Journal ArticleDOI
Development and advancement of iridium(III)-based complexes for photocatalytic hydrogen evolution
TLDR
In this article , a review of the design and evaluation of transition metal compounds as photocatalysts/photosensitizers for hydrogen evolution reactions has been presented, where photo-redox mechanisms are addressed, and structure-catalytic activity relationships are identified.About:
This article is published in Coordination Chemistry Reviews.The article was published on 2022-05-01. It has received 26 citations till now. The article focuses on the topics: Photocatalysis & Iridium.read more
Citations
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Journal ArticleDOI
ZnIn2S4-based photocatalysts for photocatalytic hydrogen evolution via water splitting
Yuqi Yang,Xin-Ya Zheng,Yiming Song,Yuhao Liu,Daoxiong Wu,Jing Li,Weifeng Liu,Lirong Fu,Yijun Shen,Xinlong Tian +9 more
TL;DR: Zinc indium sulfide (ZnIn2S4) has attracted extensive research interest in PHE application due to its excellent semiconductor properties, like nontoxicity, suitable band gap, and high stability as mentioned in this paper .
Journal ArticleDOI
An efficient photo Fenton system for in-situ evolution of H2O2via defective iron-based metal organic framework@ZnIn2S4 core-shell Z-scheme heterojunction nanoreactor.
TL;DR: In this article , a core@shell Z-scheme heterojunction nanoreactor was successfully fabricated, in which hierarchical two-dimensional (2D) ZnIn2S4 nanosheets are coated on defective iron-based metal-organic frameworks (MOFs) (NH2-MIL-88B(Fe)), realizing efficient in-situ evolution of H2O2 and constructing an optimal heterogeneous Fenton platform.
Journal ArticleDOI
Recent developments of photoactive Cu(I) and Ag(I) complexes with diphosphine and related ligands
TL;DR: In this article , the relationship between the photophysical properties and the characteristics of ligands is discussed, which has a significant impact on the practical applications and utilization of Cu(I) complexes in photochemical reactions.
Journal ArticleDOI
Long-lived excited states of platinum(II)-porphyrins for co-catalyst-free solar-driven hydrogen evolution
Govardhana Babu Bodedla,Yue Dong,Geliang Tang,Jianzhang Zhao,Fuxiang Zhang,Xunjin Zhu,Wai Yeung Wong +6 more
TL;DR: In this article , two Pt(II)-porphyrins conjugated with naphthalimide (NI) chromophore, PtT(p-NI)PP and PtD(p)-NIPP, are synthesized in excellent yields and characterized by photophysical, electrochemical, and density functional theory studies.
Journal ArticleDOI
Photostable aggregation-induced emission of iridium(III) complex realizing robust and high-resolution imaging of latent fingerprints
TL;DR: In this paper , a handy structural design strategy based on iridium(III) complexes for the creation of photostable AIEgens is reported, where the synergistic effect of phenyl and carbazole improves the rotational activity of substituents, then activates the aggregation-induced emission property of iridium-III complexes with considerably improved photostability.
References
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Journal ArticleDOI
Powering the planet: Chemical challenges in solar energy utilization
Nathan S. Lewis,Daniel G. Nocera +1 more
TL;DR: Solar energy is by far the largest exploitable resource, providing more energy in 1 hour to the earth than all of the energy consumed by humans in an entire year, and if solar energy is to be a major primary energy source, it must be stored and dispatched on demand to the end user.
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Aggregation-induced emission of 1-methyl-1,2,3,4,5-pentaphenylsilole
Jingdong Luo,Zhiliang Xie,Jacky W. Y. Lam,Lin Cheng,Haiying Chen,Chengfeng Qiu,Hoi Sing Kwok,Xiaowei Zhan,Yunqi Liu,Daoben Zhu,Ben Zhong Tang +10 more
TL;DR: Aggregation greatly boosts emission efficiency of the silole, turning it from a weak luminophor into a strong emitter.
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Metal-Free Organic Dyes for Dye-Sensitized Solar Cells: From Structure: Property Relationships to Design Rules
TL;DR: Recent advances in molecular design and technological aspects of metal-free organic dyes for applications in dye-sensitized solar cells are focused on.
Journal ArticleDOI
Recent developments in heterogeneous photocatalysts for solar-driven overall water splitting
TL;DR: In this article, a review summarizes the basics of overall water splitting via both one-step excitation and Z-scheme processes, with a focus on standard methods of determining photocatalytic performance.
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Splitting water with cobalt.
TL;DR: Cobalt has emerged in the past five years as the most versatile non-noble metal for the development of synthetic H( 2)- and O(2)-evolving catalysts, which can be further coupled with photosensitizers to generate photocatalytic systems for light-induced hydrogen evolution from water.
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