Journal ArticleDOI
β-Diketonato(triphenylphosphine) complexes of ruthenium(II)
K. Natarajan,Umesh Agarwala +1 more
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This article is published in Inorganic and Nuclear Chemistry Letters.The article was published on 1978-01-01. It has received 34 citations till now. The article focuses on the topics: Ruthenium & Triphenylphosphine.read more
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Synthesis, characterisation and electrochemical behaviour of Cu(II), Co(II), Ni(II) and Zn(II) complexes derived from acetylacetone and p -anisidine and their antimicrobial activity
TL;DR: In this article, neutral tetradentate N2O2 type complexes of Cu(II, Ni(II), Co(II) and Zn(II)) have been synthesized using the Schiff base formed by the condensation of acetylacetone andp-anisidine.
Journal ArticleDOI
Synthesis, characterization and catalytic activities of ruthenium complexes containing triphenylphosphine/triphenylarsine and tetradentate Schiff bases ☆
TL;DR: Ruthenium(II) complexes of the type [Ru(CO)(B)(L)] (B=AsPh3, pyridine, piperidine or morpholine; L=dianion of tetradentate Schiff bases) have been synthesized and characterized by physicochemical methods as mentioned in this paper.
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Can geometry control the coordination behaviour of 2-hydroxy-1-naphthaldehyde-N(4)-phenylthiosemicarbazone? A study towards its origin
Rathinasabapathi Prabhakaran,Rathinasabapathi Prabhakaran,Kalaivani Palaniappan,R. Huang,Monica Sieger,Wolfgang Kaim,P. Viswanathamurthi,F. Dallemer,Karuppannan Natarajan +8 more
TL;DR: In this paper, the 2-hydroxy-1-naphthaldehyde-N(4)-phenylthiosemicarbazone (H 2 -Nap-ptsc) was reacted with square planar complexes of the type [MCl 2 (EPh 3 ) 2 ] (where M = Ni or Pd; E = P or As) and octahedral [RuHCl(CO)(PPh 3 ] 3 ].
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Synthetic, catalytic and biological studies of new binuclear ruthenium(II) complexes containing thiobis(β-diketones) and triphenylphosphine
TL;DR: In this paper, a convenient synthesis of binuclear ruthenium(II) complexes of the type {[RuCl(CO)(PPh3)(B)]2(bis-β-dk)} was accomplished by reacting [RuHCl( CO)(PP3)2(B)] with thiobis- β-diketones in benzene.
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Dissymmetric thiosemicarbazone ligands containing substituted aldehyde arm and their ruthenium(II) carbonyl complexes with PPh3/AsPh3 as ancillary ligands: Synthesis, structural characterization, DNA/BSA interaction and in vitro anticancer activity
Paranthaman Vijayan,Periasamy Viswanathamurthi,Vaidhyanathan Silambarasan,Devadasan Velmurugan,K. Velmurugan,Raju Nandhakumar,Ray J. Butcher,Tamilselvan Silambarasan,Ramamurthy Dhandapani +8 more
TL;DR: In this paper, a dissymmetric ruthenium(II) carbonyl complexes of the type [Ru(CO)(EPh3)(L1-2)] (1-4), [E = P or As; L1 = N4-(2-hydroxynaphthalene-1-carbaldehyde)-2-amino-5-chlorobenzophenone thiosemicarbazone] have been synthesized and characterized by several spectroscopic studies.
References
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Journal ArticleDOI
Complexes of the platinum metals. Part II. Carboxylato(triphenylphosphine) derivatives of ruthenium, osmium, rhodium, and iridium
TL;DR: In this paper, the carboxylato-derivatives are characterised by i.m.n.r. spectroscopy and 1H n.m., respectively.
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Mixed complexes of ruthenium(III) and ruthenium(II) with triphenylphosphine or triphenylarsine and other ligands
TL;DR: In this article, a new Ru(III) complex, [RuBr3(AsPh3)3] has been synthesized, which is characterised by analyses, conductivity and magnetic measurements, molecular weight and spectral studies (IR and visible).
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New complexes of ruthenium(II) with triphenylphosphine and other ligands
J. D. Gilbert,G. Wilkinson +1 more
TL;DR: In this article, the interactions of dichlorotris(triphenylphosphine)ruthenium(II), RuCl2(PPh3)3, with various reagents have been studied and the resulting complexes characterised by i.m.r.
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Triphenyl arsine and phosphine complexes of ruthenium(II) and their reactions with pyridine
Raj K. Poddar,Umesh Agarwala +1 more
TL;DR: A new complex of ruthenium(II) with triphenylarsine [Ru(AsPh3)2Cl2]2 has been prepared and structures have been assigned on the basis of magnetic, spectral and other physical studies as discussed by the authors.