Journal ArticleDOI
Crystal engineering of hybrid inorganic–organic systems based upon complexes with dissymmetric compartmental ligands
TLDR
In this paper, the versatility of mono-and heterobinuclear complexes with dissymmetric compartmental ligands in designing molecular and supramolecular heterometallic systems was illustrated.Abstract:
This paper illustrates the versatility of mono- and heterobinuclear complexes with dissymmetric compartmental ligands in designing molecular and supramolecular heterometallic systems. Mononuclear complexes with side-off bicompartmental ligands derived from o-vanillin act efficiently, through their empty compartment, as hydrogen-bond receptors and as second coordination sphere ligands. These Schiff- bases are also suitable for synthesizing 3d-3d′ and 3d-4f heterobinuclear complexes. Both 3d-3d′ and 3d-4f complexes can be employed as nodes in obtaining coordination polymers with various dimensionalities and network topologies, as well as interesting magnetic and optical properties.read more
Citations
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Compartmental Schiff-base ligands--a rich library of tectons in designing magnetic and luminescent materials.
TL;DR: 3d-3d' and 3d-4f complexes are useful precursors in designing heterotrimetallic systems with relevance in molecular magnetism.
Journal ArticleDOI
Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆
Jesús Ferrando-Soria,Julia Vallejo,María Castellano,José Martínez-Lillo,Emilio Pardo,Joan Cano,Isabel Castro,Francesc Lloret,Rafael Ruiz-García,Miguel Julve +9 more
TL;DR: Molecular magnetism has travelled a long way from the pioneering studies on electron exchange and double exchange or spin crossover and valence tautomerism in small oligonuclear complexes, from mono-to di-and tetranuclear species, to the current investigations about magnetic anisotropy and spin dynamics or quantum coherence of simple mono- or large polynuclear complexes.
Journal ArticleDOI
Molecularly designed architectures – the metalloligand way
Girijesh Kumar,Rajeev Gupta +1 more
TL;DR: The present review is expected to provide new strategies for constructing functional materials through metalloligands for challenging and practical applications by focusing on the recent progress achieved through assorted molecular building blocks towards generating ordered networks.
Journal ArticleDOI
The exceptionally rich coordination chemistry generated by Schiff-base ligands derived from o-vanillin.
TL;DR: This paper reviews recent data that illustrate a very fertile and dynamic research field in coordination chemistry and materials science.
Journal ArticleDOI
Study of the luminescent and magnetic properties of a series of heterodinuclear [Zn(II)Ln(III)] complexes.
Traian D. Pasatoiu,Carmen Tiseanu,Augustin M. Madalan,Bogdan Jurca,Carine Duhayon,Carine Duhayon,Jean-Pascal Sutter,Jean-Pascal Sutter,Marius Andruh +8 more
TL;DR: The synthesis, structural investigation, and magnetic and photophysical properties of a series of 13 heterodinuclear complexes, which have been obtained employing a Schiff-base compartmental ligand derived from o-vanillin, have been reported.
References
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