Journal ArticleDOI
Bonding and structure trends of thiosemicarbazone derivatives of metals—An overview
TLDR
In this article, the coordination chemistry of thiosemicarbazones and all the metals for which complexes are reported are discussed with respect to their bonding and structures, variable bonding properties, metallation, metal-metal interactions, role of solvents/other factors in stabilization of sulfur-bridging in coinage metals, and the nature of substituents at azomethine carbon.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2009-04-01. It has received 526 citations till now. The article focuses on the topics: Coordination complex & Coinage metals.read more
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A novel water soluble ligand bridged cobalt(II) coordination polymer of 2-oxo-1,2-dihydroquinoline-3-carbaldehyde (isonicotinic) hydrazone: evaluation of the DNA binding, protein interaction, radical scavenging and anticancer activity.
TL;DR: Investigation of the antioxidative properties showed that the polymeric Co(II) complex has a strong radical scavenging potency against hydroxyl radicals, 2,2-diphenyl-1-picrylhydrazyl radicals), nitric oxide and superoxide anion radicals.
Journal ArticleDOI
Copper complexes as therapeutic agents
Clare Duncan,Anthony R. White +1 more
TL;DR: A broad insight is provided into some of the diverse actions of Cu complexes and the strong future for these compounds as potential therapeutic agents is demonstrated.
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Experimental and theoretical evaluation of semicarbazones and thiosemicarbazones as organic corrosion inhibitors
Carla Marins Goulart,Andressa Esteves-Souza,Carlos A. Martínez-Huitle,Ciro José Ferreira Rodrigues,Maria Aparecida Medeiros Maciel,Aurea Echevarria +5 more
TL;DR: In this article, the performance of four thiosemicarbazones (1A,D) and two semicarbazone (2A,B) towards carbon steel corrosion in 1.0 M HCl was evaluated by molecular modeling, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) at different inhibitor concentrations.
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New trends in platinum and palladium complexes as antineoplastic agents
TL;DR: In this paper, the main recent advances in the design and synthesis of platinum-and palladium-based drugs, their structural features and biological studies of them are reviewed, and an overview of the main biological techniques and approaches for testing the interaction of these molecules with the biological environment, mainly DNA, to validate the effect is also provided.
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Biological evaluation of a novel water soluble sulphur bridged binuclear copper(II) thiosemicarbazone complex.
TL;DR: Investigations of antioxidative properties showed that the copper(II) nitrate complex has strong radical scavenging properties and the cytotoxic effect of the complex was examined on HeLa, Hep G2, and HEp-2, which showing that the complex exhibited substantial cytotoxicity specificity on He La over the other two.
References
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Journal ArticleDOI
Thiosemicarbazone complexes of copper(II): structural and biological studies
Douglas X. West,Anthony E. Liberta,Subhash Padhye,Rajeev C. Chikate,Pramila Sonawane,Avinash S. Kumbhar,Ratnamala Yerande +6 more
TL;DR: In this paper, the authors discuss the biological importance of copper thiosemicarbazone complexes and their applications in the field of chemical engineering, such as chemical synthesis, chemical engineering and electrical engineering.
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Transition metal complexes of semicarbazones and thiosemicarbazones
TL;DR: In this paper, Generals survey has shown that thiosemicarbazone complexes can be formed by transition metal complexes, including d2 complexes, d3 complexes and d4 complexes.
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Main group metal complexes of semicarbazones and thiosemicarbazones. A structural review
TL;DR: The structural aspects of the complexes formed by thiosemicarbazones and semicarazones (TSCs) with the metallic elements of Groups 12, 13, 14 and 15 are surveyed up to 1998.
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2-Acetylpyridine thiosemicarbazones. 1. A new class of potential antimalarial agents
TL;DR: Screening results indicated that the presence of the 2-pyridylethylidene group was critical and that certain phenyl, benzyl, phenethyl, or cycloalkyl groups at N4 of the thiosemicarbazone moiety also contribute to antimalarial activity.