A simulation model for high-conversion pyrolysis of normal paraffinic hydrocarbons
Mitsuo Murata,Shozaburo Saito +1 more
About:
This article is published in Journal of Chemical Engineering of Japan.The article was published on 1975-03-15 and is currently open access. It has received 20 citations till now. The article focuses on the topics: Pyrolysis.read more
Citations
More filters
Journal ArticleDOI
Modeling of thermal cracking kinetics—I
K.M. Sundaram,G.F. Froment +1 more
TL;DR: In this paper, the authors derived reaction schemes for the thermal cracking of ethane, propane and their mixtures from observed product distribution, radical mechanisms, and thermodynamic principles and determined the rate parameters in a systematic way by estimation techniques minimizing a multi-response objective function.
Journal ArticleDOI
Coke Formation Mechanisms and Coke Inhibiting Methods in Pyrolysis Furnaces
TL;DR: In this paper, the authors investigated the effect of new chemical additives, tube material construction, pre-treatment of surface on the coke formation of pyrolysis furnaces.
Journal ArticleDOI
Pyrolysis of n-heptane: kinetics and modeling
Kamal K. Pant,Deepak Kunzru +1 more
TL;DR: In this article, the product distribution during pyrolysis of n-heptane was investigated in the temperature range 953 − 1023 K at atmospheric pressure, with steam as the inert diluent.
Journal ArticleDOI
High pressure pyrolysis of n-heptane
TL;DR: In this paper, the Rice-Kossiakoff theory was modified by including the bimolecular reactions of alkyl radicals with the parent hydrocarbon, and the initial product selectivities, calculated using the modified R-K mechanism, were in good agreement with the experimental selectivities.
Journal ArticleDOI
Pyrolysis Reaction Mechanism for Industrial Naphtha Cracking Furnaces
TL;DR: In this paper, a reaction mechanism set for naphtha cracking is generated on the basis of major reaction classes in pyrolysis and feed components to reduce the computational load, and the mechanism set is reduced using the eigenvalue−eigenvector decomposition method.
References
More filters
Related Papers (5)
Modeling of thermal cracking kinetics—II: Cracking of iso-butane, of n-butane and of mixtures ethane—propane—n-butane
K.M. Sundaram,G.F. Froment +1 more
A compilation of kinetic parameters for the thermal degradation of n‐alkane molecules
D. L. Allara,Robert Shaw +1 more