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Green Synthesis and Applications of ZnO and TiO2 Nanostructures.

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TLDR
A review of the recent state-of-the-art advancements in the green synthesis approach for ZnO and TiO2 nanostructures and their applications can be found in this article.
Abstract
Over the last two decades, oxide nanostructures have been continuously evaluated and used in many technological applications. The advancement of the controlled synthesis approach to design desired morphology is a fundamental key to the discipline of material science and nanotechnology. These nanostructures can be prepared via different physical and chemical methods; however, a green and ecofriendly synthesis approach is a promising way to produce these nanostructures with desired properties with less risk of hazardous chemicals. In this regard, ZnO and TiO2 nanostructures are prominent candidates for various applications. Moreover, they are more efficient, non-toxic, and cost-effective. This review mainly focuses on the recent state-of-the-art advancements in the green synthesis approach for ZnO and TiO2 nanostructures and their applications. The first section summarizes the green synthesis approach to synthesize ZnO and TiO2 nanostructures via different routes such as solvothermal, hydrothermal, co-precipitation, and sol-gel using biological systems that are based on the principles of green chemistry. The second section demonstrates the application of ZnO and TiO2 nanostructures. The review also discusses the problems and future perspectives of green synthesis methods and the related issues posed and overlooked by the scientific community on the green approach to nanostructure oxides.

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Citations
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Journal ArticleDOI

Green Fabrication of Zinc Oxide Nanoparticles Using Phlomis Leaf Extract: Characterization and In Vitro Evaluation of Cytotoxicity and Antibacterial Properties.

TL;DR: In this article, the authors used Phlomis leaf extract as an effective reducing agent to synthesize zinc oxide nanoparticles (ZnO NPs) for green nanoparticle synthesis and characterization by UV-Vis spectrophotometry, Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Dynamic light scattering (DLS), Zeta potential, and Field Emission Scanning Electron Microscope (FESEM) techniques.
Journal ArticleDOI

Green Synthesis and Characterizations of Zinc Oxide (ZnO) Nanoparticles Using Aqueous Leaf Extracts of Coffee (Coffea arabica) and Its Application in Environmental Toxicity Reduction

TL;DR: In this paper, a green deposition method of zinc oxide nanoparticles using coffee leaf extraction was successfully prepared, and the determination and reduction of Zn ions to ZnO NPs were characterized by using a UV-visible spectroscope.
Journal ArticleDOI

Breast Cancer Inhibition by Biosynthesized Titanium Dioxide Nanoparticles Is Comparable to Free Doxorubicin but Appeared Safer in BALB/c Mice.

TL;DR: In this article, a rapid, cost-effective, and green synthesis of titanium dioxide nanoparticles (NPs) has been carried out; Ex vivo and in vivoevaluation of their safety and anti-tumor efficacy compared to doxorubicin (DOX), a highly efficient breast anti-cancer agent but limited by severe cardiotoxicity in many patients.
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Synthesis, Characterization, and Antibacterial Activity of ZnO Nanoparticles from Fresh Leaf Extracts of Apocynaceae, Carissa spinarum L. (Hagamsa)

TL;DR: In this paper , Carissa spinarum extract was used to depose zinc oxide nanoparticles (ZnO NPs) in a green way using bioorganic foundations, and a characterization study was done by UV-Vis spectroscopy, X-ray diffraction, scanning electron microscope (SEM), and photoluminescence (PL).
References
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Environmental Applications of Semiconductor Photocatalysis

TL;DR: The slow pace of hazardous waste remediation at military installations around the world is causing a serious delay in conversion of many of these facilities to civilian uses as discussed by the authors, which is a serious problem.
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A review and recent developments in photocatalytic water-splitting using TiO2 for hydrogen production

TL;DR: In this article, the up-to-date development of the above-mentioned technologies applied to TiO 2 photocatalytic hydrogen production is reviewed, based on the studies reported in the literature, metal ion-implantation and dye sensitization are very effective methods to extend the activating spectrum to the visible range.
Journal ArticleDOI

Nanometer-sized semiconductor clusters: materials synthesis, quantum size effects, and photophysical properties

TL;DR: In this article, the size effect on the optical and photophysical properties of semiconductor clusters has been studied in the condensed phase and the current status of materials synthesis and the prospect for making monodisperse clusters of well-defined surfaces has been discussed.
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Parameters affecting the photocatalytic degradation of dyes using TiO2-based photocatalysts: a review.

TL;DR: The findings revealed that various parameters, such as the initial pH of the solution to be degraded, oxidizing agents, temperature at which the catalysts must be calcined, dopant(s) content and catalyst loading exert their individual influence on the photocatalytic degradation of any dye in wastewaters.
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A review of ZnO nanoparticles as solar photocatalysts: Synthesis, mechanisms and applications

TL;DR: In this paper, the photo-degradation mechanisms of persistent organic pollutants (POPs) and the recent progress in ZnO nanostructured fabrication methods including doping, heterojunction and modification techniques as well as improvements of ZnOs as a photocatalyst are reviewed.
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