Journal ArticleDOI
Borwasserstoffe, VI.: Die einfachsten Borhydride
Alfred Stock,Ernst Kuss +1 more
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This article is published in European Journal of Inorganic Chemistry.The article was published on 1923-04-11. It has received 56 citations till now.read more
Citations
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The roles of dihydrogen bonds in amine borane chemistry.
TL;DR: It is found that DHBs play a dominant role in dictating the reaction pathways (and thus different products) of amine boranes where oppositely charged hydrogens coexist for DHB formation and subsequent molecular hydrogen elimination.
Journal ArticleDOI
Ammonia borane, past as prolog
TL;DR: Ammonia borane (NH3BH3) has yielded its secrets grudgingly since its first attempted synthesis in 1923 as discussed by the authors, and its chemistry and properties have been reviewed in detail.
Journal ArticleDOI
Solid-state hydrogen rich boron–nitrogen compounds for energy storage
TL;DR: This review highlights developments in synthesis of ammonia borane and its derivatives over the last 80 years and identifies the key distinctions between homopolar and heteropolar H2 release.
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Experimental and Computational Study of the Formation Mechanism of the Diammoniate of Diborane: The Role of Dihydrogen Bonds
TL;DR: The results indicate that dihydrogen bonds between the initially formed AB and AaDB accelerate the formation of DADB in competition with the forming of AB.
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A New Perspective on Borane Chemistry: The Nucleophilicity of the B-H Bonding Pair Electrons.
TL;DR: The recognition of the nucleophilic properties of the B-H bonding pair electrons will also help to more deeply understand the different mechanisms operating in hydroboration reactions.
References
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Journal ArticleDOI
Siliciumwasserstoffe VI.: Chlorierung und Methylierung des Monosilans
Alfred Stock,Carl Somieski +1 more
Journal ArticleDOI
Dampfdrucktafeln für Temperaturbestimmungen zwischen + 25° und — 185°
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Siliciumwasserstoffe, IX.: Reaktionen mit Alkalimetall
Alfred Stock,Karl Somieski +1 more
Related Papers (5)
Hydrides of Boron. VIII. The Structure of the Diammoniate of Diborane and its Relation to the Structure of Diborane
Chemical Evidence for the Structure of the “Diammoniate of Diborane.” II. The Preparation of Ammonia-Borane
S. G. Shore,R. W. Parry +1 more