Journal ArticleDOI
Chemistry of oxo-metal ions—III: 2,2′-bipyridinium oxopentachloromolybdate(V) and its derivatives
H.K. Saha,M.C. Halder +1 more
TLDR
In this paper, it has been shown that the oxometal entity MoO3+ remains intact under various physicochemical methods and that the expected cis-trans isomers of MoOCl3·bipy has also been discussed.About:
This article is published in Journal of Inorganic and Nuclear Chemistry.The article was published on 1971-11-01. It has received 25 citations till now.read more
Citations
More filters
Journal ArticleDOI
The preparation of dimolybdenum(V,V) complexes from molybdenum quadruply bonded metal-metal dimers
TL;DR: In this article, it was shown that the geometry about each molybdenum atoms is a distorted square pyramid with terminal oxygen or sulphur atoms at the apices and in a syn conformation.
Journal ArticleDOI
Photoredox reactions of oxomolybdenum(V) with phosphines
TL;DR: The fluorescent molybdenum(V)oxo complex MoOCl 4 (H 2 O) −, and oxombdenum-vosphine-phosphine complexes derived from it, undergo thermal and photochemical reactions in acetonitrile with the series of phosphines PEt 3, PEt 2 Ph, PEt Ph 2 Ph and PEtPh 2, and PPh 3.
Journal ArticleDOI
Stéréoch1mie en chimie minérale: Complexes moléculaires de l'oxo et du dioxo-vanad1um (V) avec le coordinat fluor et des molécules organiques
TL;DR: In this article, the infrared spectra of the three compounds {VO2F(AA) and {VOF3L2} showed two strong absorptions (in the 800-950 cm−1 region) which are likely to arise from vs and vas(VO2).
Journal ArticleDOI
Magnetic properties, infrared spectroscopy, thermal and theoretical studies of oxomolybdenum(V) complexes with 2,2′-bipyrimidine
TL;DR: Theoretical calculations converged to two stable isomers named cis and trans for MoOCl3(bpym), Mo2O3Cl4(BPym)2 and Mo2Cl6(μ-bpym)6+ units.
References
More filters
Journal ArticleDOI
The Electronic Structures and Spectra of Chromyl and Molybdenyl Ions
Harry B. Gray,Curtis R. Hare +1 more
Journal ArticleDOI
The co-ordination chemistry of molybdenum—I: Some complexes of molybdenum(V) with 2:2′-dipyridyl
TL;DR: In this paper, the preparation and chemical properties of molybdenum(V) with 2:2′-dipyridyl are described and possible structures of the complexes are discussed.
Journal ArticleDOI
890. Halide and oxyhalide complexes of molybdenum and tungsten
Journal ArticleDOI
The co-ordination chemistry of molybdenum—II(1)
TL;DR: In this paper, the ultraviolet, visible and infra-red spectra of the compounds Ba(MoO 2 C 2 O 4 ) 2 5H 2 O and K(Mo O 2C 2O 4 )2·5 H 2 O have been measured and their magnetic moments determined, showing that the complex anion is dimeric in the solid and in solution.
Journal ArticleDOI
Complexes of molybdenum (V) oxide trichloride with nitrogen and phosphorus ligands
TL;DR: In this article, the reaction of molybdenum (V) oxidetrichloride with aliphatic nitriles (RCN, R = Me, Et, Pr) results in the formation of the complexes, MoOCl 3, 2RCN.
Related Papers (5)
Chemistry of oxo-metal ions-VI 1,10-phenanthrolinium oxopentachloromolybdate(V) and its derivatives
H.K. Saha,M.C. Halder +1 more
Chemistry of oxometal ions—IV 2,2′-bipyridyl complexes of quinquevalent molybdenum
H.K. Saha,A.K. Banerjee +1 more
Chemistry of oxometal-ions—V: 1, 10-phenanthrolinium oxopentabromolybdate(v) and its derivatives
H.K. Saha,A.K. Banerjee +1 more