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CaAl2Cr2O7: Formation, synthesis, and characterization of a new Cr(III) compound under air atmosphere in the Al2O3–CaO–Cr2O3 system

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TLDR
In this article, a polycrystalline ternary Cr(III) compound (CaAl2Cr2O7) was synthesized at 1500°C under air atmosphere for the first time.
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This article is published in Ceramics International.The article was published on 2019-09-01. It has received 19 citations till now. The article focuses on the topics: Powder diffraction.

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Microstructure and mechanical properties of CaAl12O19 reinforced Al2O3-Cr2O3 composites

TL;DR: In this paper, the CaAl12O19 reinforced Al 2O3-Cr2O3 composites were prepared by pressureless sintering process, and the influences of CaO content on the sinterings properties, mechanical properties, and microstructure evolution of the composites are studied.
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Influence of the Al2O3/SiO2 mass ratio and gas composition on the viscous behavior and structure of Cr-containing stainless steel slags

TL;DR: In this paper, the authors investigated the effects of the Al2O3/SiO2 mass ratio and gas composition on the viscosity and structure of Cr-containing CaO-SiO 2-MgO-Al2O 3-CrOx stainless steel slags.
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Inhibition of Cr6+ by the formation of in-situ Cr3+ containing solid-solution in Al2O3–CaO–Cr2O3–SiO2 system

TL;DR: In this article, the pseudo-ternary Al2O3-CaO-Cr2O 3 ternary system was doped with different amounts of SiO2 and heat-treated at 1400°C in the air atmosphere.
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Effective inhibition of Cr(VI) in the Al2O3-CaO-Cr2O3 refractory castables system through silica gel assisted in-situ secondary phase tuning

TL;DR: In this paper, a facile route was introduced to fabricate the Al2O3-CaO-Cr 2O3 refractory castables to mitigate Cr(VI) using basic silica sol (pH∼9) via in-situ secondary phase modification.
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Modification of interface chemistry and slag structure by transition element Cr

TL;DR: In this article, a comparative study on CaO-MgO-Al2O3-SiO2 slags and CaO−Mg O-Al 2O3−SiO 2 slags was conducted to investigate the distribution of the elements at the gas-slag interface, which revealed that sulfur exists in the form of S2− in the slag.
References
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Journal ArticleDOI

Sources and toxicity of hexavalent chromium

TL;DR: Chromium is known to have 100-fold more toxicity than trivalent chromium, for both acute and chronic exposures because of its high water solubility and mobility, as well as easy reduction.
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Chemical Unit Cosubstitution and Tuning of Photoluminescence in the Ca2(Al1–xMgx)(Al1–xSi1+x)O7:Eu2+ Phosphor

TL;DR: The concept of "chemical unit cosubstitution" is described as one such potential design scheme that enables the tuning of luminescent properties in phosphor materials and is shown to be restricted to tetrahedral sites.
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Chromium Contamination Accident in China: Viewing Environment Policy of China

TL;DR: The effects of Cr slag on ecology, environment and health will last for many years, and the industry is constantly looking for efficient and innovative routes for chromium recovery or detoxification, large amounts of such soil and wastewater are still released to the environment, throughout the world, every year.
Journal ArticleDOI

Use of plasma spray technology for deposition of high temperature oxidation/corrosion resistant coatings – a review

TL;DR: In this paper, the role of plasma spraying on superalloys has been discussed with the help of a comprehensive literature survey, and the main focus of this investigation is the studies related to plasma sprayed NiCrAlY, Ni-Cr, Nickel aluminide and Co-based coatings.
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