Coupling Gliding Discharge Treatment and Catalysis by Oyster Shell Powder for Pollution Abatement of Surface Waters

TLDR: Adsorption on oyster shell powder (OS) was combined with gliding electric discharge to abate pollution of surface waters sampled in brooks passing through large Cameroonian cities and collecting industrial and domestic wastes.

Abstract: Adsorption on oyster shell powder (OS) was combined with gliding electric discharge to abate pollution of surface waters sampled in brooks passing through large Cameroonian cities and collecting industrial and domestic wastes. OS powder incorporated into the aqueous samples after exposure to the discharge improved pollutant abatement as compared to the plasma treatment alone. The process kinetics involved pseudo zero-order reactions for treatments longer than 5 min. Total organic carbon linearly decreases with increasing exposure time to the discharge (k ≈ 0.13 mgC L−1 min−1 for a 1 g L−1 standard OS charge). The rate constant linearly increases with the incorporated OS mass, which increases the sample pH. The coupled process is more efficient than a single plasma treatment of the polluted liquid in terms of operation cost, waste abatement ratio, and reaction rate. A chemical model involving known plasma generated species and matching acid−base effects is proposed.

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November 18, 2009
Volume 48, Issue 22
Pages 9773-10162
APPLIED CHEMISTRY KINETICS, CATALYSIS, AND
REACTION ENGINEERING
MATERIALS AND INTERFACES
PROCESS DESIGN AND CONTROL
SEPARATIONS GENERAL RESEARCH RESEARCH NOTES
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APPLIED CHEMISTRY
Section:
Water
Coupling Gliding Discharge Treatment and Catalysis by Oyster Shell Powder for
Pollution Abatement of Surface Waters
Estella Njoyim, Paul Ghogomu, Samuel Laminsi, Serge Nzali, Avaly Doubla and Jean-Louis Brisset
pp 9773–9780
Publication Date (Web): September 28, 2009
(Article)
DOI: 10.1021/ie901118m
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Section:
Fermentation and Bioindustrial
Chemistry
Novel Carrier of Grafted Alginate for Covalent Immobilization of Inulinase
Magdy M. M. Elnashar, Enas N. Danial and Ghada E. A. Awad
pp 9781–9785
Publication Date (Web): September 18, 2009
(Article)
DOI: 10.1021/ie9011276
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Participation of Electrochemical Steps in Treating Tannery Wastewater
C. Ahmed Basha, P. A. Soloman, M. Velan, N. Balasubramanian and L. Roohil Kareem
pp 9786–9796
Publication Date (Web): October 9, 2009
(Article)
DOI: 10.1021/ie900464s
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Section:
Textiles and Fibers
Formation of Highly Hydrophobic Surfaces on Cotton and Polyester Fabrics Using
Silica Sol Nanoparticles and Nonfluorinated Alkylsilane
Qinwen Gao, Quan Zhu and Yuliang Guo, Charles Q. Yang
pp 9797–9803
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(Article)
DOI: 10.1021/ie9005518
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Adsorption of Copper Acetate onto Pretreated Activated Carbons over a Wide
Concentration Range
Amjad Farooq, Philippe Westreich, Naseem Irfan and Jeff Dahn
pp 9804–9808
Publication Date (Web): September 23, 2009
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DOI: 10.1021/ie900492f
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Physical Organic Chemistry
Thermochemistry of Ionic Liquid-Catalyzed Reactions: Theoretical and
Experimental Study of the Beckmann Rearrangement—Kinetic or Thermodynamic
Control?
Sergey P. Verevkin, Vladimir N. Emel’yanenko and Alexey V. Toktonov, Peter Goodrich and
Christopher Hardacre
pp 9809–9816
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DOI: 10.1021/ie900633r
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Modeling the Effects of Color on the UV Protection Provided by Cotton Woven
Fabrics Dyed with Azo Dyestuffs
Ascension Riva, Ines Algaba, Montserrat Pepio and Remedios Prieto
pp 9817–9822
Publication Date (Web): September 23, 2009
(Article)
DOI: 10.1021/ie9006694
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Plastics Manufacture and
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Preparation of Biomimetic Materials Made from Polyaspartyl Polymer and Chitosan
for Heavy-Metal Removal
Bo Sun, Zhen-Tao Mi, Gang An, Guozhu Liu and Ji-Jun Zou
pp 9823–9829
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Cellulose, Lignin, Paper, and Other
Wood Products
Bleaching Miscanthus x giganteus Acetosolv Pulps with a New Totally Chlorine-
free Sequence and the Effect of Carbohydrate Protectors
Juan Jose Villaverde, Pablo Ligero and Alberto de Vega
pp 9830–9836
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KINETICS, CATALYSIS, AND REACTION ENGINEERING
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Formation of Tarry Material from 5-HMF in Subcritical and Supercritical Water
Athika Chuntanapum and Yukihiko Matsumura
pp 9837–9846
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Adsorption and Desorption of SO
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Oliver Krocher, Markus Widmer, Martin Elsener and Dieter Rothe
pp 9847–9857
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Importance of Biomass Particle Size in Structural Evolution and Reactivity of Char
in Steam Gasification
Mohammad Asadullah, Shu Zhang, Zhenhua Min, Piyachat Yimsiri and Chun-Zhu Li
pp 9858–9863
Publication Date (Web): August 27, 2009
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Photochemistry, and Photographic
and Other Reprographic Processes
Energy Efficiency in Photocatalytic Reactors for the Full Span of Reaction Times
Benito Serrano, Aaron Ortiz, Jesus Moreira and Hugo I. de Lasa
pp 9864–9876
Publication Date (Web): October 26, 2009
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DOI: 10.1021/ie900353n
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Electrochemical, Radiational, and
Thermal Energy Technology
Kinetic Characterization of Xylose Monomer and Oligomer Concentrations during
Dilute Acid Pretreatment of Lignocellulosic Biomass from Forests and
Switchgrass
Juan E. Morinelly, Jill R. Jensen, Matthew Browne, Tomas B. Co and David R. Shonnard
pp 9877–9884
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Effect of Magnesium Addition to PtSnNa/ZSM-5 on the Catalytic Properties in the
Dehydrogenation of Propane
Linyang Bai, Yuming Zhou, Yiwei Zhang, Hui Liu and Xiaoli Sheng
pp 9885–9891
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Section:
Extractive Metallurgy
Kinetics of the Acid Digestion of Serpentine with Concurrent Grinding. 2. Detailed
Investigation and Model Development
Dirk T. Van Essendelft and Harold H. Schobert
pp 9892–9901
Publication Date (Web): August 28, 2009
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DOI: 10.1021/ie9005832
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Waste Treatment and Disposal
Wet Oxidation of Thiocyanate under Different pH Conditions: Kinetics and
Mechanistic Analysis
Sergio Collado, Adriana Laca and Mario Diaz
pp 9902–9909
Publication Date (Web): September 11, 2009
(Article)
DOI: 10.1021/ie9006485
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Biomolecules and Their Synthetic
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Intrinsic Kinetics of Catalytic Hydrogenation of Cardanol
Zhi-Bo Mao, Ting-Liang Luo, Hong-Tao Cheng, Miao Liang and Guo-Ji Liu
pp 9910–9914
Publication Date (Web): September 1, 2009
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DOI: 10.1021/ie900655a
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Degradation of Methylene Blue by Heterogeneous Fenton Reaction Using
Titanomagnetite at Neutral pH Values: Process and Affecting Factors
Shijian Yang, Hongping He, Daqing Wu, Dong Chen, Yuehong Ma, Xiaoli Li, Jianxi Zhu and Peng Yuan
pp 9915–9921
Publication Date (Web): September 10, 2009
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DOI: 10.1021/ie900666b
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MATERIALS AND INTERFACES
Section:
Cellulose, Lignin, Paper, and Other
Wood Products
Steam-Generating Composite Sheets Prepared Using Techniques in the
Papermaking Process. 1. Effective Retention of Iron Powder in a Sheet Using
Fibrillated Cellulose Fibers
Yoshiaki Kumamoto, Masataka Ishikawa, Hironobu Kawajiri, Takeshi Nakajima and Akira Isogai
pp 9922–9929
Publication Date (Web): October 6, 2009
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DOI: 10.1021/ie900875u
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Steam-Generating Composite Sheets Prepared Using Techniques in the
Papermaking Process. 2. Relationships between Sheet Structures and Steam-
Generation Behavior
Yoshiaki Kumamoto, Masataka Ishikawa, Hironobu Kawajiri, Kuniyuki Nakanishi and Akira Isogai
pp 9930–9935
Publication Date (Web): October 6, 2009
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DOI: 10.1021/ie900876s
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Electrochemical, Radiational, and
Thermal Energy Technology
Enhancement of the Meltdown Temperature of a Lithium Ion Battery Separator via
a Nanocomposite Coating
S. H. Yoo and C. K. Kim
pp 9936–9941
Publication Date (Web): September 24, 2009
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DOI: 10.1021/ie901141u
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http://pubs.acs.org/toc/iecred/48/22

Section:
Plastics Manufacture and
Processing
Rheology, Morphology, Mechanical Properties and Free Volume of Poly
(trimethylene terephthalate)/Polycarbonate Blends
Indose Aravind, Kyung Hyun Ahn, C. Ranganathaiah and Sabu Thomas
pp 9942–9951
Publication Date (Web): July 31, 2009
(Article)
DOI: 10.1021/ie9007503
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Section:
Plastics Manufacture and
Processing
Measurements and Correlation of Octyltriethoxysilane Solubility in Supercritical
CO
2
and Assembly of Functional Silane Monolayers on the Surface of Nanometric
Particles
Carlos A. Garcia-Gonzalez, Julio Fraile, Ana Lopez-Periago, Javier Saurina and Concepcion Domingo
pp 9952–9960
Publication Date (Web): September 23, 2009
(Article)
DOI: 10.1021/ie900775z
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Unit Operations and Processes
Managing Distribution in Supply Chain Networks
Rodolfo Dondo, Carlos A. Mendez and Jaime Cerda
pp 9961–9978
Publication Date (Web): September 9, 2009
(Article)
DOI: 10.1021/ie900792s
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Section:
Unit Operations and Processes
Efficient Numerical Solver for Partially Structured Differential and Algebraic
Equation Systems
Flavio Manenti, Ivan Dones, Guido Buzzi-Ferraris and Heinz A. Preisig
pp 9979–9984
Publication Date (Web): September 15, 2009
(Article)
DOI: 10.1021/ie9007908
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Methodology for Designing and Comparing Robust Linear versus Gain-Scheduled
Model Predictive Controllers
Rosendo Diaz-Mendoza, Jianying Gao and Hector Budman
pp 9985–9998
Publication Date (Web): October 1, 2009
(Article)
DOI: 10.1021/ie900309s
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Section:
Electrochemical, Radiational, and
Thermal Energy Technology
Integrated Analysis of Energy, Economic, and Environmental Performance of
Biomethanol from Rice Straw in China
Jun Xiao, Laihong Shen, Yanan Zhang and Jiqing Gu
pp 9999–10007
Publication Date (Web): September 1, 2009
(Article)
DOI: 10.1021/ie900680d
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SEPARATIONS
Section:
Unit Operations and Processes
Mass Transfer Enhancement in Liquid−Liquid Extraction with Very Dilute Aqueous
Salt Solutions
Javad Saien and Fatemeh Ashrafi
pp 10008–10014
Publication Date (Web): September 15, 2009
(Article)
DOI: 10.1021/ie900542w
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Section:
Surface Chemistry and Colloids
Adsorption and Diffusion of Carbon Dioxide on Metal−Organic Framework (MOF-5)
Zhenxia Zhao, Zhong Li and Y. S. Lin
pp 10015–10020
Publication Date (Web): September 11, 2009
(Article)
DOI: 10.1021/ie900665f
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3/11/2012
http://pubs.acs.org/toc/iecred/48/22