Collective dynamics in water by high energy resolution inelastic X-ray scattering.

TLDR: Thevd of liquid water proposed the exis-tence of high frequency collective excitations which prop-agate with a velocity much higher than that of ordinary sound (fast sound), which would coexist with the ordinary sound, and propagate up to momentum trans-fer comparable with the inverse of the single moleculesize.

Abstract: A propagating excitation with a velocity of sound of $3200\ifmmode\pm\else\textpm\fi{}100$ $\mathrm{m}/\mathrm{s}$ is measured in ${\mathrm{H}}_{2}\mathrm{O}$ at 294 $\mathrm{K}$ between 4 and 14 ${\mathrm{nm}}^{\ensuremath{-}1}$, using inelastic x-ray scattering with 5 $\mathrm{meV}$ energy resolution. The existence of fast sound is therefore demonstrated in an energy-momentum region much wider than that of previous neutron measurements on ${\mathrm{D}}_{2}\mathrm{O}$. The equivalence of the fast sound velocity in ${\mathrm{H}}_{2}\mathrm{O}$ and in ${\mathrm{D}}_{2}\mathrm{O}$ rules out models where this mode propagates only on the hydrogen network. These results show the ability of inelastic x-ray scattering to study the collective dynamics of liquids.