Journal ArticleDOI
Composition of the critical nucleus in multicomponent vapor nucleation
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This article is published in Journal of Chemical Physics.The article was published on 1984-02-01. It has received 197 citations till now. The article focuses on the topics: Nucleation.read more
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BookDOI
Fundamentals of Inhomogeneous Fluids
TL;DR: Development of theories of inhomogeneous fluids, J.R. Rowlinson statistical mechanical sum rules, Douglas Henderson density functionals in the theory of non-uniform fluids, and kinetic theory of strongly inhomogeneity fluids.
Journal ArticleDOI
Nucleation and Growth of Nanoparticles in the Atmosphere
TL;DR: Nucleation and Growth of Nanoparticles in the Atmosphere Renyi Zhang,* Alexei Khalizov, Lin Wang, Min Hu, and Wen Xu.
Journal ArticleDOI
Parameterizations for sulfuric acid/water nucleation rates
TL;DR: In this article, the authors present parameterized equations for calculation of sulfuric acid/water critical nucleus compositions and homogeneous nucleation rates, which are in agreement with the thermodynamically consistent version of classical binary homogeneous nuclear nucleation theory incorporating the hydration effect.
Journal ArticleDOI
A general relation between the nucleation work and the size of the nucleus in multicomponent nucleation
David W. Oxtoby,Dimo Kashchiev +1 more
TL;DR: In this paper, a general theorem that relates the variation of the work of formation of the critical nucleus with chemical potential and the size and composition of critical nuclei was proved. But the results applied to the smallest nuclei of a few molecules only.
References
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Journal ArticleDOI
The Kinetics of Phase Transitions in Binary Systems
TL;DR: In this paper, a kinetic theory of phase transitions in two component systems is presented which is applicable to the transitions, vapor to liquid and liquid to liquid, characterized by a two-dimensional vector which can be used in conjunction with the equation of continuity to develop a partial differential equation which determines the kinetics of the process.
Journal ArticleDOI
Experimental studies on the applicability of the Kelvin equation to highly curved concave menisci
TL;DR: In this article, a series of experiments designed to test the validity of the Kelvin equation by direct measurement of the mean radius of curvature of the surface of cyclohexane condensed between crossed mica cylinders was conducted.
Journal ArticleDOI
Self‐Nucleation in the Sulfuric Acid‐Water System
TL;DR: In this paper, the authors adapted Howard Reiss' ''Vector model'' to calculate the self-nucleation rate for the sulfuric acid water system and similar systems and concluded that rapid self-Nucleation would take place at sulfur acid partial pressures in the range 10−8−10−10 mm Hg.
Journal ArticleDOI
Determination of dipole coupling constants using heteronuclear multiple quantum NMR
TL;DR: In this article, the problem of extracting dipole couplings from a system of N spins I = 1/2 and one spin S by NMR techniques is analyzed, with particular emphasis being placed on the superior resolution available in HMQ spectra.
Journal ArticleDOI
Condensation of a supersaturated vapor. III. The homogeneous nucleation of CCl4, CHCl3, CCl3F, and C2H2Cl4
TL;DR: The upward thermal diffusion cloud chamber was used to measure the supersaturations required to cause an observed rate of homogeneous nucleation of 2 to 3 drops cm−3⋅sec−1.