Die Kristall- und Molekülstruktur des Hexaphenyldiplumbans

TLDR: The crystal and molecular structure of (C6H5)6Pb2 (space group and lattice parameters see above) has been newly determined from 4541 independent reflexes by the heavy atom method; the positions of all atoms, except the H atoms have been refined to give R = 0.053 as mentioned in this paper.

Abstract: Die Kristall- und Molekulstruktur von (C6H5)6Pb2 (Raumgruppe P21/c [C]; a = 17,16(1), b = 9,410(2), c = 21,60(2) A; β = 116,8(2)° Z = 4 [1, 2]) wurde anhand von 4541 unabhangigen Reflexen nach der Schweratommethode neu bestimmt und die Atomlagen bis auf die der Wasserstoffatome ermittelt (R-Wert = 0,053). Die Elementarzelle enthalt zwei kristallographisch unabhangige Molekeln. Die Mittelwerte der Bindungsabstande bzw. -winkel betragen Pb–Pb = 2,844 A, Pb–C = 2,222 A; Pb–Pb–C = 110,2°, C–Pb–C = 108,7°. Crystal and Molecular Structure of Hexaphenyldiplumbane The crystal and molecular structure of (C6H5)6Pb2 (space group and lattice parameters see above) has been newly determined from 4541 independent reflexes by the heavy atom method; the positions of all atoms, except the H atoms have been refined to give R = 0.053. The unit cell contains two crystallographically independent molecules. (Mean values of bond lengths and angles see above).