Journal ArticleDOI
Dynamic mechanical properties of styrene butadiene rubber and poly (ethylene-co-vinyl acetate) blends
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TLDR
In this article, the effects of cross-linked and uncrosslinked styrene butadiene rubber/poly (ethylene-co-vinyl acetate) (SBR/EVA) blends were studied with reference to the effect of blend ratio, crosslinking systems, a compatibilizer viz. maleic-anhydride grafted poly [styrene-b-(ethyleneco-butylene)-b-styrene] (SEBS-g-MA), frequency and temperature.Abstract:
The dynamic mechanical behaviour of uncrosslinked and crosslinked styrene butadiene rubber/poly (ethylene-co-vinyl acetate) (SBR/EVA) blends was studied with reference to the effects of blend ratio, crosslinking systems, a compatibilizer viz. maleic-anhydride grafted poly [styrene-b-(ethylene-co-butylene)-b-styrene] (SEBS-g-MA), frequency and temperature. The two separate tan δ peaks, obtained during DMA, indicated the immiscibility of SBR/EVA system. The damping properties increased with SBR content for uncrosslinked and crosslinked blends. In the case of crosslinked systems, depending upon the type of crosslinking agent used, the glass transition temperature (T
g) of SBR phase has been found to be shifted to higher temperatures. The damping characteristics of the blends were observed to be affected by the variations in frequency. The addition of the compatibilizer improved the storage modulus and reduced the damping properties. These results have been correlated with the morphology of the blends, attested by scanning electron micrographs. The activation energy for glass transition has been computed. The experimental data on storage modulus were compared with theoretical predictions.read more
Citations
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Journal ArticleDOI
A MARTINI Coarse-Grained Model of a Thermoset Polyester Coating
Giulia Rossi,Ioannis Giannakopoulos,Luca Monticelli,Luca Monticelli,Niko K. J. Rostedt,Sakari R. Puisto,Chris Lowe,Ambrose C. Taylor,Ilpo Vattulainen,Ilpo Vattulainen,Tapio Ala-Nissila,Tapio Ala-Nissila +11 more
TL;DR: In this paper, a coarse-grained model of a typical polyester resin for coil coating applications is presented, and the model estimates the glass transition temperature of the coating within 30 K of the experimental measurement.
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Mechanically robust conductive carbon clusters confined ethylene methyl acrylate–based flexible composites for superior shielding effectiveness
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Thermally conductive boron nitride/SEBS/EVA ternary composites: “Processing and characterization”
TL;DR: In this article, the effect of hexagonal boron nitride (BN) particle shape/size and loading level on the thermal, mechanical, electrical properties, and morphology of styrene-ethylene-butylene-styrene terpolymer (SEBS)/poly(ethylene co-vinyl acetate) (EVA) blends to be used as thermal interface materials (TIM) is investigated.
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Preparation of high damping elastomer with broad temperature and frequency ranges based on ternary rubber blends
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Compatibility study of chlorinated polyethylene/ethylene methacrylate copolymer blends using thermal, mechanical, and chemical analysis
Purabi Bhagabati,T. K. Chaki +1 more
TL;DR: In this paper, the compatibility of CPE/EMA blends was investigated using differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA), and Fourier transform infrared (FTIR) spectroscopy techniques.
References
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Book
Viscoelastic properties of polymers
TL;DR: In this article, the authors describe the nature of Viscoelastic behavior of polymeric systems and approximate relations among the linear Viscoels and approximate interrelations among the Viscelastic Functions.
Journal ArticleDOI
Statistical mechanics of cross-linked polymer networks ii. swelling
Paul J. Flory,John Rehner +1 more
TL;DR: In this paper, the interaction of solvents with cross-linked network structures, such as occur in vulcanized rubber, is subjected to a statistical mechanical treatment based on the model and procedure presented in the preceding paper.
Book
Dynamic Mechanical Analysis: A Practical Introduction
TL;DR: An Introduction to Dynamic Mechanical Analysis as discussed by the authors is a good starting point for a discussion of the application of dynamic testing in real world problems, as well as guidelines for DMA applications to real problems.