Bifunctional {Pb10K2}–Organic Framework for High Catalytic Activity in Cycloaddition of CO2 with Epoxides and Knoevenagel Condensation
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This article is published in ACS Catalysis.The article was published on 2022-08-09. It has received 21 citations till now.read more
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Nanocage-Based Tb3+-Organic Framework for Efficiently Catalyzing the Cycloaddition Reaction of CO2 with Epoxides and Knoevenagel Condensation.
TL;DR: In this article , a combination of [Tb4(μ2-OH)2(CO2)8] cluster and 2,6-bis(2,4-dicarboxylphenyl)-4-(4-carboxyl phenyl)pyridine (H5BDCP) ligand generated a highly robust nanoporous framework of {[Tb 4(BDCP]2]·3DMF·5H2O}n (NUC-58), in which each four clusters are woven together to generate an elliptical nanocage.
Journal ArticleDOI
Undulated Ni(II)-Framework with In Situ-Grafted Open-Metal and Basic Sites for High-Performance Electrochemical Water Oxidation and Flexible Composite-Driven Size-Exclusive Autotandem Catalysis
TL;DR: In this article , the authors report an unprecedented integration of multiple active sites, including Lewis acid centers, free pyridine, and amine moiety, inside the pore wall of a thermochemically stable and undulated mixed-ligand Ni(II) framework.
Journal ArticleDOI
Nanochannel-Based Heterometallic {CoIITbIII}-Organic Framework for Fluorescence Recognition of Tryptophan and Catalytic Cycloaddition of Epoxides with CO2
TL;DR: In this paper , a honeycomb nanochannel of metal-organic frameworks (MOFs) was used as a potential fluorescence probe for the targeted detection of tryptophan of ecosystems, which has excellent physical and chemical properties of high specific surface area, good chemical stability, and highly open coexistence of Lewis acid-base sites.
Journal ArticleDOI
Bifunctional Self-Penetrating Co(II)-Based 3D MOF for High-Performance Environmental and Energy Storage Applications
TL;DR: KA@MOF-S is a self-penetrating three-dimensional (3D) framework, which shows a 3.4,4,T25 underlying topological net as mentioned in this paper .
Journal ArticleDOI
Robust {Cd4}-Organic Framework for Efficiently Catalyzing CO2 Cycloaddition and Knoevenagel Condensation
TL;DR: In this article , the inner surface of channels in activated NUC-67a is functionalized by Lewis acid sites of unsaturated Cd2+ ions and Lewis base sites of μ3-OH groups, CH3CO2 anions, free pyridine, and C═O groups.
References
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Metal-Organic Frameworks for Photocatalysis and Photothermal Catalysis.
Juan-Ding Xiao,Hai-Long Jiang +1 more
TL;DR: It is shown that MOFs provide a powerful platform to study photocatalysis, in which the involved three key processes, namely, light harvesting, electron-hole separation, and surface redox reactions, can be rationally improved.
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Incorporation of Imidazolium-Based Poly(ionic liquid)s into a Metal–Organic Framework for CO2 Capture and Conversion
Meili Ding,Hai-Long Jiang +1 more
TL;DR: In this article, imidazolium-based poly(ionic liquid)s (denoted as polyILs) have been confined into the metal-organic framework (MOF) material MIL-101 via in situ polymerization of encapsulated monomers.
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Bi‑Microporous Metal–Organic Frameworks with Cubane [M 4 (OH) 4 ] (M=Ni, Co) Clusters and Pore‑Space Partition for Electrocatalytic Methanol Oxidation Reaction
Ya-Pan Wu,Jun-Wu Tian,Shan Liu,Bo Li,Jun Zhao,Lu-Fang Ma,Dongsheng Li,Ya-Qian Lan,Xianhui Bu +8 more
TL;DR: A new material based on pore-space partition of the cubic primitive minimal-surface net (MOF-14-type) has been realized through an ingenious scheme of tri-component charge matching, in conjunction with size/symmery matching, and is likely the first example of pore space partition by a ligand pair.
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Monometallic Catalytic Models Hosted in Stable Metal-Organic Frameworks for Tunable CO2 Photoreduction
Xiao-Kun Wang,Jiang Liu,Lei Zhang,Long-Zhang Dong,Shun-Li Li,Yu-He Kan,Dongsheng Li,Ya-Qian Lan +7 more
TL;DR: In this paper, three stable and isostructural metal-organic frameworks (MOF-Ni, MOF-Co, and MoF-Cu) have been synthesized and used as heterogeneous catalysts in photocatalytic CO2 reduction reaction (CO2RR).
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Photocatalytic Molecular Oxygen Activation by Regulating Excitonic Effects in Covalent Organic Frameworks.
TL;DR: In addition to providing in-depth insights into molecular oxygen activation, this work opens an avenue to the regulation of excitonic effects based on COFs.