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An infra-red spectroscopic study of molecular orientation and conformational changes in poly(ethylene terephthalate)

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TLDR
In this article, polarized infra-red (i.r.) spectroscopy has been used to study the changes in molecular orientation and conformation which occur on drawing poly(ethylene terephthalate) sheets.
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This article is published in Polymer.The article was published on 1974-11-01. It has received 151 citations till now.

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Journal ArticleDOI

Orientational Measurements in Polymers Using Vibrational Spectroscopy

TL;DR: A review of the recent theoretical and experimental results which have occurred since the review of Zbinden [3] can be found in this paper. But the review is limited to infrared and Raman measurements since they are complementary to each other in their a...
Journal ArticleDOI

Review Polarised Raman spectroscopy for the study of molecular orientation distributions in polymers

TL;DR: Polarized Raman spectroscopy is a vibrational spectroscopic technique that is used widely for the chemical and physical analyses of materials since it is both non-destructive and suitable for remote analysis as discussed by the authors.
Journal ArticleDOI

Characterization of biaxial orientation in poly(ethylene terephthalate) by means of refractive index measurements and Raman and infra-red spectroscopies

TL;DR: In this paper, the three principal refractive indices of poly(ethylene terephthalate) were found to be 1.645, 1.573, and 1.541.
Journal ArticleDOI

Elucidation of the Chain Conformation in a Glassy Polyester, PET, by Two-Dimensional NMR

TL;DR: The chain conformation of glassy poly(ethylene terephthalate) (PET) was characterized by two-dimensional double-quantum nuclear magnetic resonance (NMR) and an average gauche torsion angle of 70 degrees was obtained.
Journal ArticleDOI

Enzymatic surface modification and functionalization of PET: A water contact angle, FTIR, and fluorescence spectroscopy study

TL;DR: In this paper, a lypolytic enzyme was applied to polyethylene terephthalate (PET) to investigate the changes induced by a lysergic enzyme on the surface properties.
References
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Book

Mechanical properties of solid polymers

I. M. Ward
TL;DR: A concise, self-contained introduction to solid polymers, the mechanics of their behavior and molecular and structural interpretations can be found in this article, which provides extended coverage of recent developments in rubber elasticity, relaxation transitions, non-linear viscoelastic behavior, anisotropic mechanical behavior, yield behavior of polymers and other fields.
Journal ArticleDOI

Beziehungen zwischen elastischen Konstanten und Dehnungsdoppelbrechung hochelastischer Stoffe

TL;DR: In this article, the optischen Doppelbrechung zur mechanischen Ruckstellkraft (dyn/cm2) erweist sich dabei als unabhangig von der Anzahl der pro cm3 der Substanz vorhandenen Kristallite.
Book ChapterDOI

Infrared spectra of high polymers

TL;DR: In this article, the spectral properties of polyethylene terephthalate and three deuterated analogs have been obtained in the region of 70 to 3600 cm-i, polarized spectra having been obtained down to 330 cm-l. This assignment suggests a modification of the proposed chain structure of this polymer.
Journal ArticleDOI

Polarized Infrared Studies of Amorphous Orientation in Polyethylene and Some Ethylene Copolymers

B. E. Read, +1 more
- 01 Mar 1968 - 
TL;DR: In this article, measurements were made of the dichroic ratios of a number of infrared bands for uniaxially deformed low-density polyethylene, and orientation functions were derived from the results on the conformationally sensitive amorphous bands at 1368/cm, 1352/ cm, 1303/cm and 1078/cm.
Journal ArticleDOI

The infrared spectrum of polyethylene terephthalate. I The effect of crystallization

TL;DR: In this paper, the intensity change of the infrared spectral bands resulting from drawing and heating of amorphous polyethylene terephthala to various extents were followed.
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