Journal ArticleDOI
Stéréoch1mie en chimie minérale: Complexes moléculaires de l'oxo et du dioxo-vanad1um (V) avec le coordinat fluor et des molécules organiques
TLDR
In this article, the infrared spectra of the three compounds {VO2F(AA) and {VOF3L2} showed two strong absorptions (in the 800-950 cm−1 region) which are likely to arise from vs and vas(VO2).About:
This article is published in Journal of Molecular Structure.The article was published on 1974-01-01. It has received 10 citations till now.read more
Citations
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Journal ArticleDOI
Medium and high oxidation state metal/non-metal fluoride and oxide–fluoride complexes with neutral donor ligands
TL;DR: In this article, the coordination chemistry of d, f and p-block fluorides and oxide fluorides with neutral ligands with donor atoms drawn from Groups 15 and 16 and including N-heterocyclic carbenes is discussed, and differences in properties compared to complexes containing the heavier halides are illustrated.
Journal ArticleDOI
Complexes of Vanadium(V) oxide trifluoride with nitrogen and oxygen donor ligands: Coordination chemistry and some fluorination reactions
TL;DR: In this paper, the geometry of VOF3(MeCN) is characterized by micro-analysis, IR, UV/Vis and multinuclear NMR [51V, 19F{1H, 31P{ 1H}, 1H] spectroscopy, the data showing them to besixcoordinate with trans F-V-F units and the neutralligands trans to O and F, respectively.
Journal ArticleDOI
Synthesis, chemistry and structures of complexes of the dioxovanadium(V) halides VO2F and VO2Cl
Martin F. Davis,Marek Jura,Alethea Leung,William Levason,Benjamin T. R. Littlefield,Gillian Reid,Michael Webster +6 more
TL;DR: Neither VO2F nor VO2Cl form isolable complexes with MeCN, thf or MeO(CH2)2OMe, and both are reduced by P-, As-, S- or Se-donor ligands.
Journal ArticleDOI
Synthesis, properties and structures of NbOF3 complexes and comparisons with NbOCl3 analogues.
TL;DR: The first series of complexes of niobium(v) oxide trifluoride have been prepared, either by reaction of the corresponding complexes of NbF5 and hexamethyldisiloxane (HMDSO) in CH2Cl2-MeCN solution, or directly from Nb F5, ligand and HMDSO.
Journal ArticleDOI
Dioxofluoro-oxalato-vanadat: ein fünffach koordiniertes, monomeres Komplexion des Vanadins(V)
H. Rieskamp,R. Mattes +1 more
TL;DR: In this article, Vanadin et al. reported that vanadium is trigonal bipyramidally coordinated by two terminal oxygen atoms in cis position, fluorine and a bidentate oxalate ion.
References
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Journal ArticleDOI
Properties of Metal-to-Oxygen Multiple Bonds, Especially Molybdenum-to-Oxygen Bonds
F. A. Cotton,R. M. Wing +1 more
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Infra-red studies of pyridine N-oxide and its Co(II), Ni(II), Cu(II), Zn(II), Al(III), Cr(III), Fe(II), Fe(III) and Sn(IV) complexes in the 3–15 μ region
S. Kida,S. Kida,J.V. Quagliano,J.V. Quagliano,J. A. Walmsley,J. A. Walmsley,S. Y. Tyree,S. Y. Tyree +7 more
TL;DR: In this article, the infra-red spectra of various types of complexes of pyridine Noxide with cobalt(II), nickel, zinc, aluminum, chromium, iron, and tin were measured in the 3-15 μ region.
Journal ArticleDOI
The Donor Properties of 2,2'-Bipyridine N,N'-Dioxide
Journal ArticleDOI
Metal-ligand stretching, N-O stretching and C-H out-of-plane bending vibrations of pyridine N-oxide and hexakis (pyridine N-oxide) metal perchlorates
TL;DR: In this article, the spectral properties of pyridine N-oxide and its metal complexes were investigated in the 2000-300 cm−1 region and the frequencies of the metal-ligand stretching, of the N-O stretching and of the CH out-of-plane bending vibrations were found to be closely correlated.