Journal ArticleDOI
Far infra-red spectra and metal-ligand force constants of metal ammine complexes☆
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TLDR
In this article, a normal co-ordinate analysis of these complex ions has been made, including all the ligand atoms, in order to check the vibration assignments made experimentally and to clarify the normal modes of vibration for the observed bands.About:
This article is published in Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy.The article was published on 1966-04-01. It has received 93 citations till now. The article focuses on the topics: Ligand & Molecular vibration.read more
Citations
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Infrared Spectra and Normal Coordinate Analysis of Metalloporphins
TL;DR: In this article, the Urey-Bradley force constants for the corresponding metal-nitrogen stretching modes are estimated to be 0.553, 0.662, and 0.760 mdyn/A, respectively.
Journal ArticleDOI
Infrared and Raman spectra of heterocyelic compounds—IV: The infrared studies and normal vibrations of some 1:1 transition metal complexes of 2,2'-bipyridine
J.S. Strukl,J.L. Walter +1 more
TL;DR: In this paper, a normal coordinate analysis was performed on chloro complexes employing a Urey-Bradley force field with resonance parameter and suitable general valence force field terms about the metal site.
Journal ArticleDOI
Vibrational spectra and force constants of pure ammine complexes
K.H. Schmidt,Achim Müller +1 more
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Skeletal vibrational spectra, force constants, and bond properties of transition metal ammine complexes
K. H. Schmidt,A. Mueller +1 more
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Far infra-red spectra and force constants of ammine complexes of Pt(IV), Pt(II) and Pd(II)
TL;DR: In this article, the metal-nitrogen in-plane bending vibrations were measured in the frequency region from 300 to 200 cm −1 and the metal out-of-planar bending vibrations from 250 to 180 cm−1.
References
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Journal ArticleDOI
The Crystal Structure of Trans-dichloro-diethylenediamine-cobalt. (III). Chloride Hydrochloride Dihydrate, [Coen2Cl2]Cl·HCl·2H2O
TL;DR: The crystal structure of trans-dichlorodiethylenediamine-cobalt (III) chloride hydrochloride has been determined using the rotation method (Fe Kαλ=1937 A).
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Infrared spectra of some hexahalogeno complexes
TL;DR: In this paper, the infrared spectra of hexachloro complexes have been measured from 14 to 35 μ and a strong band observed in the range 350 ∼ 300 cm −1 was assigned to the triply degenerate stretching vibration.
Journal ArticleDOI
Vibrational assignments for metal ammines
TL;DR: In this article, the infra-red spectra of a number of di-, tetra-, and hexammine metal complexes have been measured as solids in KBr wafers.