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Journal ArticleDOI

Effect of the physical state of the activators on the combustion of composite rocket propellants. I. The applied catalysts

TLDR
In this paper, the effects on the burning and thermal decomposition of composite rocket propellants, based on ammonium perchlorate and butyl rubber, of oxide-coated catalysts applied to the surface of the ammonium-perchlorate crystals and introduced into the propellant in the form of a colloidal suspension are investigated.
Abstract
The effects on the burning and thermal decomposition of composite rocket propellants, based on ammonium perchlorate and butyl rubber, of oxide coated catalysts applied to tge surface of the ammonium perchlorate crystals and introduced into the propellant in the form of a colloidal suspension are investigated. It is shown that the possibility of changing the burning rate by means of applying the catalyst on the oxidizer crystal surface is determined by the chemical nature, the content of the compounds deposited on the oxidizer surface, and by the structure of the coating formed on the ammonium perchlorate surface. Excluding the agglomeration of the catalytic additives using the developed methods, the variation in their dispersivity and the nature of localization in the propellant are the indicators of the propellant's performance efficiency within the region of small additive concentrations (up to 0.5%) in the propellant.

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Citations
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Journal ArticleDOI

Studies on the role of iron oxide and copper chromite in solid propellant combustion

TL;DR: In this paper, a systematic study has been carried out, by undertaking experiments at varying levels of combinations of the individual components (ammonium perchlorate, oxidizer and hydroxyl terminated poly butadiene, which is both fuel and binder) of composite solid propellant.
Journal ArticleDOI

Catalysis and inhibition of the combustion of ammonium perchlorate based solid propellants

TL;DR: In this paper, the effect of additives of metal oxides on the combustion of a composite solid propellant based on ammonium perchlorate is studied. And the potentials for affecting the composite solid liquid propellant via gas-phase oxidation-reduction reactions is indicated by the additive of organic sources of active species.
Journal ArticleDOI

Effect of the physical state of activators on the combustion of composite rocket propellants. II. Colloidal inhibitors

TL;DR: In this article, the effect of inhibitors added as powders and colloidal solutions to propellants on the combustion of ammonium perchlorate composite rocket propellants is investigated, and it is shown that multilinear expansion is applicable for a quantitative description of the dependence of the burning rate on the concentration and particle size of the additive.
References
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Journal ArticleDOI

Location of action of burning-rate catalysts in composite propellantcombustion.

TL;DR: HUG as mentioned in this paper is a Fortran-Fap Code for Computing Normal Shock and Detonation Parameters in Gases, which can be used to compute normal shock and detonation parameters in O2-H2 Mixtures.
Journal ArticleDOI

Burning Behavior of Composite Solid Propellant containing porous ammonium perchlorate

TL;DR: Etude de l'influence de la teneur en perchlorate d'ammonium poreux et de la taille des grains sur la vitesse de combustion.
Journal ArticleDOI

Variation of the dispersity and phase composition of a ferrous oxide catalyst in the burning of an ammonium perchlorate-polymethylmethacrylate mixture

TL;DR: In this paper, products of conversion of the ferrous oxide catalyst collected from the burning region of an AP-PMMA mixture show significant aggregation of the catalyst, with large (40-50 μm) spherical particles having a metallic glitter.
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