Journal ArticleDOI
Ammonia-borane and related compounds as dihydrogen sources.
Reads0
Chats0
Citations
More filters
Journal ArticleDOI
Dehydrogenation and related reactions catalyzed by iridium pincer complexes
TL;DR: McDonald et al. as mentioned in this paper proposed a method to solve the problem of protein synthesis in the context of the 239th American Chemical Society (ACS) National Meeting of Organometallics 2010.
Journal ArticleDOI
Nanoscaled metal borides and phosphides: recent developments and perspectives
TL;DR: Chimie de la Matier̀e Condenseé de Paris, UPMC Univ Paris 06, UMR 7574, Colleǵe de France, 11 Place Marcelin Berthelot, 75231 Paris Cedex 05; Laboratory Heteroelements and Coordination, Chemistry Department, Ecole Polytechnique, CNRS-UMR 7653, Palaiseau, France
Journal ArticleDOI
First-Row Transition Metal (De)Hydrogenation Catalysis Based On Functional Pincer Ligands.
TL;DR: This review aims at providing a comprehensive picture of the utilization of functional pincer ligands in first-row transition metal hydrogenation and dehydrogenation catalysis and related synthetic concepts relying on these such as the hydrogen borrowing methodology.
Journal ArticleDOI
Efficient Subnanometric Gold-Catalyzed Hydrogen Generation via Formic Acid Decomposition under Ambient Conditions
TL;DR: Applying an ultradispersed gold catalyst comprising TEM-invisible gold subnanoclusters deposited on zirconia to a FA-amine mixture affords turnover frequencies (TOFs) up to 1590 per hour and a turnover number of more than 118,400 at 50 °C.
Journal ArticleDOI
Synthesis and reactions of N-heterocyclic carbene boranes.
Dennis P. Curran,Andrey Solovyev,Malika Makhlouf Brahmi,Louis Fensterbank,Max Malacria,Emmanuel Lacôte +5 more
TL;DR: This Review provides comprehensive coverage of the synthesis, characterization, and reactions of NHC-boranes.
References
More filters
Journal ArticleDOI
Metal hydride materials for solid hydrogen storage: a review
TL;DR: A review of metal hydrides on properties including hydrogen-storage capacity, kinetics, cyclic behavior, toxicity, pressure and thermal response is presented in this article, where a group of Mg-based hydride stand as promising candidate for competitive hydrogen storage with reversible hydrogen capacity up to 7.6 W% for on-board applications.
Journal ArticleDOI
Frustrated Lewis pairs: metal-free hydrogen activation and more.
Douglas W. Stephan,Gerhard Erker +1 more
TL;DR: Sterically encumbered Lewis acid and Lewis base combinations do not undergo the ubiquitous neutralization reaction to form "classical" Lewis acid/Lewis base adducts, but both the unquenched Lewis acidity and basicity of such sterically "frustrated Lewis pairs (FLPs)" is available to carry out unusual reactions.
Journal ArticleDOI
Mechanisms of the H2-hydrogenation and transfer hydrogenation of polar bonds catalyzed by ruthenium hydride complexes
TL;DR: In this article, the authors classified the catalytic cycles for the H2-hydrogenation (H) and transfer hydrogenation (T) of CO and cN bonds catalyzed by over 100 ruthenium hydride complexes in organic and aqueous media.
Journal ArticleDOI
Main-group elements as transition metals
TL;DR: The last quarter of the twentieth century and the beginning decade of the twenty-first witnessed spectacular discoveries in the chemistry of the heavier main-group elements, which led to new structural and bonding insights as well as a gradually increasing realization that the science more resembles that of transition-metal complexes than that of their lighter main- group congeners.
Journal ArticleDOI
Characterization of a Dihydrogen Bond on the Basis of the Electron Density
TL;DR: In this article, the authors applied a set of criteria developed in the context of the theory of atoms in molecules to study dihydrogen bonds, which were previously successfully used to study conventional hydrogen bonds.