Journal ArticleDOI
Bicyclische lithium-t-butylaminofluorsilane, moleküle mit zwei- und vierfachkoordinierten lithium
Reads0
Chats0
TLDR
In this paper, a bicyclic compound with fourfold [F2Li(THF)N] and twofold [NLiN] coordinated lithium was obtained and the NMR spectra in solution showed an equilibration of the H, C, F and Si atoms.About:
This article is published in Journal of Organometallic Chemistry.The article was published on 1988-04-12. It has received 38 citations till now. The article focuses on the topics: Nuclear magnetic resonance spectroscopy & Bicyclic molecule.read more
Citations
More filters
Journal ArticleDOI
Structures of Two Highly Reactive Intermediates upon LiAlH4 Reduction in the Solid State and in Solution: [(Me3Si)2NAlH3Li · 2Et2O]2 and [(Me3Si)2N]2AlH2Li · 2Et2O
Andreas Heine,Dietmar Stalke +1 more
TL;DR: The mean interplanar distance between the hydroxyphenyl moiety and benzoquinone skeleton was 3.13 A, and the O.O distance in the hydrogen bonds was 2.743 as mentioned in this paper.
Journal ArticleDOI
Stable silaimines with three- and four-coordinate silicon atoms.
Prinson P. Samuel,Ramachandran Azhakar,Rajendra S. Ghadwal,Sakya S. Sen,Herbert W. Roesky,Markus Granitzka,Julia Matussek,Regine Herbst-Irmer,Dietmar Stalke +8 more
TL;DR: Compounds 5-9 are stable under inert atmosphere and were characterized by elemental analysis, NMR spectroscopy, and single-crystal X-ray studies.
Journal ArticleDOI
Direct observation of a lithiated oxirane: a synergistic study using spectroscopic, crystallographic, and theoretical methods on the structure and stereodynamics of lithiated ortho-trifluoromethyl styrene oxide
Antonio Salomone,Filippo Maria Perna,Aurelia Falcicchio,Sten O. Nilsson Lill,Anna Moliterni,Reent Michel,Saverio Florio,Dietmar Stalke,Vito Capriati +8 more
TL;DR: In this paper, the solution and the solid state structure of an α-lithiated aryloxirane (1-Li) were determined using a single crystal X-ray diffraction analysis of 1-Li performed at 100 K applying the X-TEMP-2 device.
Journal ArticleDOI
Experimental Charge Density Studies of Cyclotetrasilazane and Metal Complexes Containing the Di‐ and Tetraanion
TL;DR: In this paper, the tetraanion [Me2SiN]4 was synthesized to investigate the nature of the covalent Si-N single bond in the presence of various metals.
Journal ArticleDOI
Synthesis and Molecular Structure of the Solvent‐Free [LiN(SiMe3)(2,6iPr2C6H3)]2 Dimer
TL;DR: The first solid-state X-ray analysis of a four-membered [LiN]2 heterocycle with two solvent-free two-coordinate Li centers was performed in this paper.
References
More filters
Journal ArticleDOI
Structure and reactivity of sterically hindered lithium amides and their diethyl etherates: crystal and molecular structures of [Li{N(SiMe3)2}(OEt2)]2 and tetrakis(2,2,6,6-tetramethylpiperidinatolithium)
Journal ArticleDOI
The crystal structure of N-lithiohexamethyldisilazane, [LiN(SiMe3)2]3
TL;DR: The crystal structure of [LiN(SiMe3)2]3 has been determined from single-crystal X-ray diffraction data collected by counter methods as mentioned in this paper.
Journal ArticleDOI
Stereochemistry of polynuclear compounds of the main group elements. Neutron and x-ray diffraction investigation of lithium-hydrogen-carbon interactions in lithium tetramethylborate
Journal ArticleDOI
Tris(trimethylsilylamino)silanes RSi(NHSiMe3)3: synthesis, crystal and molecular structure of three dimeric trilithio derivatives
TL;DR: MeSi(NHSiMe 3 ) 3 (I) and t-BuSi(NSiMe 2 ) 3(II) have been shown by X-ray diffraction to form trilithio derivatives VI, VII and VIII as discussed by the authors.
Related Papers (5)
Spectroscopic and structural characterization of 2,4,6-tris(trifluoromethyl)phenyllithium·Et2O: a dimer stabilized by lithium ⋯ fluorine contacts
Diisopropyl‐(2,4,6‐tri‐tert‐butylphenylimino)silan – ein sehr stabiles, freies Silaimin
Michael Hesse,Uwe Klingebiel +1 more