Journal ArticleDOI
Amine Oxides. VI. The Formation of 2,5-Norbornadiene and 2-Norbornene from 5-Dimethylamino-2-norbornene and 2-Dimethylaminonorbornane1,2
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This article is published in Journal of the American Chemical Society.The article was published on 1959-06-01. It has received 32 citations till now. The article focuses on the topics: Norbornadiene.read more
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Diels‐Alder‐Reaktionen: Zum Reaktionsmechanismus
TL;DR: In this paper, the mechanistischen Alternativen der praparativ so fruchtbaren Diels-Alder-Reaktionen anhand der experimentellen Fakten kritisch zu diskutieren.
Journal ArticleDOI
Eine Studie der DIELS‐ALDER‐Reaktion, I. Die Reaktivität von Dienophilen gegenüber Cyclopentadien und 9.10‐Dimethyl‐anthracen
TL;DR: In this article, die Additionsgeschwindigkeiten verschiedener Dienophile an Cyclopentadien und 9.10-Dimethyl-anthracen werden in wasserfreiem Dioxan als Solvens durch kinetische Messungen ermittelt und in Hinsicht auf den Mechanismus der DIELS-ALDER-Reaktion diskutiert.
Journal ArticleDOI
Mesoporous silica-aluminas as catalysts for the alkylation of aromatic hydrocarbons with olefins
Carlo Perego,S. Amarilli,Angela Carati,C. Flego,Giannino Pazzuconi,Caterina Rizzo,G. Bellussi +6 more
TL;DR: In this paper, two mesoporous silica-aluminas (MSA and MCM-41) were compared with the amorphous microporous silicas-alumina (ERS-8) and the zeolite beta in the liquid-phase alkylation of toluene with propylene.
Journal ArticleDOI
Acetylene equivalents in cycloaddition reactions
Journal ArticleDOI
Polymerization of carboxylic ester functionalized norbornenes catalyzed by (η3‐allyl)palladium complexes bearing N‐heterocyclic carbene ligands
TL;DR: In this paper, an in situ generated cationic allylpalladium complex bearing N-heterocy-clic carbene (NHC) ligands, derived from the reaction of ((g 3 -C3H5)Pd(nHC)Cl) with AgX (X ¼ BF4 or SbF6), is an active catalyst for the addition polymerization of norbor- nene and norbornene derivatives (5-norbornene-2-carboxylic acid methyl ester (b )a nd 5