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Gold nanoclusters prepared from an eighteenth century two-phases procedure supported on thiol-containing SBA-15 for liquid phase oxidation of cyclohexene with molecular oxygen

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TLDR
In this article, the incorporation of finely divided and well-dispersed Au species into SBA-15 mesoporous silica functionalized with mercaptopropyl groups, and the catalytic activity of the resulting Au-materials in the liquid phase oxidation of cyclohexene with molecular oxygen at atmospheric pressure is described.
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This article is published in Catalysis Today.The article was published on 2017-09-01. It has received 13 citations till now. The article focuses on the topics: Cyclohexene & Nanoclusters.

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Ten Years of Aberration Corrected Electron Microscopy for Ordered Nanoporous Materials

TL;DR: In this article, the authors reviewed the recent progress of electron microscopy science applied to the characterization of different nanoporous materials since the first work that made use of spherical aberration (C-s) corrected electron microscope in 2010.
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H5PV2Mo10O40 encapsulated into Cu3(BTC)2 as an efficient heterogeneous nanocrystalline catalyst for styrene epoxidation

TL;DR: In this article, a nanocrystalline POM@MOF was formulated as [Cu12(BTC)8(H2O)12][H5PV2Mo10O40] and analyzed using powder X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, scanning electron microscopy (SEM), thermal gravimetric analysis (TGA) and nitrogen adsorption-desorption analysis.
Journal ArticleDOI

Observation of Ag Nanoparticles in/on Ag@MIL-100(Fe) Prepared Through Different Procedures.

TL;DR: The aim of this study is to evaluate whether the MIL-100 would uptake metal particles using a similar principle as that of the ion exchange in zeolites, or else, their inherent humidity would favor the “dissolution” of the metal salt, thus yielding very small metal particles.
Journal ArticleDOI

Immobilization of gold on short-channel mesoporous SBA-15 functionalized with thiol and hydrophobic groups for oxidation reactions

TL;DR: In this article, nanosized gold entities have been used as catalysts for the oxidation of cyclohexene with molecular oxygen in liquid phase at atmospheric pressure, and the effect of the nature of the sulphur functional group was studied.
References
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Journal ArticleDOI

Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology.

TL;DR: A review of gold nanoparticles can be found in this article, where the most stable metal nanoparticles, called gold colloids (AuNPs), have been used for catalysis and biology applications.
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Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid-liquid system

TL;DR: Using two-phase reduction of AuCl4 by sodium borohydride in the presence of an alkanethiol, solutions of 1-3 nm gold particles bearing a surface coating of thiol have been prepared and characterised; this novel material can be handled as a simple chemical compound as mentioned in this paper.
BookDOI

Transmission Electron Microscopy

TL;DR: The client would like to get a larger, approximately 3 cm in diameter, well fixed tissue sample, together with a detailed report of the clinical presentation, gross, and microscopic lesions, along with the submission of samples prepared in a similar manner by the client for processing.
Journal ArticleDOI

Size and temperature dependence of the plasmon absorption of colloidal gold nanoparticles

TL;DR: In this paper, the size and temperature dependence of the plasmon absorption of 9, 15, 22, 48, and 99 nm gold nanoparticles in aqueous solution were studied.
Journal ArticleDOI

The Bakerian Lecture: Experimental Relations of Gold (and Other Metals) to Light

TL;DR: The undulatory theory of light, with the phenomena for which it strives to account, seems to me, who am only an experimentalist, to stand midway between what we may conceive to be the coarser mechanical actions of matter, with their explanatory philosophy, and that other branch which includes, or should include, the physical idea of forces acting at a distance as mentioned in this paper.
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