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Book ChapterDOI

Grain Refinement Mechanism of Aluminum by Al-Ti-B Master Alloys

Xiaoming Wang, +1 more
- pp 189-193
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TLDR
In this article, a dynamic nucleation theory for the grain refinement is proposed as a dynamic Al3Ti layer in the thickness of a couple of atoms existing on the surface of (Ti,Al)B2 and being responsible for nucleating aluminum grains.
Abstract
Al-Ti-B type master alloys are routinely added into aluminum for a grain refinement purpose. However, a consensus about the mechanism of grain refinement is still yet to reach. This work is aiming at further understanding the grain refinement mechanism through studying the stability of TiB2 in pure aluminum and TiB2/Al3Ti interfaces in aluminum by transmission electron microscopic (TEM) techniques. It is found that TiB2 reacts with aluminum forming (Ti,Al)B2 solid solution and releasing titanium into aluminum. A crystallographic orientation relationship exists between TiB2 and Al3Ti in Al-Ti-B alloys. A dynamic nucleation theory for the grain refinement is therefore proposed as a dynamic Al3Ti layer in the thickness of a couple of atoms existing on the surface of (Ti,Al)B2 and being responsible for nucleating aluminum grains.

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Journal ArticleDOI

Modelling of inoculation of metallic melts : Application to grain refinement of aluminium by Al-Ti-B

TL;DR: In this article, a numerical model is presented for the prediction of grain size in inoculated castings and is tested against measured grain sizes obtained in standard grain-refiner tests on aluminium alloys.
Journal ArticleDOI

Grain refinement of aluminium and its alloys by heterogeneous nucleation and alloying

TL;DR: A review of the literature on grain refinement by heterogeneous nucleation and alloying can be found in this paper, where the types of grain refiner, Al-Ti-B master alloys in particular, and their methods of manufacture are discussed.
Journal ArticleDOI

Grain refining of aluminium and its alloys using inoculants

TL;DR: Grain structure is an important and readily observable feature in cast aluminium alloys as mentioned in this paper, and three types of grain morphology are possible, namely, columnar, twinned columnar and equiaxed.
Journal ArticleDOI

Mechanism of grain refinement in aluminium

TL;DR: In this article, the commercial grain refining practice of aluminium has been experimentally simulated by introducing synthetic TiB2 crystallites into melts by a specially developed technique, and experimental findings indicate that TiB 2 crystallites alone do not nucleate α-Al.
Journal ArticleDOI

Grain Refining Mechanism in the Al/Al-Ti-B System

TL;DR: In this paper, a high-resolution electron microscopy investigation has confirmed the existence of a Ti-rich monolayer on the surface of the (0.0, 0.1) TiB2 surface, which is most likely to be a (1 − 1 2 ) Al3Ti 2DC.
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