Journal ArticleDOI
Functionalized fluoroalkyl and alkenyl silanes: Preparations, reactions, and synthetic applications
TLDR
In this paper, a review of functionalized fluoroalkyl and alicyclic silanes has been presented, focusing mainly on the chemistries of (1) 1-substituted difluoromethyl silanes (XCF2SiR3), (2) 2,2-diffluorovinylsilanes (CF2 CX SiR3) and (3) trifluorooisopropenyl, triffluoroacetimidoyl, and (4) other fluorinated alicycyclAbout:
This article is published in Journal of Fluorine Chemistry.The article was published on 2008-07-01. It has received 43 citations till now. The article focuses on the topics: Silanes & Alicyclic compound.read more
Citations
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Journal ArticleDOI
Selective difluoromethylation and monofluoromethylation reactions
Jinbo Hu,Wei Zhang,Fei Wang +2 more
TL;DR: This feature article summarizes the presently known selective diffluoromethylation and monofluorometHylation methods, including nucleophilic, electrophilic, and free radical di- and mon ofluorometric hylation reagents and reactions.
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Efficient and direct nucleophilic difluoromethylation of carbonyl compounds and imines with Me3SiCF2H at ambient or low temperature.
TL;DR: It is found that, by using a proper Lewis base activator, Me(3)SiCF(2)H can efficiently difluoromethylate various aldehydes, ketones, and imines to give the corresponding products in good to excellent yields at room temperature or even at -78 °C.
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Palladium-catalyzed 2,2,2-trifluoroethylation of organoboronic acids and esters.
Yanchuan Zhao,Jinbo Hu +1 more
TL;DR: It is surmised that a transition-metal-catalyzed 2,2,2-trifluoroethylation using readily available trifluoromethyl iodide (CF3CH2I) and organoboronic acids could provide an alternative method for the preparation of (2,1,2 -trifloroethyl)arenes; a process that has not been reported to date.
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Difluoromethylation and trifluoromethylation reagents derived from tetrafluoroethane β-sultone: Synthesis, reactivity and applications
TL;DR: A review of TFES-derived difluoromethylation reagents can be found in this paper, where the authors discuss the recent progress of the TFES and reports on TFES derived derivatives as reagents.
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Fabrication of superhydrophobic coatings for corrosion protection by electrodeposition: a comprehensive review
TL;DR: In this article, a general theory of super-hydrophobic surface, including factors affecting wettability and theoretical wetting models, is reviewed, and the mechanism, application status and anti-corrosion performance of superhydrophilic coatings prepared by metal electrodeposition, non-metallic electrodepositions, and composite electrodeposing are summarized in detail, respectively.
References
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Comprehensive organic chemistry : the synthesis and reactions of organic compounds
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Perfluoroalkylation with Organosilicon Reagents
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