Journal ArticleDOI
Coriolis interaction and anharmonic potential function of ozone from the microwave spectra in the excited vibrational states
Takehiko Tanaka,Yonezo Morino +1 more
TLDR
In this article, the microwave absorption spectra of ozone were identified in the excited vibrational states with v1 = 1, v2 = 1 and 2, and v3 = 1.About:
This article is published in Journal of Molecular Spectroscopy.The article was published on 1970-03-01. It has received 222 citations till now. The article focuses on the topics: Excited state.read more
Citations
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Possible existence and role of excited ozone precursors in the stratosphere
Sheo S. Prasad,Peter G. Burton +1 more
TL;DR: In this paper, a metastable, energetic, and reactive form of ozone was found in the upper atmosphere and this species can potentially affect the upper atmospheric photochemistry and heat balance, and there is a need for further quantum theoretical and laboratory chemical kinetic studies addressing some of the relevant properties of internally excited ozone precursors.
Journal ArticleDOI
Franck-Condon simulation of photoelectron spectroscopy of HOO- : Including Duschinsky effects
TL;DR: In this paper, the electron affinity and the term energy (X ∼ 2 A ) of HOO were calculated at various theory levels, and spectral simulations of vibrational structures based on the computed Franck-Condon factors are in excellent agreement with the observed spectra.
Journal ArticleDOI
Radiative Transfer of Atomic and Molecular Resonant Emissions in the Upper Atmospheres II
Takao Tohmatsu,Hiromasa Yamamoto +1 more
TL;DR: In this paper, a theory of radiative transfer has been developed which describes quantitatively the radiative features of resonant atomic and molecular emissions in the upper stratosphere, mesosphere and the thermosphere.
Journal ArticleDOI
Structures and vibrational frequencies of NaO3 and NaO3+: the ionization energy of NaO3
TL;DR: In this paper, the authors used high-level ab initio, up to RCCSD(T), and the density functional theory (DFT) method, B3LYP, to obtain the geometry, vibrational frequencies, and heats of formation of NaO3(X~2B1) and NaO 3+(X~1A1).
Journal ArticleDOI
The optically pumped ozone laser
TL;DR: In this article, the CW observation and assignment of 7 lines of 16O3 pumped by a CO2 laser are reported. And the frequency measurement of one line of 18O3 has also been obtained.
References
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Journal ArticleDOI
Calculation of inertia defect: Part I. General formulation
Takeshi Oka,Yonezo Morino +1 more
TL;DR: In this paper, a general formula for inertia defect of a molecule is presented following Nielsen's theory of vibration-rotation interaction, simplified by the use of general properties of 1 matrix which transforms the normal coordinates to the Cartesian coordinates.
Journal ArticleDOI
Equilibrium structure and potential function of sulfur dioxide from the microwave spectrum in the excited vibrational state
TL;DR: In this paper, the microwave spectra of the SO2 molecule were measured in the first excited states of all the normal vibrations as well as in the second excited state of the ν2 vibration.
Journal ArticleDOI
The Molecular Structure, Dipole Moment, and g Factor of Ozone from Its Microwave Spectrum
TL;DR: In this paper, four low-J rotational transitions of 0316 have been measured in the region from 42 to 118 kmc and the rotational spectroscopic constants found are A = 106,530.0±1.1 Mc, B = 13,349.06±0.06 Mc, C = 11,834.3±1 Mc.
Journal ArticleDOI
The infrared spectrum of ozone
David J. McCaa,John H. Shaw +1 more
TL;DR: In this article, 14 bands of ozone between 500 and 3300 cm −1 have been identified and values of the vibrational anharmonic constants determined and the integrated band absorptances of many of these bands have been measured from spectra of a 32-m path of ozone-oxygen mixtures containing up to 30 atm cm O ǫ near 25°C.
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Infrared spectra of 16O3 and 18O3: Darling and Dennison resonance and anharmonic potential function of ozone
Alain Barbe,C. Secroun,P. Jouve +2 more