Journal ArticleDOI
Dynamic combinatorial chemistry.
Peter T. Corbett,Julien Leclaire,Laurent Vial,Kevin R. West,Jean-Luc Wietor,Jeremy K. M. Sanders,Sijbren Otto +6 more
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This article is published in Chemical Reviews.The article was published on 2006-09-01. It has received 1585 citations till now. The article focuses on the topics: Dynamic combinatorial chemistry & Dynamic covalent chemistry.read more
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From supramolecular chemistry towards constitutional dynamic chemistry and adaptive chemistry
TL;DR: Supramolecular chemistry considers chemical objects and systems capable of responding to external solicitations by modification of their constitution through component exchange or reorganisation, and opens the way towards an adaptive and evolutive chemistry, a further step towards the chemistry of complex matter.
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Click Chemistry for Drug Development and Diverse Chemical–Biology Applications
Journal ArticleDOI
Using the dynamic bond to access macroscopically responsive structurally dynamic polymers
TL;DR: The emergence of a new trend in the design of adaptive materials that involves the use of reversible chemistry to programme a response that originates at the most fundamental (molecular) level is described.
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Metathesis Reactions in Total Synthesis
Kyriacos C. Nicolaou,Kyriacos C. Nicolaou,Paul G. Bulger,Paul G. Bulger,David Sarlah,David Sarlah +5 more
TL;DR: Examples of total syntheses in which metathesis reactions of olefins, enynes, and alkynes played a crucial role and which imparted to these endeavors certain elements of novelty, elegance, and efficiency are highlighted.
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Recent advances in dynamic covalent chemistry
TL;DR: The scope of dynamic covalent reactions is rapidly expanding, and the reversible reactions suitable for DCvC are still very limited.
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Stereochemistry of Organic Compounds
TL;DR: Stereochemistry of Alkenes Conformation of Acyclic Molecules Configuration and conformation of cyclic Molecule Stereoselective Synthesis Chiroptical Properties Chirality in Molecules Devoid of Chiral Centres as discussed by the authors.
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Self-Assembly of Discrete Cyclic Nanostructures Mediated by Transition Metals
Journal ArticleDOI
Dynamic covalent chemistry.
Stuart J. Rowan,Stuart Cantrill,Graham R. L. Cousins,Jeremy K. M. Sanders,J. Fraser Stoddart +4 more
TL;DR: Some recent examples where dynamic covalent chemistry has been demonstrated are shown to emphasise the basic concepts of this area of science.
Journal ArticleDOI
A Molecular Orbital Theory of Reactivity in Aromatic Hydrocarbons
TL;DR: In this paper, the electron density at each carbon atom, of the highest occupied π−orbital in the ground state of the molecule is calculated by means of the LCAO method.