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Copolymerization of Ethylene and Acrylates by Nickel Catalysts

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The article was published on 2003-07-31. It has received 58 citations till now. The article focuses on the topics: Ethylene & Nickel.

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Journal ArticleDOI

Coordination polymerization of polar vinyl monomers by single-site metal catalysts.

TL;DR: The aim of this review was to establish ana-C2v-Ligated Catalysts as a stand-alone database of Lanthanide Complexes with a focus on the latter stages of their development in the second half of the 1990s.
Journal ArticleDOI

Palladium and Nickel Catalyzed Chain Walking Olefin Polymerization and Copolymerization

TL;DR: In this paper, the chain walking polymerization mechanism is discussed followed by its implications in olefin polymerization and copolymerization with polar functionalized comonomers, and some recent developments and perspectives on very fast and very slow chain walking catalysts are discussed.
Journal ArticleDOI

Post-metallocenes in the industrial production of polyolefins.

TL;DR: This Review gives a comprehensive overview of post-metallocene polymerization catalysts that have been put into practice and the decisive properties for this success of a given catalyst structure are delineated.
Journal ArticleDOI

Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts

TL;DR: Efforts to probe and developCopolymerizations of polar vinyl monomers with ethylene using more functional group-tolerant late metal catalysts potentially offer an attractive alternative for generating value-added copolymers since ligand variations may provide more control of polymer microstructures and milder reaction conditions would apply.
Journal ArticleDOI

Designing late-transition metal catalysts for olefin insertion polymerization and copolymerization

TL;DR: The examples described in this review showcase the power of the design of well-defined late-metal catalysts for tailored polyolefin synthesis, which may usher in a new era in the polymer industry.
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