Journal ArticleDOI
A new procedure for the oxidation of saturated hydrocarbons
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In this article, a system comprising hydrogen sulphide and iron powder in pyridine containing acetic acid and a little water was used to oxidize adamantane with unusual efficiency.Abstract:
The oxidation of adamantane can be achieved with unusual efficiency using molecular oxygen and a system comprising hydrogen sulphide and iron powder in pyridine containing acetic acid and a little water.read more
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Journal ArticleDOI
Activation of c-h bonds by metal complexes
A. E. Shilov,Georgiy B. Shul'pin +1 more
TL;DR: In this article, it was shown that the same alkylhydridoplatinum(IV) complex is the intermediate in the reaction of ethane with platinum(II) σ-complexes.
Journal ArticleDOI
Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution
TL;DR: The Holy Grail of C-H activation research is not to find new CH activation reactions but to obtain an understanding of them that will allow the development of reagents capable of selective transformations of C -H bonds into more reactive functionalized molecules as discussed by the authors.
Journal ArticleDOI
If C-H bonds could talk: selective C-H bond oxidation.
TL;DR: The perspective taken herein will allow C-H oxidation reactions to be more readily incorporated into synthetic planning and to emphasize chemoselectivity imposed by the nature of the substrate.
Journal ArticleDOI
Cyclohexane oxidation continues to be a challenge
Ulf Schuchardt,Dilson Cardoso,Ricardo Sercheli,Ricardo Pereira,Rosenira Serpa da Cruz,Mário César Guerreiro,Dalmo Mandelli,Estevam V. Spinacé,Emerson L. Pires +8 more
TL;DR: In this article, the most interesting systems for the cyclohexane synthesis with different oxidants such as hydrogen peroxide, tert -butyl hydroperoxide and molecular oxygen were reviewed.
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