Book ChapterDOI
Azo coupling reactions structures and mechanisms
Ivanka Szele,Heinrich Zollinger +1 more
About:
This article is published in ChemInform.The article was published on 1983-11-22. It has received 67 citations till now. The article focuses on the topics: Azo coupling & Electrophilic aromatic substitution.read more
Citations
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Journal ArticleDOI
Synthesis of azobenzenes: the coloured pieces of molecular materials
TL;DR: This critical review covers the various synthetic methods reported on azo compounds with special emphasis on the more recent ones and their mechanistic aspects (170 references).
Journal ArticleDOI
Control over molecular motion using the cis–trans photoisomerization of the azo group
Estíbaliz Merino,María Ribagorda +1 more
TL;DR: This work describes selected examples of systems containing an azobenzene moiety and their motions and geometrical changes caused by external stimuli.
Journal ArticleDOI
Mechanism of the coupling of diazonium to single-walled carbon nanotubes and its consequences.
TL;DR: A mechanistic model is proposed that predicts reactivity and selectivity as a function of diazonium electrophilicity and metallic-to-semiconducting CNT ratio, thus opening perspectives of controlled high-yield functionalization and purification.
Journal ArticleDOI
Label-free detection in biological applications of surface-enhanced Raman scattering
TL;DR: This review highlights recent developments in label-free SERS-based techniques for bimolecular detection, including direct biomolecular identification, biomolecule–ligand recognition via spectral differences among molecular bridges, and indirect phenolic molecule detection based on azo couplings.
Journal ArticleDOI
Advances in Application of Azobenzene as a Trigger in Biomedicine: Molecular Design and Spontaneous Assembly.
TL;DR: Azobenzene is a well-known derivative of stimulus-responsive molecular switches and has shown superior performance as a functional material in biomedical applications as mentioned in this paper, and has been used as a hypoxia-sensitive connector via biological cleavage under appropriate stimulus conditions.
References
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Journal ArticleDOI
The Proton in Chemistry
R. P. Bell,Simon H. Bauer +1 more
TL;DR: The first edition of this book was based on the lectures which I gave at Cornell University during 1958 as George Fisher Baker Lecturer, and I would like to repeat my warmest thanks to Professor F. A. Long and the other members of the Department of Chemistry for their kindness and helpful advice as discussed by the authors.
Journal ArticleDOI
Kinetik und Mechanismus 1.3‐Dipolarer Cycloadditionen
TL;DR: In this paper, mechanistische Kriterien fur die zu funfgliedrigen Ringen fuhrende 1.3-Dipolare Cycloaddition dienen die Stereoselektivitat bei Verwendung cis-trans-isomerer Dipolarophile, die Einflusse von Losungsmittel and Substituenten auf die Reaktionsgeschwindigkeitskonstanten, die Aktivierungsparameter and die Orientierung'sphan