Journal ArticleDOI
A new 1-D energetic complex [Cu(2,3′-bpt)2·H2O]n: synthesis, structure, and catalytic thermal decomposition for ammonium perchlorate
TLDR
A new energetic complex, [Cu(2,3′-bpt)2·H2O]n (1) was synthesized and characterized by single-crystal X-ray diffraction, thermogravimetric analyses, elemental analysis, X-rays powder diffraction and IR spectroscopy.Abstract:
A new energetic complex, [Cu(2,3′-bpt)2·H2O]n (1) (2,3′-Hbpt = 3-(2-pyridyl)-5-(3′-pyridyl)1H-1,2,4-triazole), was synthesized and characterized by single-crystal X-ray diffraction, thermogravimetric analyses, elemental analysis, X-ray powder diffraction, and IR spectroscopy. The title complex belongs to the monoclinic system, space group P21/c. In the complex, one 2,3′-bpt− is a chelate binding to Cu(II) centers forming a Cu(2,3′-bpt)+ unit. Then the other 2,3′-bpt− adopts chelate/bridging tridentate mode linking adjacent Cu(2,3′-bpt)+ units to a zigzag chain along the (110) direction and a 1-D channel in the ac plane. Hydrogen-bond interactions link the channels into 2-D planes. The thermal decomposition of ammonium perchlorate (AP) with 1 was explored by differential scanning calorimetry from 323 to 773 K. AP is completely decomposed in a shorter time in the presence of 1, and the decomposition heat of the mixture is 1946 J g−1, significantly higher than pure AP. By Kissinger’s method, the ratio of Ea/...read more
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Catalytic Reactivity of Graphene Oxide Stabilized Transition Metal Complexes of Triaminoguanidine on Thermolysis of RDX
Wei He,Jia-Hao Guo,Cheng-Kai Cao,Xiao-Kang Liu,Jie-Yao Lv,Shuwen Chen,Peijin Liu,Qi-Long Yan +7 more
TL;DR: In this article, the catalytic reactivity of GO stabilized TAG-M (M = Cu, Co, Ni) energetic composites on thermolysis of 1,3,5-trinitro-1,3-5-triazinane (RDX) has been investigated by using DSC/TGA techniques.
Journal ArticleDOI
New energetic complexes as catalysts for ammonium perchlorate thermal decomposition
Guorong Lei,Ye Zhong,Yiqiang Xu,Fan Yang,Jiandong Bai,Zhimin Li,Jian-Guo Zhang,Tonglai Zhang +7 more
Journal ArticleDOI
A New Energetic Complex [Co(2,4,3-tpt)2(H2O)2]·2NO3: Synthesis, Structure, and Catalytic Thermal Decomposition for Ammonium Perchlorate
TL;DR: In this article, a 0D motif with a unit of [Co(2,4,3-tpt)2(H2O)2] was synthesized and characterized by single-crystal X-ray diffraction, thermogravimetric analyses, elemental analysis, Xray powder diffraction and IR spectroscopy.
Journal ArticleDOI
Thermodynamics and Catalytic Properties of Two Novel Energetic Complexes Based on 3-Amino-1,2,4-triazole-5-carboxylic Acid
TL;DR: In this article , two new energetic complexes, Mn(atzc)2(H2O)2·2 H2O (1) and Zn(atz c) 2(H 2O) (2) (Hatzc = 3-amino-1,2,4-triazole-5-carboxylic acid), were synthesized by solvent evaporation and diffusion methods, respectively.
Journal ArticleDOI
A new oxygen-rich and poly-nitrogen energetic complex: synthesis, properties of high energy materials and catalytic decomposition of ammonium perchlorate
TL;DR: In this paper, a new energetic complex, Co(Hatzc)2(H2O)2] · 2H 2O (1) (H2atzc = 3-carboxyl...
References
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Advances in science and technology of modern energetic materials: an overview.
TL;DR: This paper also reviews work done on primary explosives of current and futuristic interest based on energetic co-ordination compounds and highlights the important contributions made by the various researchers in the frontier areas energetic ballistic modifiers, energetic binders and energetic plasticizers.
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Thermal decomposition of ammonium perchlorate
TL;DR: In this article, the authors summarize literature data on thermal decomposition of ammonium perchlorate and discuss the mechanism of the decomposition and various factors that influence the thermal decompositions of perchlorates.
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3,3′‐Azobis(6‐amino‐1,2,4,5‐tetrazine): A Novel High‐Nitrogen Energetic Material
Journal ArticleDOI
Synthesis of CuO nanorods and their catalytic activity in the thermal decomposition of ammonium perchlorate
TL;DR: In this article, the authors used X-ray diffraction (XRD), thermogravimetric (TG) analysis coupled with differential thermal analysis (DTA), transmission electron microscope (TEM), Brunauer-Emmett-Teller (BET) technique, and Fourier transformation infrared spectroscopy (FTIR) for ammonium perchlorate (AP) decomposition.