Journal ArticleDOI
Coriolis interaction and anharmonic potential function of ozone from the microwave spectra in the excited vibrational states
Takehiko Tanaka,Yonezo Morino +1 more
TLDR
In this article, the microwave absorption spectra of ozone were identified in the excited vibrational states with v1 = 1, v2 = 1 and 2, and v3 = 1.About:
This article is published in Journal of Molecular Spectroscopy.The article was published on 1970-03-01. It has received 222 citations till now. The article focuses on the topics: Excited state.read more
Citations
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Microwave spectrum of formic acid and its isotopic species in D, 13C and 18O. Study of Coriolis resonances between ν7 and ν9 vibrational excited states
TL;DR: In this article, the rotational spectrum of the ground state of H12COOH, H13COH, DCOOH and HCOOD has been investigated and two non-rigid independent rotors were used to obtain a set of parameters which fit the transitions well.
Journal ArticleDOI
The infrared spectrum of cyclotetraoxygen, O4: A theoretical investigation employing the single and double excitation coupled cluster method
TL;DR: In this article, the authors used the coupled cluster single and double excitation (CCSD) method to predict the structure and infrared spectrum of cyclotetraoxygen molecules.
Journal ArticleDOI
The effect of parent internal motion on photofragment rotational distributions: Vector correlation of angular momenta and C2v symmetry breaking in dissociation of AB2 molecules
TL;DR: In this article, a semiclassical calculation is presented that fully accounts for the angular momentum disposal in photodissociation of triatomic molecules, and the contributions to the diatomic fragment rotational distribution from both parent triatom rotation and zero point bending vibration are computed.
Journal ArticleDOI
Ab Initio Study on the Mechanism of the Atmospheric Reaction OH+O3→HO2+O2
TL;DR: The different methodologies employed in this paper consistently predict the barrier height of reaction (1) to be within the range 2.16-5.11 kcal mol-1, somewhat higher than the experimental value of 2.0 kcal Mol-1.
Journal ArticleDOI
Millimeter wave spectrum of ozone
TL;DR: In this paper, the microwave transitions of O3 have been observed to the frequency of 320 GHz, and the spectrum recalculated to obtain new rotational constants for the molecule, including the Stark effect.
References
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Journal ArticleDOI
Calculation of inertia defect: Part I. General formulation
Takeshi Oka,Yonezo Morino +1 more
TL;DR: In this paper, a general formula for inertia defect of a molecule is presented following Nielsen's theory of vibration-rotation interaction, simplified by the use of general properties of 1 matrix which transforms the normal coordinates to the Cartesian coordinates.
Journal ArticleDOI
Equilibrium structure and potential function of sulfur dioxide from the microwave spectrum in the excited vibrational state
TL;DR: In this paper, the microwave spectra of the SO2 molecule were measured in the first excited states of all the normal vibrations as well as in the second excited state of the ν2 vibration.
Journal ArticleDOI
The Molecular Structure, Dipole Moment, and g Factor of Ozone from Its Microwave Spectrum
TL;DR: In this paper, four low-J rotational transitions of 0316 have been measured in the region from 42 to 118 kmc and the rotational spectroscopic constants found are A = 106,530.0±1.1 Mc, B = 13,349.06±0.06 Mc, C = 11,834.3±1 Mc.
Journal ArticleDOI
The infrared spectrum of ozone
David J. McCaa,John H. Shaw +1 more
TL;DR: In this article, 14 bands of ozone between 500 and 3300 cm −1 have been identified and values of the vibrational anharmonic constants determined and the integrated band absorptances of many of these bands have been measured from spectra of a 32-m path of ozone-oxygen mixtures containing up to 30 atm cm O ǫ near 25°C.
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Infrared spectra of 16O3 and 18O3: Darling and Dennison resonance and anharmonic potential function of ozone
Alain Barbe,C. Secroun,P. Jouve +2 more