Journal ArticleDOI
Coriolis interaction and anharmonic potential function of ozone from the microwave spectra in the excited vibrational states
Takehiko Tanaka,Yonezo Morino +1 more
TLDR
In this article, the microwave absorption spectra of ozone were identified in the excited vibrational states with v1 = 1, v2 = 1 and 2, and v3 = 1.About:
This article is published in Journal of Molecular Spectroscopy.The article was published on 1970-03-01. It has received 222 citations till now. The article focuses on the topics: Excited state.read more
Citations
More filters
Journal ArticleDOI
Infrared diode laser spectrum of the ν1 band of CF2 (X̃ 1A1)
TL;DR: In this article, the ν1 fundamental band of difluorocarbene (CF2) in its ground electronic state has been investigated using diode laser absorption spectroscopy.
Journal ArticleDOI
Microwave spectrum of sulfur difluoride in the first excited vibrational states vibrational potential function and equilibrium structure
TL;DR: In this article, a comparison of the observed inertia defects in the ν1 and ν3 states with those calculated by omitting the contributions of the Coriolis interaction between the two modes led to a ν 1 - ν 3 vibrational frequency differences of 25.72 ± 0.33 cm−1.
Journal ArticleDOI
The effect of correlation on molecular magnetizabilities and rotational g tensors
TL;DR: In this article, the effect of electron correlation on molecular magnetizabilities and rotational g tensors is investigated using multiconfigurational self-consistent field wave functions and perturbation-dependent basis sets.
Journal ArticleDOI
Photofragment excitation spectrum for O(1D) from the photodissociation of jet-cooled ozone in the wavelength range 305–329 nm
TL;DR: The photofragment excitation (PHOFEX) spectrum for O(1D) production from the photolysis of ozone under supersonic free-jet conditions was measured, scanning the photodissociation wavelength in the region of 305-329 nm and probing the O( 1D) atoms by vacuum ultraviolet laser induced fluorescence at 115.2 nm.
Journal ArticleDOI
Accurate electric dipole and quadrupole moment, dipole polarizability, and first and second dipole hyperpolarizability of ozone from coupled cluster calculations
TL;DR: In this article, the authors reported accurate values for the dipole (μ) and quadrupole (Θ) moment, dipole polarizability, and first and second dipole hyperpolarizability of ozone.
References
More filters
Journal ArticleDOI
Calculation of inertia defect: Part I. General formulation
Takeshi Oka,Yonezo Morino +1 more
TL;DR: In this paper, a general formula for inertia defect of a molecule is presented following Nielsen's theory of vibration-rotation interaction, simplified by the use of general properties of 1 matrix which transforms the normal coordinates to the Cartesian coordinates.
Journal ArticleDOI
Equilibrium structure and potential function of sulfur dioxide from the microwave spectrum in the excited vibrational state
TL;DR: In this paper, the microwave spectra of the SO2 molecule were measured in the first excited states of all the normal vibrations as well as in the second excited state of the ν2 vibration.
Journal ArticleDOI
The Molecular Structure, Dipole Moment, and g Factor of Ozone from Its Microwave Spectrum
TL;DR: In this paper, four low-J rotational transitions of 0316 have been measured in the region from 42 to 118 kmc and the rotational spectroscopic constants found are A = 106,530.0±1.1 Mc, B = 13,349.06±0.06 Mc, C = 11,834.3±1 Mc.
Journal ArticleDOI
The infrared spectrum of ozone
David J. McCaa,John H. Shaw +1 more
TL;DR: In this article, 14 bands of ozone between 500 and 3300 cm −1 have been identified and values of the vibrational anharmonic constants determined and the integrated band absorptances of many of these bands have been measured from spectra of a 32-m path of ozone-oxygen mixtures containing up to 30 atm cm O ǫ near 25°C.
Related Papers (5)
Infrared spectra of 16O3 and 18O3: Darling and Dennison resonance and anharmonic potential function of ozone
Alain Barbe,C. Secroun,P. Jouve +2 more