Journal ArticleDOI
Generation of O-quinone methides in solution. Trimerization
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This article is published in Journal of Organic Chemistry.The article was published on 1970-03-01. It has received 38 citations till now.read more
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o-Quinone methides: intermediates underdeveloped and underutilized in organic synthesis
Journal ArticleDOI
Modeling of α-tocopherol loss and oxidation products formed during thermoxidation in triolein and tripalmitin mixtures
Tom Verleyen,Afaf Kamal-Eldin,Carmen Dobarganes,Roland Verhé,Koen Dewettinck,André Huyghebaert +5 more
TL;DR: The results indicate a very high susceptibility of α-tocopherol to capture peroxyl radicals upon oxidation, leading to the formation of polar tocopherol oxidation products.
Journal ArticleDOI
Synthesis of UV-curable tung oil and UV-curable tung oil based alkyd
TL;DR: In this paper, two UV-curable tung oil-based resins were synthesized via a Diels-Alder cycloaddition and characterized by 1H NMR, 13C NMR and MALDI-TOF mass spectroscopy.
Journal ArticleDOI
Quinones and quinone-methides—I : Cyclization and dimerisation of crystalline ortho-quinone methides from phenol oxidation reactions
TL;DR: In this paper, the structure of the colorless dimer, which is of a type not previously reported, suggests that an ionic reaction is involved in its formation, which rapidly dimerises in polar solvents.
Journal ArticleDOI
Efficient Generation of ortho-Quinone Methide: Application to the Biomimetic Syntheses of (±)-Schefflone and Tocopherol Trimers
TL;DR: An efficient method using silver oxide-mediated oxidation for the synthesis of ortho-quinone methides has been developed and applied to the biomimetic syntheses of novel trimeric natural products, (±)-schefflone and tocopherol trimers.