Journal ArticleDOI
π-Bonding and the Lone Pair Effect in Multiple Bonds between Heavier Main Group Elements
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This article is published in Chemical Reviews.The article was published on 1999-12-08. It has received 952 citations till now. The article focuses on the topics: Lone pair & Main group element.read more
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Main-group elements as transition metals
TL;DR: The last quarter of the twentieth century and the beginning decade of the twenty-first witnessed spectacular discoveries in the chemistry of the heavier main-group elements, which led to new structural and bonding insights as well as a gradually increasing realization that the science more resembles that of transition-metal complexes than that of their lighter main- group congeners.
Journal ArticleDOI
π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium
Roland Fischer,Philip P. Power +1 more
TL;DR: The key unifying feature of almost all molecules discussed in this review is that they are generally stabilized by the use of bulky substituents which block associative or various decomposition pathways.
Journal ArticleDOI
Stable Heavier Carbene Analogues
TL;DR: The early silylene research was concerned largely with comparing the chemistry of the dihalosilylenes with that of carbenes, so it might be difficult to isolate metallylenes as stable compounds under ambient conditions.
Journal ArticleDOI
A stable silicon(0) compound with a Si=Si double bond.
Yu-Zhong Wang,Yaoming Xie,Pingrong Wei,R. Bruce King,Henry F. Schaefer,Paul von Ragué Schleyer,Gregory H. Robinson +6 more
TL;DR: Complementary computational studies confirm the nature of the bonding in L:(Cl)Si–Si(Cl):L and L:Si=Si:L, a carbene-stabilized diatomic silicon molecule with the Si atoms in the formal oxidation state of zero.
Journal ArticleDOI
Cyclic (Alkyl)(amino)carbenes (CAACs): Recent Developments
TL;DR: The most important results published up to the end of 2013 are briefly summarized, while the majority of this Review focuses on findings reported within the last three years.
References
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BookDOI
The chemistry of organic silicon compounds
Zvi Rappoport,Yitzhak Apeloig +1 more
TL;DR: A.R.Bassindale and P.G.Taylor as mentioned in this paper discussed the photochemistry of organosilicon compounds, A.R., B.B.Birkofer and O.Ojima.
Journal ArticleDOI
Chemical Bonding in Higher Main Group Elements
TL;DR: In this article, it was shown that the XO bonds in phosphane oxides, sulfoxides, oxo acids and related compounds are better formulated as semipolar rather than as true double bonds, even if they behave in some respects like double bonds.
Related Papers (5)
π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium
Roland Fischer,Philip P. Power +1 more