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Open AccessJournal ArticleDOI

Function of Hydrogen in Embrittlement of High-strength Steels

Michihiko Nagumo
- 15 Jun 2001 - 
- Vol. 41, Iss: 6, pp 590-598
TLDR
In this article, the role of deformation-induced defects that interact with hydrogen is discussed, and a model is proposed in which increased vacancy density and agglomeration lead to the promotion of failure.
Abstract
Various models so far proposed for the mechanism of hydrogen embrittlement (HE) of steels are critically reviewed with respect to the manifestation of hydrogen in the fracture process. Recent studies that elucidate the hydrogen states and their relevance to HE are discussed. Particular attention is paid to the role of deformation-induced defects that interact with hydrogen. A model is proposed in which increased vacancy density and agglomeration lead to the promotion of failure. The model ascribes HE to the context of ductile fracture in which vacancies play the primary role.

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Citations
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Journal ArticleDOI

Hydrogen Embrittlement Understood

TL;DR: The connection between hydrogen-enhanced plasticity and the hydrogen-induced fracture mechanism and pathway is established through examination of the evolved microstructural state immediately beneath fracture surfaces including voids, quasi-cleavage, and intergranular surfaces as discussed by the authors.
Journal ArticleDOI

Hydrogen Embrittlement Understood

TL;DR: The connection between hydrogen-enhanced plasticity and the hydrogen-induced fracture mechanism and pathway is established through examination of the evolved microstructural state immediately beneath fracture surfaces including voids, quasi-cleavage, and intergranular surfaces as discussed by the authors.
Journal ArticleDOI

Stability and clusterization of hydrogen-vacancy complexes in α-Fe: An ab initio study

TL;DR: In this article, the stability of hydrogen-monovacancy complexes and their binding preferences in Fe-rich structural materials were investigated by means of ab initio supercell calculations based on the density-functional theory.
Journal ArticleDOI

Hydrogen embrittlement of ferritic steels: Observations on deformation microstructure, nanoscale dimples and failure by nanovoiding

TL;DR: In this article, fracture surface features were studied and compared using high-resolution surface-sensitive scanning electron microscopy, and the deformation microstructures just beneath the fracture surfaces were studied using transmission electron microscope, providing a mechanistic view of failure catalyzed by hydrogen.
Journal ArticleDOI

Hydrogen enhances strength and ductility of an equiatomic high-entropy alloy

TL;DR: In this article, the authors show that hydrogen in an equiatomic CoCrFeMnNi high-entropy alloy leads not to catastrophic weakening, but instead increases both, its strength and ductility.
References
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Book

Hydrogen in metals

Journal ArticleDOI

The theory of stress corrosion cracking in alloys

TL;DR: In this paper, stress corrosion cracking is a phenomenon that is of interest to a wide range of metal users when it occurs under service conditions, often without any prior indication of impeding failure, its effect may be catastrophic.

Hydrogen embrittlement and stress corrosion cracking

R. Gibala, +1 more
TL;DR: In this paper, the authors present proceedings which give an account of knowledge and understanding of hydrogen embrittlement and stress corrosion cracking from the viewpoints of the authors, with papers by experts in the field contained in each section.
Book ChapterDOI

Hydrogen in Metals

TL;DR: Buck and his many collaborators spanned this last endeavor as mentioned in this paper, and significant features of our understanding of alloys of metals with hydrogen are described using important papers from his career, using important features of his career.
Journal ArticleDOI

Dislocation modeling and acoustic emission observation of alternating ductile/brittle events in Fe-3wt%Si crystals

TL;DR: In this paper, it has been established that hydrogen assisted subcritical crack growth in Fe-3wt%Si single crystals is discontinuous while accompanied by substantial plasticity, and the near crack tip stress distribution in an elastic-plastic analysis enabled insight into how dislocation shielding led to mirocrack nucleation.
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