Journal ArticleDOI
Catalytic activity of Pd (AcO)2 coordinated to cross-linked polymeric isocyanides
TLDR
Palladium acetate (Pd(AcO)2) undergoes easy and quantitative coordination to hydrophilic macromolecular isocyanides to give monoisocyano-Pd[NC]-Pd as mentioned in this paper.About:
This article is published in Journal of Molecular Catalysis.The article was published on 1993-05-10. It has received 12 citations till now. The article focuses on the topics: Catalysis & Palladium(II) acetate.read more
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The coordination chemistry of carbon dioxide and its relevance for catalysis: a critical survey
TL;DR: The ability of carbon dioxide to act as a ligand in transition metal complexes is now well documented and several coordination modes of CO2 have been described as mentioned in this paper, but activation by coordination is not a necessary prerequisite for catalytic conversion of CO 2 to useful chemicals.
Journal ArticleDOI
Combined Homogeneous and Heterogeneous Catalysts. Rhodium and Platinum Isocyanide Complexes Tethered on Silica-Supported Metal Heterogeneous Catalysts: Arene and Cyclohexanone Hydrogenation †
Hanrong Gao,Robert J. Angelici +1 more
TL;DR: In this paper, the TCSM (tethered complex on supported metal) catalysts were used to catalyze the hydrogenation of arenes (Rh−CNR2/Pd−SiO2 and rhCl[CN(CH2)3Si(OC2H5)3]2) under mild conditions of 40 °C and 1 atm.
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Combined homogeneous and heterogeneous catalysts.: Rhodium carbonyl thiolate complexes tethered on silica-supported metal heterogeneous catalysts: olefin hydroformylation and arene hydrogenation
Hanrong Gao,Robert J. Angelici +1 more
TL;DR: In this paper, a tethered complex on a supported-metal (TCSM) was used to catalyze the hydroformylation of olefins and the hydrogenation of toluene under atmospheric pressure.
Journal ArticleDOI
Rhodium–phosphine complex catalysts tethered on silica-supported heterogeneous metal catalysts: arene hydrogenation under atmospheric pressure
Hanrong Gao,Robert J. Angelici +1 more
TL;DR: In this article, the tethered rhodium-phosphine complex (Rh-P) was shown to have the same structure as the free rh-P complex in all of these combination catalysts.
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Rhodium amine complexes tethered on silica-supported metal catalysts. highly active catalysts for the hydrogenation of arenes
Hanrong Gao,Robert J. Angelici +1 more
TL;DR: In this article, the TCSM catalysts of the tethered rhodium amine complex and the SiO2-supported metal were investigated for the hydrogenation of toluene.
References
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Journal ArticleDOI
Carbon dioxide activation and catalytic lactone synthesis by telomerization of butadiene and carbon dioxide
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Synthesis and reactivity of novel palladium(II)-isocyanide complexes
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Rhodium catalyzed reaction of butadiene and carbon dioxide
Arno Behr,Ren He +1 more
TL;DR: In this article, the selective synthesis of the δ-lactone 2-ethyl-2,4-heptadien-4-olide by the palladium-catalyzed reaction of carbon dioxide and butadiene is described.
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Palladium-catalyzed Reactions of 1,3-Dienes with Active Methylene Compounds. IV. Palladium-diphosphine Complex Catalysts
TL;DR: In this paper, active methylene compounds, such as acetylacetone and ethyl acetoacetate, reacted with 1,3-butadiene in the presence of palladium-diphosphine complex catalysts to yield two 1 : 1 adducts, 1 and 2.
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Steuerungsmöglichkeiten bei der übergangsmetall‐katalysierten Umsetzung von 1,3‐Dienen mit Kohlendioxid
TL;DR: The reaction of butadiene with carbon dioxide using homogeneous palladium, ruthenium, and nickel catalysts affords the C9-lactone 2-ethylidene-6-hepten-5-olide (3) in yields up to 59% as mentioned in this paper.