Journal ArticleDOI
A study of square-planar tellurium(II) complexes with thiourea type ligands
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TLDR
In this article, four planar tellurium(II) complexes with thiourea type ligands have been characterized and the crystal structures for two of the complexes are reported.About:
This article is published in Inorganica Chimica Acta.The article was published on 1981-01-01. It has received 8 citations till now. The article focuses on the topics: Thiourea & Crystal structure.read more
Citations
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Synthesis and characterisation of mercaptoimidazole, mercaptopyrimidine and mercaptopyridine complexes of platinum(II) and platinum(III). The crystal and molecular structures of tetra(2-mercaptobenzimidazole)- and tetra(2-mercaptoimidazole)platinum(II) chloride
TL;DR: In this article, K2[PtCl4] with 2-captobenzimidazole (HL2) and 2-mercaptoimidaze (HL3) in aqueous ethanol gave the new, crystalline, square-planar platinum(II) complexes [Pt(HL 2)4]Cl2EtOH (4) and [Ptp(HL 3]Cl22H2O (5), the crystal and molecular structures of which are reported in both complexes the ligands are present in the thione form
Journal ArticleDOI
The nature of the chemical bond in linear three-body systems: from i3- to mixed chalcogen/halogen and trichalcogen moieties.
M. Carla Aragoni,Massimiliano Arca,Francesco A. Devillanova,Alessandra Garau,Francesco Isaia,Vito Lippolis,Annalisa Mancini +6 more
TL;DR: The existence of correlations between the two bond distances and more importantly the linearity observed for all these systems, independently on the degree of their asymmetry, support the state of hypervalency of the central atom.
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A study of cis-octahedral compounds of tin(IV) halides with thiourea or urea type ligands
TL;DR: In this article, the crystal structures of two of the compounds are reported and the crystal structure determination of SnBr4 2(1,3-diethylthiourea) has been limited to the nearest atoms of the tin centre.
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Te(CS(NH2)2)4SO4·2H2O: A Three-in-One Semiorganic Nonlinear Optical Crystal with an Unusual Quadrilateral (TeS4)6– Chromophore
Xiaoya Weng,Chensheng Lin,Guang Peng,Guang Peng,Huixin Fan,Huixin Fan,Xin Zhao,Xin Zhao,Kaichuang Chen,Kaichuang Chen,Min Luo,Min Luo,Ning Ye,Ning Ye +13 more
TL;DR: The first tellurium(II) thiourea sulfate semiorganic nonlinear optical (NLO) material, Te(CS(NH2)(2))(4)SO4 center dot 2H(2)O, was successfully obtained using the slow evaporation technique as mentioned in this paper.
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Arylbis(thiosemicarbazone)tellurium(II) chlorides; three coordinate tellurium(II) complexes
Ajeet Singh,J.K. Basumatary +1 more
TL;DR: Three coordinate tellurium(II) complexes of the type [ArTe(XTSC) 2 ]Cl, where Ar = C 6 H 5, 4-HOC 6 H 4 or 4-CH 3 OC 6H 4 as discussed by the authors, have been synthesized by treating ArTeCl 3 with the thiosemicarbazones in aqueous methanol.
References
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International tables for X-ray crystallography
Norman Fordyce McKerron Henry,Lonsdale, Kathleen, Dame,John S. Kasper,Caroline H. MacGillavry,Gerard D. Rieck,James A. Ibers,Walter C. Hamilton +6 more
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Complexes of Divalent Tellurium.
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An interpretation of 125Te Mössbauer isomer shifts and quadrupole splittings in some tellurium compounds
TL;DR: In this paper, a relationship between 125Te Mossbauer isomer shifts versus holes in the 5p shell for tellurium compounds which are pure p-bonded was derived.
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