Journal ArticleDOI
Electrode materials for aqueous rechargeable lithium batteries
TLDR
In this paper, the authors describe the historical development of aqueous rechargeable lithium batteries, the advantages and challenges associated with the use of the aqueously electrolytes in lithium rechargeable battery with an emphasis on the electrochemical performance of various electrode materials.Abstract:
In this review, we describe briefly the historical development of aqueous rechargeable lithium batteries, the advantages and challenges associated with the use of aqueous electrolytes in lithium rechargeable battery with an emphasis on the electrochemical performance of various electrode materials. The following materials have been studied as cathode materials: LiMn2O4, MnO2, LiNiO2, LiCoO2, LiMnPO4, LiFePO4, and anatase TiO2. Addition of certain additives like TiS2, TiB2, CeO2, etc. is found to increase the performance of MnO2 cathode. The following materials have been studied as anode materials: VO2 (B), LiV3O8, LiV2O5, LiTi2(PO4)3, TiP2O3, and very recently conducting polymer, polypyrrole (PPy). The cell PPy/LiCoO2, constructed using polypyrrole as anode delivers an average voltage of 0.86 V with a discharge capacity of 47.7 mA h g−1. It retains the capacity for first 120 cycles. The cell, LiTi2(PO4)3/1 M Li2SO4/LiMn2O4, delivers a capacity of 40 mA h g−1 and specific energy of 60 mW h g−1 with an output voltage of 1.5 V over 200 charge–discharge cycles. An aqueous lithium cell constructed using MWCNTs/LiMn2O4 as cathode material is found to exhibit more than 1,000 cycles with good rate capability.read more
Citations
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Journal ArticleDOI
Aqueous Rechargeable Li and Na Ion Batteries
TL;DR: Haegyeom Kim,†,∥ Jihyun Hong,‚∥ Kyu-Young Park,*,∥ Hyungsub Kim,*,‡,∢ Sung-Wook Kim, and Kisuk Kang are authors of this paper.
Journal ArticleDOI
Polymer-Based Organic Batteries
Simon Muench,Andreas Wild,Christian Friebe,Bernhard Häupler,Tobias Janoschka,Ulrich S. Schubert +5 more
TL;DR: This review provides a comprehensive overview of novel battery systems and discusses the numerous classes of organic, polymer-based active materials as well as auxiliary components of the battery, like additives or electrolytes.
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Clean energy new deal for a sustainable world: from non-CO2 generating energy sources to greener electrochemical storage devices
Philippe Poizot,Franck Dolhem +1 more
TL;DR: In this paper, the authors tackle the tricky energy question and associated environmental issues as personally perceived and highlight the eminent role of electric energy produced from decarbonized sources in a future sustainable economy.
Journal ArticleDOI
A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage
TL;DR: A new type of safe, fast, inexpensive, long-life aqueous electrolyte battery, which relies on the insertion of potassium ions into a copper hexacyanoferrate cathode and a novel activated carbon/polypyrrole hybrid anode and an electrochemically active additive to tune its potential.
Journal ArticleDOI
Emerging applications of atomic layer deposition for lithium-ion battery studies.
TL;DR: Recent advances in using ALD for LIB studies are thoroughly reviewed, covering two technical routes: one for designing and synthesizing new LIB components, i.e., anodes, cathodes, and solid electrolytes, and; 2) ALD used in modifying electrode properties via surface coating.
References
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Journal ArticleDOI
Phospho‐olivines as Positive‐Electrode Materials for Rechargeable Lithium Batteries
TL;DR: In this article, the authors showed that a reversible loss in capacity with increasing current density appears to be associated with a diffusion-limited transfer of lithium across the two-phase interface.
Book
Modern Aspects of Electrochemistry
TL;DR: In this paper, the authors focus on topics at the forefront of electrochemical research, such as splitting water by electrolysis, splitting water with visible light, and the recent development of lithium batteries.
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Lithium insertion into manganese spinels
TL;DR: In this article, Li has been inserted chemically and electrochemically into Mn3O4 and Li[Mn2]O4 at room temperature from X-ray diffraction.
Journal ArticleDOI
Rechargeable Lithium Batteries with Aqueous Electrolytes
TL;DR: Rechargeable lithium-ion batteries that use an aqueous electrolyte have been developed and provide a fundamentally safe and cost-effective technology that can compete with nickelcadmium and lead-acid batteries on the basis of stored energy per unit of weight.
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