Journal ArticleDOI
Electrogeneration of Hydroxyl Radicals on Boron-Doped Diamond Electrodes
TLDR
In this paper, the electrogeneration of hydroxyl radicals was studied at a synthetic B-doped diamond (BDD) thin film electrode, where spin trapping was used for detection of hydoxyl radicals with 5,5-dimethyl-1-pyrroline-Noxide and with salicylic acid using ESR and liq. chromatog.Abstract:
The electrogeneration of hydroxyl radicals was studied at a synthetic B-doped diamond (BDD) thin film electrode. Spin trapping was used for detection of hydroxyl radicals with 5,5-dimethyl-1-pyrroline-N-oxide and with salicylic acid using ESR and liq. chromatog. measurements, resp. The prodn. of H2O2 and competitive oxidn. of formic and oxalic acids were also studied using bulk electrolysis. Oxidn. of salicylic acid gives hydroxylated products (2,3- and 2,5-dihydroxybenzoic acids). The oxidn. process on BDD electrodes involves hydroxyl radicals as electrogenerated intermediates. [on SciFinder (R)]read more
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Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods. An updated review
TL;DR: In this paper, a review of the electrochemical methods used at lab and pilot plant scale to decontaminate synthetic and real effluents containing dyes, considering the period from 2009 to 2013, as an update of our previous review up to 2008.
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Direct And Mediated Anodic Oxidation of Organic Pollutants
Marco Panizza,Giacomo Cerisola +1 more
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Electrogenerated Chemiluminescence and Its Biorelated Applications
TL;DR: ECL has now become a very powerful analytical technique and been widely used in the areas of immunoassay, food and water testing, and biowarfare agent detection and has also been successfully exploited as a detector of flow injection analysis (FIA), high-performance liquid chromatography (HPLC), capillary electrophoresis, and micro total analysis (μTAS).
Journal ArticleDOI
Advanced Oxidation Processes in Water/Wastewater Treatment: Principles and Applications. A Review
TL;DR: Advanced oxidation processes (AOPs) constitute important, promising, efficient, and environmental-friendly methods developed to principally remove persistent organic pollutants (POP) from waters and wastewaters.
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Electrochemical advanced oxidation processes: A review on their application to synthetic and real wastewaters
TL;DR: In this article, an exhaustive review on the treatment of various synthetic and real wastewaters by five key EAOPs, i.e., anodic oxidation (AO), anodic oxidation with electrogenerated H 2 O 2, electro-Fenton (EF), photoelectro-fenton (PEF), alone and in combination with other methods like biological treatment, electrocoagulation, coagulation and membrane filtration processes.
References
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Journal ArticleDOI
Critical Review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals (⋅OH/⋅O− in Aqueous Solution
TL;DR: In this article, the rate constants for over 3500 reaction are tabulated, including reaction with molecules, ions and other radicals derived from inorganic and organic solutes, and the corresponding radical anions, ⋅O− and eaq−, have been critically pulse radiolysis, flash photolysis and other methods.
Journal Article
Critical review of rate condtants for reaction of hydrated electrons, hydrogen atoms and hydroxyl radicals in aqueous solution
Journal ArticleDOI
Spin trapping: ESR parameters of spin adducts.
TL;DR: In this article, the electron spin resonance hyperfine splitting constants of spin adducts of interest in this area are tabulated and a brief comment on the source of the radical trapped is given.
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Electrocatalysis in the electrochemical conversion/combustion of organic pollutants for waste water treatment
TL;DR: In this article, a simplified mechanism for the electrochemical oxidation or combustion of organics is presented according to which selective oxidation occurs with oxide anodes (MOx) forming the so-called higher oxide MOx+1 and combustion occurs with electrodes at the surface of which OH radicals are accumulated.
Electrocatalysis in the electrochemical conversion/combustion of organic pollutants for wastewater treatment
TL;DR: In this paper, a simplified mechanism for the electrochemical oxidation or combustion of organics is presented according to which selective oxidation occurs with oxide anodes (MOx) forming the so-called higher oxide MOx+1 and combustion occurs with electrodes at the surface of which OH radicals are accumulated.