances in Cathode Materials for Solid Oxide Fuel Cells: Complex Oxides without Alkaline Earth Metal Elements
Yubo Chen,Wei Zhou,Dong Ding,Meilin Liu,Francesco Ciucci,Moses O. Tadé,Zongping Shao,Zongping Shao +7 more
TL;DR: In this paper, a comprehensive review of the latest advances in the development of SOFC cathodes is presented: complex oxides without alkaline earth metal elements (because these elements could be vulnerable to phase segregation and contaminant poisoning). Various strategies are discussed for enhancing ORR activity while minimizing the effect of contaminant on electrode durability.
Journal ArticleDOI
Evaluation of A-site cation-deficient (Ba0.5Sr0.5)1−xCo0.8Fe0.2O3−δ (x > 0) perovskite as a solid-oxide fuel cell cathode
TL;DR: A-site cation deficiency resulted in a steady increase in cathode polarization resistance, because impurities formed at the cathode/electrolyte interface, reducing the electronic conductivity.
Journal ArticleDOI
Evaluation of the La2Ni1-xCuxO4+δ system as SOFC cathode material with 8YSZ and LSGM as electrolytes
TL;DR: In this article, materials formulated as La 2 Ni 1−− x Cu x O 4 + δ (0,≤ x ǫ ≥ 1) have been synthesized to be evaluated as possible cathode materials in SOFCs.
References
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Journal ArticleDOI
Impedance of Solid Oxide Fuel Cell LSM/YSZ Composite Cathodes
TL;DR: In this article, a number of lanthanum strontium manganate/yttria-stabilized zirconia (LSM/YSZ) composite electrodes are investigated using impedance spectroscopy.
Journal ArticleDOI
Cathodic Polarization Phenomena of Perovskite Oxide Electrodes with Stabilized Zirconia
TL;DR: In this paper, the cathodic polarization of the electrodes sputtered on yttria stabilized zirconia electrolyte was studied at 800°C in air and the system showed high electrode activity for oxygen reduction.
Journal ArticleDOI
Oxygen diffusion and transport properties in non-stoichiometric Ln2 − xNiO4 + δ oxides
Emmanuelle Boehm,Jean-Marc Bassat,P. Dordor,Fabrice Mauvy,Jean-Claude Grenier,Philippe Stevens +5 more
TL;DR: In this paper, materials formulated with respect to their mixed ionic/electronic conducting properties have been prepared and characterized using various techniques using various types of materials, including materials formulated Ln 2−−− x −− y y y Ca x NiO 4+− δ (with (i ) x ǫ = 0 for Lnǫ, La, Pr, Nd, (ii) x  = 0 when y Â= 0 or yǫ≠ 0 for ln  for lnn  or y
Journal ArticleDOI
A comparative study of the Ruddlesden-Popper series, Lan+1NinO3n+1 (n = 1, 2 and 3), for solid-oxide fuel-cell cathode applications
TL;DR: In this article, a comparative investigation of the much-studied La 2 NiO 4+ δ ( n ǫ = 1) phase and the higher-order Ruddlesden-Popper phases, La n + 1 Ni n O 3 n +1 ( nǫ= 2 and 3), has been undertaken to determine their suitability as cathodes for intermediate-temperature solid-oxide fuel cells.
Journal ArticleDOI
Cathodic and Anodic Polarization Phenomena at Platinum Electrodes with Doped CeO2 as Electrolyte I . Steady‐State Overpotential
Da Yu Wang,A. S. Nowick +1 more
TL;DR: In this paper, a scanning electron microscope study of the electrode structure helps to understand the deterioration of electrical properties which occurs when samples are subjected to high temperatures and/or current densities.
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