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Journal ArticleDOI

A low-operating-temperature solid oxide fuel cell in hydrocarbon-Air mixtures

TLDR
The performance of a single-chamber solid oxide fuel cell was studied using a ceria-basedsolid electrolyte at temperatures below 773 kelvin, where the solid electrolyte functioned as a purely ionic conductor.
Abstract
The performance of a single-chamber solid oxide fuel cell was studied using a ceria-based solid electrolyte at temperatures below 773 kelvin. Electromotive forces of ∼900 millivolts were generated from the cell in a flowing mixture of ethane or propane and air, where the solid electrolyte functioned as a purely ionic conductor. The electrode-reaction resistance was negligibly small in the total internal resistances of the cell. The resulting peak power density reached 403 and 101 milliwatts per square centimeter at 773 and 623 kelvin, respectively.

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Citations
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Journal ArticleDOI

Materials for fuel-cell technologies

TL;DR: Recent progress in the search and development of innovative alternative materials in the development of fuel-cell stack is summarized.
Journal ArticleDOI

A high-performance cathode for the next generation of solid-oxide fuel cells

TL;DR: BSCF is presented as a new cathode material for reduced-temperature SOFC operation and demonstrated that BSCF is ideally suited to ‘single-chamber’ fuel-cell operation, where anode and cathode reactions take place within the same physical chamber.
Journal ArticleDOI

Oxygen vacancies in transition metal and rare earth oxides: Current state of understanding and remaining challenges

TL;DR: In this article, structural and electronic properties and energetic quantities related to the formation of oxygen defects at transition metal (TM) and rare earth (RE) oxide surfaces, neutral oxygen vacancies in particular, play a major role in a variety of technological applications.
Journal ArticleDOI

Readily processed protonic ceramic fuel cells with high performance at low temperatures

TL;DR: A proton-conduction cathode and simpler fabrication enable lower-temperature operation of methane-fueled ceramic fuel cells and develops a proton-, oxygen-ion–, and electron-hole–conducting PCFC-compatible cathode material that greatly improved oxygen reduction reaction kinetics at intermediate to low temperatures.
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Materials challenges toward proton-conducting oxide fuel cells: a critical review

TL;DR: This critical review provides a broad overview of the most recent progresses obtained tailoring the properties of proton-conducting oxides for fuel cell applications, analyzing and comparing the different strategies proposed to match high-proton conductivity with good chemical stability.
References
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Journal ArticleDOI

Direct oxidation of hydrocarbons in a solid-oxide fuel cell

TL;DR: The observation that a solid-oxide fuel cell can be operated on dry hydrocarbons, including liquid fuels, without reforming, suggests that this type of fuel cell could provide an alternative to hydrogen-based fuel-cell technologies.
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A direct-methane fuel cell with a ceria-based anode

TL;DR: In this paper, the authors reported the direct electrochemical oxidation of methane in solid oxide fuel cells that generate power densities upto 0.37 W cm−2 at 650°C.
Journal ArticleDOI

Selective oxidation of methane to synthesis gas using transition metal catalysts

TL;DR: In this article, it was shown that the partial oxidation of methane to synthesis gas can be carried out at temperatures of only ∼775 °C by using lanthanide ruthenium oxide catalysts.
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Doped Ceria as a Solid Oxide Electrolyte

TL;DR: In this paper, the conductivity of doped ceria with divalent or trivalent cations is investigated and compared to calcia-stabilized zirconia (CSZ), showing a higher conductivity, lower activation energy (0.76 eV), and absence of polarization effects to lower temperatures.
Journal ArticleDOI

Electrochemical Impedance Study of Electrode-Membrane Assemblies in PEM Fuel Cells: I. Electro-oxidation of H 2 and H 2 / CO Mixtures on Pt-Based Gas-Diffusion Electrodes

TL;DR: In this article, a characterization of the effects of interfacial kinetics in determining polarization losses in the presence of CO is performed by comparing impedance patterns obtained for cells of the type H{sub 2}/H{sub2} with H{ sub 2}/(H{Sub 2} + CO).
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