Journal ArticleDOI
Free‐Electron Model and Doublet Splitting in Aromatic Hydrocarbon Ions
TLDR
In this paper, the doublet splitting in hydrocarbon ions due to spin-orbit interaction arising from electron circulation around the ring was calculated using a free electron model, and the model was extended to the case of free electron models.Abstract:
Doublet splitting in hydrocarbon ions due to spin—orbit interaction arising from electron circulation around the ring has been calculated using a free electron model.read more
Citations
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Jahn—Teller effects in substituted benzene cations. II. Gas phase emission spectrum of 1, 3, 5-C6F3D+3 and comparison with 1, 3, 5-C6F3H+3
TL;DR: In this paper, the Jahn-Teller spectrum of the emission spectrum of 1, 3, 5-C 6 F 3 D + 3 in the 4376-5435 A region has been photographed and vibronically analyzed.
Journal ArticleDOI
Sublimation Energy of Benzene
Purnendranath Sen,Sadhan Basu +1 more
TL;DR: Using a free-electron model for the πelectron system in benzene, the electronic quadrupole moment has been calculated to be 2629 × 10−26 esu as discussed by the authors.
Journal ArticleDOI
Free electron model and photoionization of π-electrons from aromatic hydrocarbons
TL;DR: Using the free electron wave function, it has been shown that the propability of photoionization of a π-electron from aromatic hydrocarbons should be maximum if the incident photon has energy sufficient to ionize and to leave an additional momentum p=√5 Kħ2/2 to the escaping electron.
Journal ArticleDOI
Free electron model and magnetic susceptibility of aromatic hydrocarbons
TL;DR: Using a free electron model for the π-electron system in aromatic hydrocarbons, the susceptibility due to Langevin diamagnetism and Van Vleck high frequency para-magnetism (H. F.) have been calculated.
References
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Journal ArticleDOI
Spin‐Orbit Coupling in Orbitally Degenerate States of Aromatic Ions
TL;DR: In this paper, it was shown that in the orbitally degenerate ground state of the benzene negative ion there is a first-order electron spinorbit interaction associated with the electronic orbital motion around the ring.
Journal ArticleDOI
A Mobile Electron Model for Aromatic Molecules
Klaus Rüdenberg,Robert G. Parr +1 more
TL;DR: In this paper, a three-dimensional mobile electron model for unsaturation electrons in aromatic molecules is described, which allows leakage of electrons across rings and takes aromatic atoms explicitly into account.